An unprecedented up-field shift in the 13C NMR spectrum of the carboxyl carbons of the lantern-type dinuclear complex TBA[Ru2(O2CCH3)4Cl2] (TBA+ = tetra(n-butyl)ammonium cation)

A large up-field shift (-763 ppm) has been observed for the carboxyl carbons of the dichlorido complex TBA[Ru(2)(O(2)CCH(3))(4)Cl(2)] (TBA(+) = tetra(n-butyl)ammonium cation) in the (13)C NMR spectrum (CD(2)Cl(2) at 25 °C). The DFT calculations showed spin delocalization from the paramagnetic Ru(2)(...

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Bibliographic Details

Published in:	Dalton transactions : an international journal of inorganic chemistry Vol. 44; no. 30; pp. 13439 - 13443
Main Authors:	Hiraoka, Yuya, Ikeue, Takahisa, Sakiyama, Hiroshi, Guégan, Frédéric, Luneau, Dominique, Gillon, Béatrice, Hiromitsu, Ichiro, Yoshioka, Daisuke, Mikuriya, Masahiro, Kataoka, Yusuke, Handa, Makoto
Format:	Journal Article
Language:	English
Published:	England 14.08.2015
ISSN:	1477-9234
Online Access:	Get more information
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