Metal-Oxide-Based Nucleation Process under Confined Conditions: Two Mixed-Valence V6-Type Aggregates Closing the W48 Wheel-Type Cluster Cavities

Getting together helps: The wheel‐shaped {P8W48} polyoxotungstate (see picture) provides a reaction chamber for the directed assembly of two unprecedented mixed‐valence vanadium oxide cavity‐capping groups based on linked octahedra and tetrahedra with VIV and VV centers, respectively. The magnetic a...

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Bibliographic Details

Published in:	Angewandte Chemie International Edition Vol. 46; no. 24; pp. 4477 - 4480
Main Authors:	Müller, Achim, Pope, Michael T., Todea, Ana Maria, Bögge, Hartmut, van Slageren, Joris, Dressel, Martin, Gouzerh, Pierre, Thouvenot, René, Tsukerblat, Boris, Bell, Aidan
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 2007 WILEY‐VCH Verlag
Subjects:	confined geometries directed‒assembly electronic structure mixed‒valent compounds polyoxometalates
ISSN:	1433-7851, 1521-3773
Online Access:	Get full text
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