Co-Ligand Involvement in Ground and Excited States of Electron-Rich (Polypyridyl)PtII Complexes
The electronic absorption and luminescence properties of electron‐rich organometallic platinum(II) complexes with aromatic α‐diimine ligands [(α‐diimine)PtR2] (R = alkyl, alkynyl, Ph or Mes, Mes = 2,4,6‐trimethylphenyl) were examined. The crystal and molecular structures of [(bpy)PtMe2], [(tap)PtPh2...
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| Published in: | European journal of inorganic chemistry Vol. 2003; no. 10; pp. 1917 - 1938 |
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| Main Authors: | , , |
| Format: | Journal Article |
| Language: | English |
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Weinheim
WILEY-VCH Verlag
01.05.2003
WILEY‐VCH Verlag |
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| ISSN: | 1434-1948, 1099-0682 |
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| Abstract | The electronic absorption and luminescence properties of electron‐rich organometallic platinum(II) complexes with aromatic α‐diimine ligands [(α‐diimine)PtR2] (R = alkyl, alkynyl, Ph or Mes, Mes = 2,4,6‐trimethylphenyl) were examined. The crystal and molecular structures of [(bpy)PtMe2], [(tap)PtPh2] and [(tmphen)PtMes2] were determined from single‐crystal XRD and discussed in view of intermolecular interactions that influence the emission behaviour. The combination of theoretical calculations (DFT) and spectroscopic techniques (absorption and emission) revealed the character of electronic transitions and excited states. In particular they showed that the co‐ligand involvement in the frontier orbitals is small for R = Me, but large in case of R = alkynyl, Ph or Mes. Depending on the chelate ligand and its substitution pattern, the emission efficiencies of the complexes cover a wide range from strong emission in fluid solution at ambient temperature to very weak emission in rigid matrices (glasses) at low temperatures with no emission at ambient temperature. The emission lifetimes, determined at low temperature in solvent glasses, mainly depend on the chelate ligand and not on the co‐ligands. The emission quantum yields of the complexes in solution at room temperatures are much larger for R = Mes than for R = Ph or Me. The emission bands for the complexes with unsaturated co‐ligands show slight structuring at low temperatures in contrast to the alkyl‐substituted ones. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) |
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| AbstractList | The electronic absorption and luminescence properties of electron‐rich organometallic platinum(II) complexes with aromatic α‐diimine ligands [(α‐diimine)PtR2] (R = alkyl, alkynyl, Ph or Mes, Mes = 2,4,6‐trimethylphenyl) were examined. The crystal and molecular structures of [(bpy)PtMe2], [(tap)PtPh2] and [(tmphen)PtMes2] were determined from single‐crystal XRD and discussed in view of intermolecular interactions that influence the emission behaviour. The combination of theoretical calculations (DFT) and spectroscopic techniques (absorption and emission) revealed the character of electronic transitions and excited states. In particular they showed that the co‐ligand involvement in the frontier orbitals is small for R = Me, but large in case of R = alkynyl, Ph or Mes. Depending on the chelate ligand and its substitution pattern, the emission efficiencies of the complexes cover a wide range from strong emission in fluid solution at ambient temperature to very weak emission in rigid matrices (glasses) at low temperatures with no emission at ambient temperature. The emission lifetimes, determined at low temperature in solvent glasses, mainly depend on the chelate ligand and not on the co‐ligands. The emission quantum yields of the complexes in solution at room temperatures are much larger for R = Mes than for R = Ph or Me. The emission bands for the complexes with unsaturated co‐ligands show slight structuring at low temperatures in contrast to the alkyl‐substituted ones. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) |
| Author | Záliš, Stanislav Slageren, Joris van Klein, Axel |
| Author_xml | – sequence: 1 givenname: Axel surname: Klein fullname: Klein, Axel email: aklein@iac.uni-stuttgart.de organization: Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany – sequence: 2 givenname: Joris van surname: Slageren fullname: Slageren, Joris van email: slageren@pi1.physik.uni-stuttgart.de organization: Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands – sequence: 3 givenname: Stanislav surname: Záliš fullname: Záliš, Stanislav organization: J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 18000 Prague 8, Czech Republic |
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| References | J. F. Michalec , S. A. Bejune , D. G. Cuttell , G. C. Summerton , J. A. Gertenbach , J. S. Field , R. J. Haines , D. R. McMillin , Inorg. Chem. 2001 , 40 , 2193 −2200 . W. B. Connick , V. M. Miskowski , V. H. Houlding , H. B. Gray , Inorg. Chem. 2000 , 39 , 2585 −2592 . D. Andrae , U. Haeussermann , M. Dolg , H. Stoll , H. Preuss , Theor. Chim. Acta 1990 , 77 , 123 −141 . Z. Hao , Z. Tang , Q. Shi , Inorg. Chim. Acta 1999 , 284 , 112 −115 . J. A. Bailey , M. G. Hill , R. E. Marsh , V. M. Miskowski , W. P. Schaefer , H. B. Gray , Inorg. Chem. 1995 , 34 , 4591 −4599 . S. Ernst , C. Vogler , A. Klein , W. Kaim , Inorg. Chem. 1996 , 35 , 1295 −1300 . V. M. Miskowski , V. H. Houlding , C.-M. Che , Y. Wang , Inorg. Chem. 1993 , 32 , 2518 −2524 . V. H. Houlding , V. M. Miskowski , Coord. Chem. Rev. 1991 , 111 , 145 −152 . A. D. Becke , Phys. Rev. A 1988 , 38 , 3098 −3100 . C. Fonseca Guerra , J. G. Snijders , G. te Velde , E. J. Baerends , Theor. Chim. Acta 1998 , 99 , 391 −403 . C.-W. Chan , L.-K. Cheng , C.-M. Che , Coord. Chem. Rev. 1994 , 132 , 87 −97 . A. Klein , W. Kaim , E. Waldhoer , H.-D. Hausen , J. Chem. Soc., Perkin Trans. 2 1995 , 2121 −2126 . H. C. Clark , L. E. Manzer , J. Organomet. Chem. 1973 , 59 , 411 −428 . M. R. Waterland , K. C. Gordon , J. J. McGarvey , P. M. Jayaweera , J. Chem. Soc., J. Chem. Soc., Dalton Trans. 1998 , 609 −616 . J. E. McGarrah , Y.-J. Kim , M. Hissler , R. Eisenberg , Inorg. Chem. 2001 , 40 , 4510 −4511 . A. Kirsch-De Mesmaeker , R. M. D. Nasielski-Hinkens , D. Pauwels , J. Nasielski , Inorg. Chem. 1984 , 23 , 377 −379 . S. J. A. van Gisbergen , J. G. Snijders , E. J. Baerends , Comput. Phys. Commun. 1999 , 118 , 119 −138 . J. van Slageren , D. J. Stufkens , S. Záliš , A. Klein , J. Chem. Soc., Dalton Trans. 2002 , 218 −225 . D. E. Woon , T. H. J. Dunning , J. Chem. Phys. 1993 , 98 , 1358 −1371 . I. R. Farrell , J. van Slageren , S. Záliš , A. Vlček, Jr. , Inorg. Chim. Acta 2001 , 315 , 44 −52 . K. Karlsson , C. Moucheron , A. Kirsch-De Mesmaeker , New J. Chem. 1994 , 18 , 721 −729 . V. Balzani , A. Credi , M. Venturi , Coord. Chem. Rev. 1998 , 171 , 3 −16 . A. Von Zelewsky , P. Belser , P. Hayoz , R. Dux , X. Hua , A. Suckling , H. Stoeckli-Evans , Coord. Chem. Rev. 1994 , 132 , 75 −85 . J. D. Scott , R. J. Puddephatt , Organometallics 1983 , 2 , 1643 −1648 . W. Kaim , A. Klein , Organometallics 1995 , 14 , 1176 −1186 . J. A. Weinstein , N. N. Zheligovskaya , M. Y. Mel′nikov , F. Hartl , J. Chem. Soc., J. Chem. Soc., Dalton Trans. 1998 , 15 , 2459 −2466 . W. B. Connick , D. Geiger , R. Eisenberg , Inorg. Chem. 1999 , 38 , 3264 −3265 . A. Vogler , H. Kunkely , Comments Inorg. Chem. 1990 , 9 , 201 −220 . R. M. Hartshorn , J. K. Barton , J. Am. Chem. Soc. 1992 , 114 , 5919 −5925 . C. Vogler , B. Schwederski , A. Klein , W. Kaim , J. Organomet. Chem. 1992 , 436 , 367 −378 . W. Kaim , A. Klein , S. Hasenzahl , H. Stoll , S. Záliš , J. Fiedler , Organometallics 1998 , 17 , 237 −247 . W. P. Schaefer , W. B. Connick , V. M. Miskowski , H. B. Gray , Acta Crystallogr., Sect. C 1992 , 48 , 1776 −1778 . J. P. Perdew , Phys. Rev. B 1986 , 33 , 8822 −8824 . Y.-Y. Ng , C.-M. Che , S.-M. Peng , New J. Chem. 1996 , 20 , 781 −789 . M. T. Cocker , R. E. Bachman , Inorg. Chem. 2001 , 40 , 1550 −1556 . K. E. Dungey , B. D. Thompson , N. A. P. Kane-Maguire , L. L. Wright , Inorg. Chem. 2000 , 39 , 5192 −5196 . M. Textor , H. R. Oswald , Z. Anorg. Allg. Chem. 1974 , 407 , 244 −256 . W. Paw , S. D. Cummings , M. A. Mansour , W. B. Connick , D. K. Geiger , R. Eisenberg , Coord. Chem. Rev. 1998 , 171 , 125 −150 . Q.-Z. Yang , L.-Z. Wu , Z.-X. Wu , L.-P. Zhang , C.-H. Tung , Inorg. Chem. 2002 , 41 , 5653 −5655 . S. Hasenzahl , H.-D. Hausen , W. Kaim , Chem. Eur. J. 1995 , 1 , 95 −99 . H. D. Stoeffler , N. B. Thornton , S. L. Temkin , K. S. Schanze , J. Am. Chem. Soc. 1995 , 117 , 7119 −7128 . S. Achar , V. J. Catalano , Polyhedron 1997 , 16 , 1555 −1561 . A. Klein , H.-D. Hausen , W. Kaim , J. Organomet. Chem. 1992 , 440 , 207 −217 . R. S. Osborn , D. Rogers , J. Chem. Soc., Dalton Trans. 1974 , 1002 −1004 . A. Klein , J. van Slageren , S. Záliš , Inorg. Chem. 2002 , 41 , 5216 −5225 . J. Biedermann , G. Gliemann , U. Klement , K.-J. Range , M. Zabel , Inorg. Chem. 1990 , 29 , 1884 −1888 . M. Hissler , J. E. McGarrah , W. B. Connick , D. K. Geiger , S. D. Cummings , R. Eisenberg , Coord. Chem. Rev. 2000 , 208 , 115 −137 . A. Klein , E. J. L. McInnes , W. Kaim , J. Chem. Soc., Dalton Trans. 2002 , 2371 −2378 . M. Kato , C. Kosuge , S. Yano , M. Kimura , Acta Crystallogr., Sect. C 1998 , 54 , 621 −623 . M. Maestri , D. Sandrini , V. Balzani , L. Chassot , P. Jolliet , A. Von Zelewsky , Chem. Phys. Lett. 1985 , 122 , 375 −379 . L. Jacquet , J. M. Kelly , A. Kirsch-De Mesmaeker , J. Chem. Soc., Chem. Commun. 1995 , 913 −914 . A. Klein , T. Scheiring , W. Kaim , Z. Anorg. Allg. Chem. 1999 , 625 , 1177 −1180 . C. Eaborn , K. Kundu , A. Pidcock , J. Chem. Soc., Dalton Trans. 1981 , 933 −938 . N. Chaudhury , R. J. Puddephatt , J. Organomet. Chem. 1975 , 84 , 105 −115 . V. M. Miskowski , V. H. Houlding , Inorg. Chem. 1989 , 28 , 1529 −1533 . M. Hissler , W. B. Connick , D. K. Geiger , J. E. McGarrah , D. Lipa , R. J. Lachicotte , R. Eisenberg , Inorg. Chem. 2000 , 39 , 447 −457 . P. J. Stephens , F. J. Devlin , C. F. Cabalowski , M. J. Frisch , J. Phys. Chem. 1994 , 98 , 11623 −11627 . E. van Lenthe , A. Ehlers , E. J. Baerends , J. Chem. Phys. 1999 , 110 , 8943 −8953 . W. Lu , M. C. W. Chan , K.-K. Cheung , C.-M. Che , Organometallics 2001 , 20 , 2477 −2486 . A. Klein , C. Vogler , W. Kaim , Organometallics 1996 , 15 , 236 −244 . V. M. Miskowski , V. H. Houlding , Inorg. Chem. 1991 , 30 , 4446 −4452 . W. B. Connick , R. E. Marsh , W. P. Schaefer , H. B. Gray , Inorg. Chem. 1997 , 36 , 913 −922 . D. R. McMillin , J. J. Moore , Coord. Chem. Rev. 2002 , 229 , 113 −121 . R. E. Holmlin , J. A. Yao , J. K. Barton , Inorg. Chem. 1999 , 38 , 174 −189 . C. J. Kleverlaan , D. J. Stufkens , I. P. Clark , M. W. George , H. van Willigen , A. Vlček, Jr. , J. Am. Chem. Soc. 1998 , 120 , 10871 −10879 . C. E. Whittle , J. A. Weinstein , M. W. George , K. S. Schanze , Inorg. Chem. 2001 , 40 , 4053 −4062 . A. Klein , J. van Slageren , S. Záliš , J. Organomet. Chem. 2001 , 620 , 202 −210 . E. M. Kober , J. L. Marshall , W. J. Dressick , B. P. Sullivan , J. V. Caspar , T. J. Meyer , Inorg. Chem. 1985 , 24 , 2755 −2763 . 1994; 132 1991; 111 1983; 2 1992; 440 1986; 33 1973; 59 1995; 34 1984; 23 1988; 38 1974 1999; 284 1996; 35 2001; 40 2001; 620 1985; 24 1985; 122 1998; 15 1998; 171 1998; 17 2002; 41 1993; 32 1992; 114 2000; 208 1992; 436 1997; 16 2002; 229 1992; 48 1981 1975; 84 1998; 54 1996; 20 1998; 99 1998; 120 1990; 77 1995; 14 1991; 30 1974; 407 1998 1995; 117 1995 2002 1995; 1 1996; 15 1989; 28 2001; 20 1999; 625 2000; 39 1990; 29 1999; 38 1997; 36 1993; 98 1999; 110 1994; 18 1999; 118 1990; 9 2001; 315 1994; 98 |
| References_xml | – reference: K. Karlsson , C. Moucheron , A. Kirsch-De Mesmaeker , New J. Chem. 1994 , 18 , 721 −729 . – reference: A. Klein , C. Vogler , W. Kaim , Organometallics 1996 , 15 , 236 −244 . – reference: J. van Slageren , D. J. Stufkens , S. Záliš , A. Klein , J. Chem. Soc., Dalton Trans. 2002 , 218 −225 . – reference: A. Kirsch-De Mesmaeker , R. M. D. Nasielski-Hinkens , D. Pauwels , J. Nasielski , Inorg. Chem. 1984 , 23 , 377 −379 . – reference: W. P. Schaefer , W. B. Connick , V. M. Miskowski , H. B. Gray , Acta Crystallogr., Sect. C 1992 , 48 , 1776 −1778 . – reference: P. J. Stephens , F. J. Devlin , C. F. Cabalowski , M. J. Frisch , J. Phys. Chem. 1994 , 98 , 11623 −11627 . – reference: W. Lu , M. C. W. Chan , K.-K. Cheung , C.-M. Che , Organometallics 2001 , 20 , 2477 −2486 . – reference: Y.-Y. Ng , C.-M. Che , S.-M. Peng , New J. Chem. 1996 , 20 , 781 −789 . – reference: J. F. Michalec , S. A. Bejune , D. G. Cuttell , G. C. Summerton , J. A. Gertenbach , J. S. Field , R. J. Haines , D. R. McMillin , Inorg. Chem. 2001 , 40 , 2193 −2200 . – reference: S. J. A. van Gisbergen , J. G. Snijders , E. J. Baerends , Comput. Phys. Commun. 1999 , 118 , 119 −138 . – reference: R. M. Hartshorn , J. K. Barton , J. Am. Chem. Soc. 1992 , 114 , 5919 −5925 . – reference: V. M. Miskowski , V. H. Houlding , Inorg. Chem. 1991 , 30 , 4446 −4452 . – reference: C.-W. Chan , L.-K. Cheng , C.-M. Che , Coord. Chem. Rev. 1994 , 132 , 87 −97 . – reference: J. Biedermann , G. Gliemann , U. Klement , K.-J. Range , M. Zabel , Inorg. Chem. 1990 , 29 , 1884 −1888 . – reference: A. Klein , W. Kaim , E. Waldhoer , H.-D. Hausen , J. Chem. Soc., Perkin Trans. 2 1995 , 2121 −2126 . – reference: A. Klein , E. J. L. McInnes , W. Kaim , J. Chem. Soc., Dalton Trans. 2002 , 2371 −2378 . – reference: W. B. Connick , D. Geiger , R. Eisenberg , Inorg. Chem. 1999 , 38 , 3264 −3265 . – reference: I. R. Farrell , J. van Slageren , S. Záliš , A. Vlček, Jr. , Inorg. Chim. Acta 2001 , 315 , 44 −52 . – reference: J. P. Perdew , Phys. Rev. B 1986 , 33 , 8822 −8824 . – reference: D. Andrae , U. Haeussermann , M. Dolg , H. Stoll , H. Preuss , Theor. Chim. Acta 1990 , 77 , 123 −141 . – reference: D. E. Woon , T. H. J. Dunning , J. Chem. Phys. 1993 , 98 , 1358 −1371 . – reference: R. E. Holmlin , J. A. Yao , J. K. Barton , Inorg. Chem. 1999 , 38 , 174 −189 . – reference: M. R. Waterland , K. C. Gordon , J. J. McGarvey , P. M. Jayaweera , J. Chem. Soc., J. Chem. Soc., Dalton Trans. 1998 , 609 −616 . – reference: W. B. Connick , V. M. Miskowski , V. H. Houlding , H. B. Gray , Inorg. Chem. 2000 , 39 , 2585 −2592 . – reference: W. B. Connick , R. E. Marsh , W. P. Schaefer , H. B. Gray , Inorg. Chem. 1997 , 36 , 913 −922 . – reference: M. Kato , C. Kosuge , S. Yano , M. Kimura , Acta Crystallogr., Sect. C 1998 , 54 , 621 −623 . – reference: N. Chaudhury , R. J. Puddephatt , J. Organomet. Chem. 1975 , 84 , 105 −115 . – reference: C. J. Kleverlaan , D. J. Stufkens , I. P. Clark , M. W. George , H. van Willigen , A. Vlček, Jr. , J. Am. Chem. Soc. 1998 , 120 , 10871 −10879 . – reference: W. Paw , S. D. Cummings , M. A. Mansour , W. B. Connick , D. K. Geiger , R. Eisenberg , Coord. Chem. Rev. 1998 , 171 , 125 −150 . – reference: D. R. McMillin , J. J. Moore , Coord. Chem. Rev. 2002 , 229 , 113 −121 . – reference: H. C. Clark , L. E. Manzer , J. Organomet. Chem. 1973 , 59 , 411 −428 . – reference: C. Vogler , B. Schwederski , A. Klein , W. Kaim , J. Organomet. Chem. 1992 , 436 , 367 −378 . – reference: W. Kaim , A. Klein , Organometallics 1995 , 14 , 1176 −1186 . – reference: C. Fonseca Guerra , J. G. Snijders , G. te Velde , E. J. Baerends , Theor. Chim. Acta 1998 , 99 , 391 −403 . – reference: Z. Hao , Z. Tang , Q. Shi , Inorg. Chim. Acta 1999 , 284 , 112 −115 . – reference: W. Kaim , A. Klein , S. Hasenzahl , H. Stoll , S. Záliš , J. Fiedler , Organometallics 1998 , 17 , 237 −247 . – reference: E. van Lenthe , A. Ehlers , E. J. Baerends , J. Chem. Phys. 1999 , 110 , 8943 −8953 . – reference: A. D. Becke , Phys. Rev. A 1988 , 38 , 3098 −3100 . – reference: J. D. Scott , R. J. Puddephatt , Organometallics 1983 , 2 , 1643 −1648 . – reference: V. Balzani , A. Credi , M. Venturi , Coord. Chem. Rev. 1998 , 171 , 3 −16 . – reference: A. Klein , H.-D. Hausen , W. Kaim , J. Organomet. Chem. 1992 , 440 , 207 −217 . – reference: V. M. Miskowski , V. H. Houlding , C.-M. Che , Y. Wang , Inorg. Chem. 1993 , 32 , 2518 −2524 . – reference: V. H. Houlding , V. M. Miskowski , Coord. Chem. Rev. 1991 , 111 , 145 −152 . – reference: Q.-Z. Yang , L.-Z. Wu , Z.-X. Wu , L.-P. Zhang , C.-H. Tung , Inorg. Chem. 2002 , 41 , 5653 −5655 . – reference: S. Achar , V. J. Catalano , Polyhedron 1997 , 16 , 1555 −1561 . – reference: A. Klein , J. van Slageren , S. Záliš , Inorg. Chem. 2002 , 41 , 5216 −5225 . – reference: J. E. McGarrah , Y.-J. Kim , M. Hissler , R. Eisenberg , Inorg. Chem. 2001 , 40 , 4510 −4511 . – reference: A. Klein , T. Scheiring , W. Kaim , Z. Anorg. Allg. Chem. 1999 , 625 , 1177 −1180 . – reference: M. Maestri , D. Sandrini , V. Balzani , L. Chassot , P. Jolliet , A. Von Zelewsky , Chem. Phys. Lett. 1985 , 122 , 375 −379 . – reference: C. E. Whittle , J. A. Weinstein , M. W. George , K. S. Schanze , Inorg. Chem. 2001 , 40 , 4053 −4062 . – reference: M. T. Cocker , R. E. Bachman , Inorg. Chem. 2001 , 40 , 1550 −1556 . – reference: S. Ernst , C. Vogler , A. Klein , W. Kaim , Inorg. Chem. 1996 , 35 , 1295 −1300 . – reference: J. A. Bailey , M. G. Hill , R. E. Marsh , V. M. Miskowski , W. P. Schaefer , H. B. Gray , Inorg. Chem. 1995 , 34 , 4591 −4599 . – reference: L. Jacquet , J. M. Kelly , A. Kirsch-De Mesmaeker , J. Chem. Soc., Chem. Commun. 1995 , 913 −914 . – reference: M. Textor , H. R. Oswald , Z. Anorg. Allg. Chem. 1974 , 407 , 244 −256 . – reference: A. Von Zelewsky , P. Belser , P. Hayoz , R. Dux , X. Hua , A. Suckling , H. Stoeckli-Evans , Coord. Chem. Rev. 1994 , 132 , 75 −85 . – reference: A. Vogler , H. Kunkely , Comments Inorg. Chem. 1990 , 9 , 201 −220 . – reference: H. D. Stoeffler , N. B. Thornton , S. L. Temkin , K. S. Schanze , J. Am. Chem. Soc. 1995 , 117 , 7119 −7128 . – reference: E. M. Kober , J. L. Marshall , W. J. Dressick , B. P. Sullivan , J. V. Caspar , T. J. Meyer , Inorg. Chem. 1985 , 24 , 2755 −2763 . – reference: J. A. Weinstein , N. N. Zheligovskaya , M. Y. Mel′nikov , F. Hartl , J. Chem. Soc., J. Chem. Soc., Dalton Trans. 1998 , 15 , 2459 −2466 . – reference: A. Klein , J. van Slageren , S. Záliš , J. Organomet. Chem. 2001 , 620 , 202 −210 . – reference: C. Eaborn , K. Kundu , A. Pidcock , J. Chem. Soc., Dalton Trans. 1981 , 933 −938 . – reference: K. E. Dungey , B. D. Thompson , N. A. P. Kane-Maguire , L. L. Wright , Inorg. Chem. 2000 , 39 , 5192 −5196 . – reference: V. M. Miskowski , V. H. Houlding , Inorg. Chem. 1989 , 28 , 1529 −1533 . – reference: M. Hissler , W. B. Connick , D. K. Geiger , J. E. McGarrah , D. Lipa , R. J. Lachicotte , R. Eisenberg , Inorg. Chem. 2000 , 39 , 447 −457 . – reference: R. S. Osborn , D. Rogers , J. Chem. Soc., Dalton Trans. 1974 , 1002 −1004 . – reference: M. Hissler , J. E. McGarrah , W. B. Connick , D. K. Geiger , S. D. Cummings , R. Eisenberg , Coord. Chem. Rev. 2000 , 208 , 115 −137 . – reference: S. Hasenzahl , H.-D. Hausen , W. Kaim , Chem. Eur. J. 1995 , 1 , 95 −99 . – volume: 40 start-page: 4053 year: 2001 end-page: 4062 publication-title: Inorg. Chem. – volume: 41 start-page: 5653 year: 2002 end-page: 5655 publication-title: Inorg. Chem. – volume: 14 start-page: 1176 year: 1995 end-page: 1186 publication-title: Organometallics – volume: 171 start-page: 125 year: 1998 end-page: 150 publication-title: Coord. Chem. Rev. – volume: 36 start-page: 913 year: 1997 end-page: 922 publication-title: Inorg. Chem. – volume: 407 start-page: 244 year: 1974 end-page: 256 publication-title: Z. Anorg. Allg. Chem. – volume: 77 start-page: 123 year: 1990 end-page: 141 publication-title: Theor. Chim. Acta – volume: 32 start-page: 2518 year: 1993 end-page: 2524 publication-title: Inorg. Chem. – volume: 440 start-page: 207 year: 1992 end-page: 217 publication-title: J. Organomet. Chem. – volume: 17 start-page: 237 year: 1998 end-page: 247 publication-title: Organometallics – volume: 99 start-page: 391 year: 1998 end-page: 403 publication-title: Theor. Chim. Acta – volume: 15 start-page: 2459 year: 1998 end-page: 2466 publication-title: J. Chem. Soc., J. Chem. Soc., Dalton Trans. – volume: 34 start-page: 4591 year: 1995 end-page: 4599 publication-title: Inorg. Chem. – volume: 39 start-page: 447 year: 2000 end-page: 457 publication-title: Inorg. Chem. – start-page: 913 year: 1995 end-page: 914 publication-title: J. Chem. Soc., Chem. Commun. – volume: 38 start-page: 3098 year: 1988 end-page: 3100 publication-title: Phys. Rev. A – volume: 33 start-page: 8822 year: 1986 end-page: 8824 publication-title: Phys. Rev. B – volume: 54 start-page: 621 year: 1998 end-page: 623 publication-title: Acta Crystallogr., Sect. C – volume: 132 start-page: 75 year: 1994 end-page: 85 publication-title: Coord. Chem. Rev. – volume: 23 start-page: 377 year: 1984 end-page: 379 publication-title: Inorg. Chem. – volume: 9 start-page: 201 year: 1990 end-page: 220 publication-title: Comments Inorg. Chem. – volume: 48 start-page: 1776 year: 1992 end-page: 1778 publication-title: Acta Crystallogr., Sect. C – volume: 118 start-page: 119 year: 1999 end-page: 138 publication-title: Comput. Phys. Commun. – volume: 120 start-page: 10871 year: 1998 end-page: 10879 publication-title: J. Am. Chem. Soc. – volume: 2 start-page: 1643 year: 1983 end-page: 1648 publication-title: Organometallics – volume: 35 start-page: 1295 year: 1996 end-page: 1300 publication-title: Inorg. Chem. – volume: 436 start-page: 367 year: 1992 end-page: 378 publication-title: J. Organomet. Chem. – volume: 24 start-page: 2755 year: 1985 end-page: 2763 publication-title: Inorg. Chem. – start-page: 609 year: 1998 end-page: 616 publication-title: J. Chem. Soc., J. Chem. Soc., Dalton Trans. – volume: 110 start-page: 8943 year: 1999 end-page: 8953 publication-title: J. Chem. Phys. – volume: 84 start-page: 105 year: 1975 end-page: 115 publication-title: J. Organomet. Chem. – volume: 114 start-page: 5919 year: 1992 end-page: 5925 publication-title: J. Am. Chem. Soc. – volume: 15 start-page: 236 year: 1996 end-page: 244 publication-title: Organometallics – volume: 29 start-page: 1884 year: 1990 end-page: 1888 publication-title: Inorg. Chem. – volume: 40 start-page: 4510 year: 2001 end-page: 4511 publication-title: Inorg. Chem. – volume: 171 start-page: 3 year: 1998 end-page: 16 publication-title: Coord. Chem. Rev. – start-page: 1002 year: 1974 end-page: 1004 publication-title: J. Chem. Soc., Dalton Trans. – volume: 132 start-page: 87 year: 1994 end-page: 97 publication-title: Coord. Chem. Rev. – start-page: 933 year: 1981 end-page: 938 publication-title: J. Chem. Soc., Dalton Trans. – volume: 16 start-page: 1555 year: 1997 end-page: 1561 publication-title: Polyhedron – start-page: 2371 year: 2002 end-page: 2378 publication-title: J. Chem. Soc., Dalton Trans. – volume: 117 start-page: 7119 year: 1995 end-page: 7128 publication-title: J. Am. Chem. Soc. – volume: 122 start-page: 375 year: 1985 end-page: 379 publication-title: Chem. Phys. Lett. – volume: 111 start-page: 145 year: 1991 end-page: 152 publication-title: Coord. Chem. Rev. – volume: 98 start-page: 1358 year: 1993 end-page: 1371 publication-title: J. Chem. Phys. – volume: 38 start-page: 3264 year: 1999 end-page: 3265 publication-title: Inorg. Chem. – volume: 41 start-page: 5216 year: 2002 end-page: 5225 publication-title: Inorg. Chem. – volume: 38 start-page: 174 year: 1999 end-page: 189 publication-title: Inorg. Chem. – volume: 18 start-page: 721 year: 1994 end-page: 729 publication-title: New J. Chem. – volume: 315 start-page: 44 year: 2001 end-page: 52 publication-title: Inorg. Chim. Acta – volume: 229 start-page: 113 year: 2002 end-page: 121 publication-title: Coord. Chem. Rev. – volume: 40 start-page: 2193 year: 2001 end-page: 2200 publication-title: Inorg. Chem. – volume: 620 start-page: 202 year: 2001 end-page: 210 publication-title: J. Organomet. Chem. – volume: 20 start-page: 2477 year: 2001 end-page: 2486 publication-title: Organometallics – volume: 20 start-page: 781 year: 1996 end-page: 789 publication-title: New J. Chem. – volume: 284 start-page: 112 year: 1999 end-page: 115 publication-title: Inorg. Chim. Acta – volume: 1 start-page: 95 year: 1995 end-page: 99 publication-title: Chem. Eur. J. – volume: 98 start-page: 11623 year: 1994 end-page: 11627 publication-title: J. Phys. Chem. – volume: 40 start-page: 1550 year: 2001 end-page: 1556 publication-title: Inorg. Chem. – volume: 30 start-page: 4446 year: 1991 end-page: 4452 publication-title: Inorg. Chem. – volume: 28 start-page: 1529 year: 1989 end-page: 1533 publication-title: Inorg. Chem. – start-page: 218 year: 2002 end-page: 225 publication-title: J. Chem. Soc., Dalton Trans. – volume: 208 start-page: 115 year: 2000 end-page: 137 publication-title: Coord. Chem. Rev. – volume: 39 start-page: 2585 year: 2000 end-page: 2592 publication-title: Inorg. Chem. – start-page: 2121 year: 1995 end-page: 2126 publication-title: J. Chem. Soc., Perkin Trans. 2 – volume: 39 start-page: 5192 year: 2000 end-page: 5196 publication-title: Inorg. Chem. – volume: 625 start-page: 1177 year: 1999 end-page: 1180 publication-title: Z. Anorg. Allg. Chem. – volume: 59 start-page: 411 year: 1973 end-page: 428 publication-title: J. Organomet. Chem. |
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| SubjectTerms | Crystal structure DFT Emission N ligands Optical spectroscopy Photophysics Platinum Theoretical calculations |
| Title | Co-Ligand Involvement in Ground and Excited States of Electron-Rich (Polypyridyl)PtII Complexes |
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