A Switchable Domino Process for the Construction of Novel CO2‐Sourced Sulfur‐Containing Building Blocks and Polymers

α‐Alkylidene cyclic carbonates (αCCs) recently emerged as attractive CO2‐sourced synthons for the construction of complex organic molecules. Herein, we report the transformation of αCCs into novel families of sulfur‐containing compounds by organocatalyzed chemoselective addition of thiols, following...

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Veröffentlicht in:	Angewandte Chemie International Edition Jg. 58; H. 34; S. 11768 - 11773
Hauptverfasser:	Ouhib, Farid, Grignard, Bruno, Van Den Broeck, Elias, Luxen, André, Robeyns, Koen, Van Speybroeck, Veronique, Jerome, Christine, Detrembleur, Christophe
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	WEINHEIM Wiley 19.08.2019 Wiley Subscription Services, Inc
Ausgabe:	International ed. in English
Schlagworte:	Alkylidene Atom economy Carbon dioxide Carbonates Chemistry Chemistry, Multidisciplinary Chimie Construction cyclic carbonate domino process Engineering, computing & technology Ingénierie, informatique & technologie Materials science & engineering Organic chemistry organocatalysis Physical Sciences Physical, chemical, mathematical & earth Sciences Physique, chimie, mathématiques & sciences de la terre polymerization Polymers Science & Technology Science des matériaux & ingénierie step-growth polymerization Substrates Sulfur supercritical carbon dioxide synthetic methods Thiols TRANSFORMATION carbon dioxide polymerization domino process DIOXIDE CO2 EFFICIENT SYNTHESIS HIGH REFRACTIVE-INDEX CATALYST organocatalysis PROPARGYLIC ALCOHOLS ALKYLIDENE CYCLIC CARBONATES SELECTIVE SYNTHESIS COPOLYMERIZATION synthetic methods
ISSN:	1433-7851, 1521-3773, 1521-3773
Online-Zugang:	Volltext
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