Unravelling the Redox‐catalytic Behavior of Ce4+ Metal–Organic Frameworks by X‐ray Absorption Spectroscopy

The introduction of Ce4+ as a structural cation has been shown to be a promising route to redox active metal–organic frameworks (MOFs). However, the mechanism by which these MOFs act as redox catalysts remains unclear. Herein, we present a detailed study of the active site in [Ce6O4(OH)4]‐based MOFs...

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Bibliographic Details

Published in:	Chemphyschem Vol. 19; no. 4; pp. 373 - 378
Main Authors:	Smolders, Simon, Lomachenko, Kirill A., Bueken, Bart, Struyf, Arnaud, Bugaev, Aram L., Atzori, Cesare, Stock, Norbert, Lamberti, Carlo, Roeffaers, Maarten B. J., De Vos, Dirk E.
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 19.02.2018
Subjects:	Absorption spectroscopy Alcohol Benzyl alcohol Catalysis Cations cerium Metal-organic frameworks Oxidation redox chemistry Spectrum analysis Structural integrity X ray powder diffraction X-ray spectroscopy X-rays
ISSN:	1439-4235, 1439-7641, 1439-7641
Online Access:	Get full text
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