Mechanisms of catalytic dehydrogenation of alkanes by rhodium clusters Rh n + probed by isotope labelling

The regioselectivity for the dehydrogenation of alkanes by rhodium clusters was investigated by reacting Rh n +, n = 1–20, with the isotopically labelled alkanes ethane-1,1,1- d 3 and propane-1,1,1,3,3,3- d 6. For Rh + reacting with propane a clear preference for a 1,2- over a 1,1- and 1,3-mechanism...

Full description

Saved in:

Bibliographic Details
Published in:	International journal of mass spectrometry Vol. 249; pp. 191 - 198
Main Authors:	Adlhart, Christian, Uggerud, Einar
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 01.03.2006
Subjects:	Catalysis Deuterium labelling Ion molecule reaction Isotope effect Metal cluster Nanotechnology Reaction mechanism Rhodium cluster Ion molecule reaction Metal cluster Deuterium labelling Isotope effect Rhodium cluster Reaction mechanism Catalysis Nanotechnology
ISSN:	1387-3806, 1873-2798
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Be the first to leave a comment!