Cover Feature: Facile Synthesis and Characterization of Pure Tochilinite‐like Materials from Nanoparticulate FeS (Z. Anorg. Allg. Chem. 23/2022)

The cover picture shows that pure tochilinite‐like samples can be prepared from nanoparticulate FeS with mackinawite structure under mild hydrothermal conditions. The samples have been characterized by various methods including Mössbauer spectroscopy. TEM and SEM revealed the tochilinite analogues t...

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Bibliographic Details
Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 648; no. 23
Main Authors: Bolney, Robert, Grosch, Mario, Winkler, Mario, Slageren, Joris, Weigand, Wolfgang, Robl, Christian
Format: Journal Article
Language:English
Published: 13.12.2022
Subjects:
carbonaceous chondrites
iron sulfide
Layered hybrid materials
nanotubes
Tochilinite
ISSN:0044-2313, 1521-3749
Online Access:Get full text
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Summary:The cover picture shows that pure tochilinite‐like samples can be prepared from nanoparticulate FeS with mackinawite structure under mild hydrothermal conditions. The samples have been characterized by various methods including Mössbauer spectroscopy. TEM and SEM revealed the tochilinite analogues to consist mainly of thin sheets accompanied by nanotubes. The following compositions could be determined: Fe0.76S*0.86[Fe2+0.01Fe3+0.56Mg2+0.43(OH)2.01], Fe0.89S*0.85[Fe2+0.55Fe3+0.11Al3+0.33(OH)1.84(O)0.16], and Fe0.71S*0.79[Fe2+0.25Fe3+0.73Mg2+0.01Al3+0.01(OH)1.98(O)0.02]. More details are discussed in the article by R. Bolney, M. Grosch, M. Winkler, J. van Slageren, W. Weigand, and C. Robl (DOI: 10.1002/zaac.202200219).
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.202200354