Iron-Catalyzed Direct Diazidation for a Broad Range of Olefins

Reported herein is a new iron‐catalyzed diastereoselective olefin diazidation reaction which occurs at room temperature (1–5 mol % of catalysts and d.r. values of up to >20:1). This method tolerates a broad range of both unfunctionalized and highly functionalized olefins, including those that are...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 55; no. 2; pp. 534 - 538
Main Authors:	Yuan, Yong-An, Lu, Deng-Fu, Chen, Yun-Rong, Xu, Hao
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 11.01.2016 WILEY‐VCH Verlag Wiley Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	Alkenes Alkenes - chemistry amination Azides - chemistry Catalysis Catalysts Chemistry Chemistry, Multidisciplinary Diamines homogeneous catalysis Iron Iron - chemistry Lewis acid Physical Sciences Science & Technology synthetic methods Temperature effects ALKENE DIAMINATION CONVENIENT ACCESS INTRAMOLECULAR AMINOHYDROXYLATION CONJUGATED DIENES alkenes BOND-CLEAVAGE homogeneous catalysis HYPERVALENT IODINE AZIDATION CHEMISTRY iron FUNCTIONALIZED HYDROXYLAMINES amination synthetic methods ALKYL AZIDES
ISSN:	1433-7851, 1521-3773
Online Access:	Get full text
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