A Synthesis of Exiguaquinol Dessulfate

A concise and stereoselective synthesis of exiguaquinol dessulfate is described. Sequential application of a Diels–Alder cycloaddition, a desymmetrizing aldol addition, and a reductive Heck cyclization established most of the architecture of exiguaquinol, and a carefully choreographed introduction o...

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Vydáno v:	Chemistry : a European journal Ročník 22; číslo 50; s. 17953 - 17957
Hlavní autoři:	Schwarzwalder, Gregg M., Scott, David R., Vanderwal, Christopher D.
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	WEINHEIM Blackwell Publishing Ltd 12.12.2016 Wiley Wiley Subscription Services, Inc
Témata:	Aldehydes Aldehydes - chemistry antibiotics Architecture Chemistry Chemistry, Multidisciplinary Congeners Culture Cyclization Cycloaddition Reaction epimers Forges Heck cyclization Hydrogen bonding Hydroquinones - chemical synthesis Hydroquinones - chemistry Molecular Structure natural product synthesis Physical Sciences Science & Technology Strategy sulfation Synthesis CORE SELECTIVE ANTIBACTERIAL AGENTS PYLORI GLUTAMATE RACEMASE natural product synthesis MARINE SPONGE 3,6-DIMETHOXYBENZOCYCLOBUTENONE PYRIDODIAZEPINE AMINES GASTRIC-CANCER Heck cyclization epimers sulfation INHIBITORS antibiotics HELICOBACTER-PYLORI ALKALOID JAMTINE
ISSN:	0947-6539, 1521-3765, 1521-3765
On-line přístup:	Získat plný text
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