The crystalline sponge method updated
Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal...
Saved in:
| Published in: | IUCrJ Vol. 3; no. 2; pp. 139 - 151 |
|---|---|
| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
England
International Union of Crystallography
01.03.2016
|
| Subjects: | |
| ISSN: | 2052-2525, 2052-2525 |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal preparation, pore–solvent exchange, guest soaking, data collection and crystallographic analysis, are carefully examined and thoroughly optimized to provide reliable and meaningful chemical information as chemical crystallography. Major improvements in the method have been made in the guest-soaking and data-collection steps. In the soaking step, obtaining a high site occupancy of the guest is particularly important, and dominant parameters for guest soaking (
e.g.
temperature, time, concentration, solvents) therefore have to be optimized for every sample compound. When standard conditions do not work, a high-throughput method is useful for efficiently optimizing the soaking conditions. The X-ray experiments are also carefully re-examined. Significant improvement of the guest data quality is achieved by complete data collection at high angle regions. The appropriate disorder treatment of the most flexible ZnI
2
portions of the host framework and refinement of the solvents filling the remaining void are also particularly important for obtaining better data quality. A benchmark test for the crystalline sponge method toward an achiral molecule is proposed with a guaiazulene guest, in which the guest structure (with ∼ 100% site occupancy) is refined without applying any restraints or constraints. The obtained data quality with
R
int
= 0.0279 and
R
1
= 0.0379 is comparable with that of current conventional crystallographic analysis for small molecules. Another benchmark test for this method toward a chiral molecule is also proposed with a santonin guest. The crystallographic data obtained [
R
int
= 0.0421,
R
1
= 0.0312, Flack (Parsons) = −0.0071 (11)] represents the potential ability of this method for reliable absolute structure determination. |
|---|---|
| AbstractList | Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal preparation, pore-solvent exchange, guest soaking, data collection and crystallographic analysis, are carefully examined and thoroughly optimized to provide reliable and meaningful chemical information as chemical crystallography. Major improvements in the method have been made in the guest-soaking and data-collection steps. In the soaking step, obtaining a high site occupancy of the guest is particularly important, and dominant parameters for guest soaking (e.g. temperature, time, concentration, solvents) therefore have to be optimized for every sample compound. When standard conditions do not work, a high-throughput method is useful for efficiently optimizing the soaking conditions. The X-ray experiments are also carefully re-examined. Significant improvement of the guest data quality is achieved by complete data collection at high angle regions. The appropriate disorder treatment of the most flexible ZnI2 portions of the host framework and refinement of the solvents filling the remaining void are also particularly important for obtaining better data quality. A benchmark test for the crystalline sponge method toward an achiral molecule is proposed with a guaiazulene guest, in which the guest structure (with ∼ 100% site occupancy) is refined without applying any restraints or constraints. The obtained data quality with R int = 0.0279 and R 1 = 0.0379 is comparable with that of current conventional crystallographic analysis for small molecules. Another benchmark test for this method toward a chiral molecule is also proposed with a santonin guest. The crystallographic data obtained [R int = 0.0421, R 1 = 0.0312, Flack (Parsons) = -0.0071 (11)] represents the potential ability of this method for reliable absolute structure determination. Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal preparation, pore-solvent exchange, guest soaking, data collection and crystallographic analysis, are carefully examined and thoroughly optimized to provide reliable and meaningful chemical information as chemical crystallography. Major improvements in the method have been made in the guest-soaking and data-collection steps. In the soaking step, obtaining a high site occupancy of the guest is particularly important, and dominant parameters for guest soaking (e.g. temperature, time, concentration, solvents) therefore have to be optimized for every sample compound. When standard conditions do not work, a high-throughput method is useful for efficiently optimizing the soaking conditions. The X-ray experiments are also carefully re-examined. Significant improvement of the guest data quality is achieved by complete data collection at high angle regions. The appropriate disorder treatment of the most flexible ZnI sub(2) portions of the host framework and refinement of the solvents filling the remaining void are also particularly important for obtaining better data quality. A benchmark test for the crystalline sponge method toward an achiral molecule is proposed with a guaiazulene guest, in which the guest structure (with similar to 100% site occupancy) is refined without applying any restraints or constraints. The obtained data quality with R sub(int) = 0.0279 and R sub(1) = 0.0379 is comparable with that of current conventional crystallographic analysis for small molecules. Another benchmark test for this method toward a chiral molecule is also proposed with a santonin guest. The crystallographic data obtained [R sub(int) = 0.0421, R sub(1) = 0.0312, Flack (Parsons) = -0.0071(11)] represents the potential ability of this method for reliable absolute structure determination. Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal preparation, pore-solvent exchange, guest soaking, data collection and crystallographic analysis, are carefully examined and thoroughly optimized to provide reliable and meaningful chemical information as chemical crystallography. Major improvements in the method have been made in the guest-soaking and data-collection steps. In the soaking step, obtaining a high site occupancy of the guest is particularly important, and dominant parameters for guest soaking (e.g. temperature, time, concentration, solvents) therefore have to be optimized for every sample compound. When standard conditions do not work, a high-throughput method is useful for efficiently optimizing the soaking conditions. The X-ray experiments are also carefully re-examined. Significant improvement of the guest data quality is achieved by complete data collection at high angle regions. The appropriate disorder treatment of the most flexible Zn[I.sub.2] portions of the host framework and refinement of the solvents filling the remaining void are also particularly important for obtaining better data quality. A benchmark test for the crystalline sponge method toward an achiral molecule is proposed with a guaiazulene guest, in which the guest structure (with ~ 100% site occupancy) is refined without applying any restraints or constraints. The obtained data quality with [R.sub.int] = 0.0279 and [R.sub.1] = 0.0379 is comparable with that of current conventional crystallographic analysis for small molecules. Another benchmark test for this method toward a chiral molecule is also proposed with a santonin guest. The crystallographic data obtained [[R.sub.int] = 0.0421, [R.sub.1] = 0.0312, Flack (Parsons) = -0.0071 (11)] represents the potential ability of this method for reliable absolute structure determination. Keywords: crystalline sponge method; porous materials; metal-organic frameworks; chemical crystallography. Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal preparation, pore-solvent exchange, guest soaking, data collection and crystallographic analysis, are carefully examined and thoroughly optimized to provide reliable and meaningful chemical information as chemical crystallography. Major improvements in the method have been made in the guest-soaking and data-collection steps. In the soaking step, obtaining a high site occupancy of the guest is particularly important, and dominant parameters for guest soaking (e.g. temperature, time, concentration, solvents) therefore have to be optimized for every sample compound. When standard conditions do not work, a high-throughput method is useful for efficiently optimizing the soaking conditions. The X-ray experiments are also carefully re-examined. Significant improvement of the guest data quality is achieved by complete data collection at high angle regions. The appropriate disorder treatment of the most flexible ZnI2 portions of the host framework and refinement of the solvents filling the remaining void are also particularly important for obtaining better data quality. A benchmark test for the crystalline sponge method toward an achiral molecule is proposed with a guaiazulene guest, in which the guest structure (with ∼ 100% site occupancy) is refined without applying any restraints or constraints. The obtained data quality with R int = 0.0279 and R 1 = 0.0379 is comparable with that of current conventional crystallographic analysis for small molecules. Another benchmark test for this method toward a chiral molecule is also proposed with a santonin guest. The crystallographic data obtained [R int = 0.0421, R 1 = 0.0312, Flack (Parsons) = -0.0071 (11)] represents the potential ability of this method for reliable absolute structure determination.Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal preparation, pore-solvent exchange, guest soaking, data collection and crystallographic analysis, are carefully examined and thoroughly optimized to provide reliable and meaningful chemical information as chemical crystallography. Major improvements in the method have been made in the guest-soaking and data-collection steps. In the soaking step, obtaining a high site occupancy of the guest is particularly important, and dominant parameters for guest soaking (e.g. temperature, time, concentration, solvents) therefore have to be optimized for every sample compound. When standard conditions do not work, a high-throughput method is useful for efficiently optimizing the soaking conditions. The X-ray experiments are also carefully re-examined. Significant improvement of the guest data quality is achieved by complete data collection at high angle regions. The appropriate disorder treatment of the most flexible ZnI2 portions of the host framework and refinement of the solvents filling the remaining void are also particularly important for obtaining better data quality. A benchmark test for the crystalline sponge method toward an achiral molecule is proposed with a guaiazulene guest, in which the guest structure (with ∼ 100% site occupancy) is refined without applying any restraints or constraints. The obtained data quality with R int = 0.0279 and R 1 = 0.0379 is comparable with that of current conventional crystallographic analysis for small molecules. Another benchmark test for this method toward a chiral molecule is also proposed with a santonin guest. The crystallographic data obtained [R int = 0.0421, R 1 = 0.0312, Flack (Parsons) = -0.0071 (11)] represents the potential ability of this method for reliable absolute structure determination. The protocols of the crystalline sponge method, particularly those in the soaking, data collection and refinement processes, are considerably improved to give reliable structural information. Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal preparation, pore–solvent exchange, guest soaking, data collection and crystallographic analysis, are carefully examined and thoroughly optimized to provide reliable and meaningful chemical information as chemical crystallography. Major improvements in the method have been made in the guest-soaking and data-collection steps. In the soaking step, obtaining a high site occupancy of the guest is particularly important, and dominant parameters for guest soaking (e.g. temperature, time, concentration, solvents) therefore have to be optimized for every sample compound. When standard conditions do not work, a high-throughput method is useful for efficiently optimizing the soaking conditions. The X-ray experiments are also carefully re-examined. Significant improvement of the guest data quality is achieved by complete data collection at high angle regions. The appropriate disorder treatment of the most flexible ZnI2 portions of the host framework and refinement of the solvents filling the remaining void are also particularly important for obtaining better data quality. A benchmark test for the crystalline sponge method toward an achiral molecule is proposed with a guaiazulene guest, in which the guest structure (with ∼ 100% site occupancy) is refined without applying any restraints or constraints. The obtained data quality with R int = 0.0279 and R 1 = 0.0379 is comparable with that of current conventional crystallographic analysis for small molecules. Another benchmark test for this method toward a chiral molecule is also proposed with a santonin guest. The crystallographic data obtained [R int = 0.0421, R 1 = 0.0312, Flack (Parsons) = −0.0071 (11)] represents the potential ability of this method for reliable absolute structure determination. Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal preparation, pore–solvent exchange, guest soaking, data collection and crystallographic analysis, are carefully examined and thoroughly optimized to provide reliable and meaningful chemical information as chemical crystallography. Major improvements in the method have been made in the guest-soaking and data-collection steps. In the soaking step, obtaining a high site occupancy of the guest is particularly important, and dominant parameters for guest soaking ( e.g. temperature, time, concentration, solvents) therefore have to be optimized for every sample compound. When standard conditions do not work, a high-throughput method is useful for efficiently optimizing the soaking conditions. The X-ray experiments are also carefully re-examined. Significant improvement of the guest data quality is achieved by complete data collection at high angle regions. The appropriate disorder treatment of the most flexible ZnI 2 portions of the host framework and refinement of the solvents filling the remaining void are also particularly important for obtaining better data quality. A benchmark test for the crystalline sponge method toward an achiral molecule is proposed with a guaiazulene guest, in which the guest structure (with ∼ 100% site occupancy) is refined without applying any restraints or constraints. The obtained data quality with R int = 0.0279 and R 1 = 0.0379 is comparable with that of current conventional crystallographic analysis for small molecules. Another benchmark test for this method toward a chiral molecule is also proposed with a santonin guest. The crystallographic data obtained [ R int = 0.0421, R 1 = 0.0312, Flack (Parsons) = −0.0071 (11)] represents the potential ability of this method for reliable absolute structure determination. Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal preparation, pore–solvent exchange, guest soaking, data collection and crystallographic analysis, are carefully examined and thoroughly optimized to provide reliable and meaningful chemical information as chemical crystallography. Major improvements in the method have been made in the guest-soaking and data-collection steps. In the soaking step, obtaining a high site occupancy of the guest is particularly important, and dominant parameters for guest soaking (e.g. temperature, time, concentration, solvents) therefore have to be optimized for every sample compound. When standard conditions do not work, a high-throughput method is useful for efficiently optimizing the soaking conditions. The X-ray experiments are also carefully re-examined. Significant improvement of the guest data quality is achieved by complete data collection at high angle regions. The appropriate disorder treatment of the most flexible ZnI2 portions of the host framework and refinement of the solvents filling the remaining void are also particularly important for obtaining better data quality. A benchmark test for the crystalline sponge method toward an achiral molecule is proposed with a guaiazulene guest, in which the guest structure (with ∼ 100% site occupancy) is refined without applying any restraints or constraints. The obtained data quality with Rint = 0.0279 and R1 = 0.0379 is comparable with that of current conventional crystallographic analysis for small molecules. Another benchmark test for this method toward a chiral molecule is also proposed with a santonin guest. The crystallographic data obtained [Rint = 0.0421, R1 = 0.0312, Flack (Parsons) = −0.0071 (11)] represents the potential ability of this method for reliable absolute structure determination. Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional X-ray structure analysis (crystalline sponge method). In this study, all of the steps in the crystalline sponge method, including sponge crystal preparation, pore-solvent exchange, guest soaking, data collection and crystallographic analysis, are carefully examined and thoroughly optimized to provide reliable and meaningful chemical information as chemical crystallography. Major improvements in the method have been made in the guest-soaking and data-collection steps. In the soaking step, obtaining a high site occupancy of the guest is particularly important, and dominant parameters for guest soaking (e.g. temperature, time, concentration, solvents) therefore have to be optimized for every sample compound. When standard conditions do not work, a high-throughput method is useful for efficiently optimizing the soaking conditions. The X-ray experiments are also carefully re-examined. Significant improvement of the guest data quality is achieved by complete data collection at high angle regions. The appropriate disorder treatment of the most flexible ZnI2 portions of the host framework and refinement of the solvents filling the remaining void are also particularly important for obtaining better data quality. A benchmark test for the crystalline sponge method toward an achiral molecule is proposed with a guaiazulene guest, in which the guest structure (with ∼ 100% site occupancy) is refined without applying any restraints or constraints. The obtained data quality with Rint = 0.0279 and R1 = 0.0379 is comparable with that of current conventional crystallographic analysis for small molecules. Another benchmark test for this method toward a chiral molecule is also proposed with a santonin guest. The crystallographic data obtained [Rint = 0.0421, R1 = 0.0312, Flack (Parsons) = -0.0071 (11)] represents the potential ability of this method for reliable absolute structure determination. |
| Audience | Academic |
| Author | Khutia, Anupam Inokuma, Yasuhide Xing, Hongzhu Fujita, Makoto Hoshino, Manabu |
| Author_xml | – sequence: 1 givenname: Manabu surname: Hoshino fullname: Hoshino, Manabu – sequence: 2 givenname: Anupam surname: Khutia fullname: Khutia, Anupam – sequence: 3 givenname: Hongzhu surname: Xing fullname: Xing, Hongzhu – sequence: 4 givenname: Yasuhide surname: Inokuma fullname: Inokuma, Yasuhide – sequence: 5 givenname: Makoto surname: Fujita fullname: Fujita, Makoto |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/27006777$$D View this record in MEDLINE/PubMed |
| BookMark | eNqFkltr3DAQhUVJaS7ND-hLWSiFvmwiybrYL4UQegkE-pD0WcjSeFeLLW0lO5B_33E3CblAih9kjr45zBzNIdmLKQIhHxg9YYzq0ytOJeeSSyYpF5Vu3pCDWVrO2t6j_31yXMqGUsoYl1qwd2Sfa0qV1vqAfL5ew8Ll2zLavg8RFmWb4goWA4zr5BfT1tsR_HvytrN9geO784j8_v7t-vzn8vLXj4vzs8ulUxUbl563ToBiWnZCaK94a6n0VFPPqwpapj1zDatrRKzSnbdtK-oKFHXAKkDoiFzsfH2yG7PNYbD51iQbzD8h5ZWxeQyuB9PJFidn7ewjLBeN7KRralEpy7nuJHp93Xltp3YA7yCO2fZPTJ_exLA2q3RjhNaSqbmZL3cGOf2ZoIxmCMVB39sIaSqG1UpIRWWj_o-iJSaEoSP66Rm6SVOOmCpSSjQYnpibP9lRK4uzhtglbNHh52EIDhehC6ifCeQbLbTAgo-Pp30Y8_6lEWA7wOVUSobuAWHUzAtlXiwU1uhnNS6MdgxpDiz0r1T-Be7NylU |
| CitedBy_id | crossref_primary_10_1002_sstr_202400300 crossref_primary_10_3390_molecules27228055 crossref_primary_10_1002_ange_202011171 crossref_primary_10_1016_j_tet_2018_07_038 crossref_primary_10_1002_anie_201601448 crossref_primary_10_1002_ange_202106265 crossref_primary_10_1107_S2052252522002147 crossref_primary_10_1021_jacs_7b09452 crossref_primary_10_3390_cryst8010018 crossref_primary_10_1002_ange_201509761 crossref_primary_10_1002_anie_202102559 crossref_primary_10_1107_S2052252524004871 crossref_primary_10_1039_D0SC05526C crossref_primary_10_1021_jacs_8b01775 crossref_primary_10_1007_s11426_025_2778_y crossref_primary_10_1039_D1SC04887B crossref_primary_10_1016_j_ccr_2022_214840 crossref_primary_10_1126_science_aaf9135 crossref_primary_10_1016_j_ccr_2021_213928 crossref_primary_10_1016_j_molstruc_2022_132819 crossref_primary_10_1039_D5RA00170F crossref_primary_10_1146_annurev_biochem_013118_110744 crossref_primary_10_1016_j_chempr_2020_04_009 crossref_primary_10_1002_ange_202007731 crossref_primary_10_1007_s13361_019_02276_6 crossref_primary_10_1002_tcr_202000173 crossref_primary_10_1039_D4QI02919D crossref_primary_10_1016_j_forc_2023_100480 crossref_primary_10_1016_j_tetlet_2016_09_017 crossref_primary_10_1515_cppm_2024_0001 crossref_primary_10_1002_ange_201712683 crossref_primary_10_1002_ange_201813215 crossref_primary_10_1002_anie_202106265 crossref_primary_10_1016_j_jssc_2022_123519 crossref_primary_10_1002_chem_202001466 crossref_primary_10_1002_chem_202400512 crossref_primary_10_1039_D1SC02497C crossref_primary_10_1016_j_chroma_2016_10_072 crossref_primary_10_1021_jacs_7b12894 crossref_primary_10_1002_ange_201916269 crossref_primary_10_1002_ange_202305122 crossref_primary_10_1107_S2059798321001078 crossref_primary_10_1039_D1SC04272F crossref_primary_10_1246_cl_180082 crossref_primary_10_1016_j_tetasy_2017_09_002 crossref_primary_10_1038_s41467_019_12453_6 crossref_primary_10_1002_ange_201509801 crossref_primary_10_1002_anie_201712683 crossref_primary_10_1021_jacs_8b00821 crossref_primary_10_1039_D3SC02995F crossref_primary_10_1021_jacs_2c04261 crossref_primary_10_1002_anie_201813215 crossref_primary_10_3390_cryst14100873 crossref_primary_10_1002_chem_201704163 crossref_primary_10_1039_D4NP00071D crossref_primary_10_1124_dmd_120_091140 crossref_primary_10_1002_chem_202400501 crossref_primary_10_1002_chem_202103339 crossref_primary_10_1107_S2053229623007519 crossref_primary_10_1002_chem_201806432 crossref_primary_10_1002_anie_201509801 crossref_primary_10_1002_anie_201509761 crossref_primary_10_1016_j_trac_2018_02_014 crossref_primary_10_1002_anie_201916269 crossref_primary_10_1021_jacs_8b02839 crossref_primary_10_1002_chem_201905499 crossref_primary_10_1002_anie_202305122 crossref_primary_10_1016_j_molstruc_2021_132054 crossref_primary_10_1016_j_ccr_2025_216712 crossref_primary_10_1039_C7CS00090A crossref_primary_10_1002_anie_202006438 crossref_primary_10_1016_j_ccr_2024_216035 crossref_primary_10_1039_D4CE00699B crossref_primary_10_1016_j_matpr_2022_01_018 crossref_primary_10_3390_molecules22020211 crossref_primary_10_1002_chem_202402958 crossref_primary_10_1021_jacs_5c06360 crossref_primary_10_1039_C7AN01906H crossref_primary_10_1016_j_phytochem_2023_113708 crossref_primary_10_1080_08927022_2019_1648809 crossref_primary_10_1039_C7CC03199H crossref_primary_10_1002_adma_202107212 crossref_primary_10_1002_chem_201904174 crossref_primary_10_1016_j_ccr_2022_214921 crossref_primary_10_1002_anie_202011171 crossref_primary_10_1016_j_sbi_2019_12_008 crossref_primary_10_1016_j_ccr_2017_01_009 crossref_primary_10_1002_ange_201601448 crossref_primary_10_1039_D1ME00055A crossref_primary_10_1039_C6CC07377H crossref_primary_10_1002_cplu_202000206 crossref_primary_10_1016_j_chroma_2019_460420 crossref_primary_10_1016_j_chempr_2022_10_016 crossref_primary_10_1002_ange_202501025 crossref_primary_10_1021_jacs_7b06607 crossref_primary_10_1002_chem_202400957 crossref_primary_10_1107_S205225252401217X crossref_primary_10_1039_d0pp00267d crossref_primary_10_1124_dmd_121_000663 crossref_primary_10_2116_analsci_20SAR07 crossref_primary_10_1021_acs_molpharmaceut_5c00204 crossref_primary_10_1002_chem_201701099 crossref_primary_10_1002_ange_202006438 crossref_primary_10_3390_ma15051852 crossref_primary_10_3389_fmolb_2021_821927 crossref_primary_10_1002_anie_201713219 crossref_primary_10_1038_s41598_019_51017_y crossref_primary_10_1039_D0SC03925J crossref_primary_10_1002_anie_202007731 crossref_primary_10_1038_s41467_022_32891_z crossref_primary_10_1093_nar_gkac1058 crossref_primary_10_1002_anie_202501025 crossref_primary_10_1002_chem_202501167 crossref_primary_10_1016_j_chempr_2017_07_004 crossref_primary_10_1016_j_fitote_2019_02_010 crossref_primary_10_1021_acs_jchemed_3c00714 crossref_primary_10_1021_jacs_6b05817 crossref_primary_10_1039_d0pp00002g crossref_primary_10_1002_ange_201713219 crossref_primary_10_1002_chem_201904708 crossref_primary_10_1002_chem_202002504 crossref_primary_10_1039_D0SC00485E crossref_primary_10_1039_C6CS00533K crossref_primary_10_1002_ange_202102559 |
| Cites_doi | 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z 10.1038/nature11990 10.1039/C5SC01681A 10.1002/anie.201502302 10.1002/anie.201407948 10.1039/b508135c 10.1021/ja00082a055 10.1246/cl.1997.1219 10.1002/anie.201310897 10.1021/ja00146a033 10.1021/ja046478a 10.1021/ja017560y 10.1021/ja00197a079 10.1002/jps.20578 10.1002/1521-3773(20020916)41:18<3392::AID-ANIE3392>3.0.CO;2-V 10.1107/S2052519213010014 10.1107/S1600576715001132 10.1038/nchem.742 10.1107/S0021889807029238 10.1002/anie.200805340 10.1021/ol402563v 10.1039/C5CC03840E 10.1039/C5SC01838B 10.1107/S2053273314026370 10.1107/S0108767307043930 10.1107/S2053229614024929 10.1002/anie.200462201 10.1021/jacs.5b04407 10.1002/anie.200700534 10.1107/S0021889810018601 10.1002/anie.199717251 10.1021/ja01609a076 10.1021/ja209422m 10.1002/1521-3773(20020916)41:18<3395::AID-ANIE3395>3.0.CO;2-D 10.1039/C4CS90059F 10.1002/(SICI)1521-3773(19981204)37:22<3142::AID-ANIE3142>3.0.CO;2-9 10.1002/anie.200704809 10.1093/acprof:oso/9780199219469.003.0003 10.1038/nchem.2044 10.1021/ja504269m 10.1002/anie.199521271 10.1107/S2053273314019573 10.1016/j.ccr.2007.07.022 10.1126/science.1175441 10.1007/BFb0003836 10.1021/ja2030273 |
| ContentType | Journal Article |
| Copyright | COPYRIGHT 2016 International Union of Crystallography Copyright International Union of Crystallography Mar 2016 Manabu Hoshino et al. 2016 2016 |
| Copyright_xml | – notice: COPYRIGHT 2016 International Union of Crystallography – notice: Copyright International Union of Crystallography Mar 2016 – notice: Manabu Hoshino et al. 2016 2016 |
| DBID | AAYXX CITATION NPM 7SR 7U5 8BQ 8FD 8FE 8FG ABJCF ABUWG AFKRA AZQEC BENPR BGLVJ CCPQU D1I DWQXO EHMNL HCIFZ JG9 KB. L7M PDBOC PHGZM PHGZT PIMPY PKEHL PQEST PQGLB PQQKQ PQUKI PRINS 7X8 5PM DOA |
| DOI | 10.1107/S2052252515024379 |
| DatabaseName | CrossRef PubMed Engineered Materials Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database ProQuest SciTech Collection ProQuest Technology Collection Materials Science & Engineering Collection ProQuest Central (Alumni Edition) ProQuest Central UK/Ireland ProQuest Central Essentials - QC ProQuest Central Technology Collection ProQuest One Community College ProQuest Materials Science Collection ProQuest Central Korea UK & Ireland Database SciTech Premium Collection Materials Research Database Materials Science Database Advanced Technologies Database with Aerospace Materials Science Collection Proquest Central Premium ProQuest One Academic (New) Publicly Available Content Database ProQuest One Academic Middle East (New) ProQuest One Academic Eastern Edition (DO NOT USE) ProQuest One Applied & Life Sciences ProQuest One Academic (retired) ProQuest One Academic UKI Edition ProQuest Central China MEDLINE - Academic PubMed Central (Full Participant titles) DOAJ Directory of Open Access Journals |
| DatabaseTitle | CrossRef PubMed Publicly Available Content Database Materials Research Database Technology Collection Technology Research Database ProQuest One Academic Middle East (New) ProQuest Central Essentials Materials Science Collection ProQuest Central (Alumni Edition) SciTech Premium Collection ProQuest One Community College ProQuest Central China ProQuest Central ProQuest One Applied & Life Sciences Engineered Materials Abstracts ProQuest Central Korea Materials Science Database ProQuest Central (New) Advanced Technologies Database with Aerospace ProQuest Materials Science Collection ProQuest One Academic Eastern Edition ProQuest Technology Collection ProQuest SciTech Collection METADEX UK & Ireland Database ProQuest One Academic UKI Edition Materials Science & Engineering Collection Solid State and Superconductivity Abstracts ProQuest One Academic ProQuest One Academic (New) MEDLINE - Academic |
| DatabaseTitleList | PubMed Materials Research Database MEDLINE - Academic CrossRef Publicly Available Content Database |
| Database_xml | – sequence: 1 dbid: DOA name: DOAJ Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website – sequence: 2 dbid: NPM name: PubMed url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 3 dbid: KB. name: Materials Science Database url: http://search.proquest.com/materialsscijournals sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| DocumentTitleAlternate | Crystalline sponge method |
| EISSN | 2052-2525 |
| EndPage | 151 |
| ExternalDocumentID | oai_doaj_org_article_f5b5151b67fd4a2495f5c98436a227f5 PMC4775162 3951942741 A449197474 27006777 10_1107_S2052252515024379 |
| Genre | Journal Article |
| GroupedDBID | 5VS 8FE 8FG AAFWJ AAYXX ABJCF ABUWG ADBBV ADRAZ AENEX AFFHD AFKRA AFPKN ALMA_UNASSIGNED_HOLDINGS AOIJS BCNDV BENPR BGLVJ BPHCQ CCPQU CITATION D1I EBS EHMNL EJD GROUPED_DOAJ H13 HCIFZ HYE IAO IPNFZ ITC KB. KQ8 M48 M~E OK1 PDBOC PGMZT PHGZM PHGZT PIMPY PQGLB PQQKQ PROAC RCJ RIG ROL RPM ZBA NPM 7SR 7U5 8BQ 8FD AZQEC DWQXO JG9 L7M PKEHL PQEST PQUKI PRINS 7X8 PUEGO 5PM |
| ID | FETCH-LOGICAL-c631t-d2bc4e6175f447d62ba05d070d233eb17d1c9188e61a67fdabb483e60ce13ed23 |
| IEDL.DBID | DOA |
| ISICitedReferencesCount | 184 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000371619700009&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| ISSN | 2052-2525 |
| IngestDate | Tue Oct 14 18:31:06 EDT 2025 Tue Nov 04 01:55:17 EST 2025 Fri Sep 05 07:38:26 EDT 2025 Sun Nov 09 13:00:46 EST 2025 Fri Jul 25 11:59:04 EDT 2025 Tue Nov 04 17:40:28 EST 2025 Mon Jul 21 06:07:36 EDT 2025 Tue Nov 18 22:42:31 EST 2025 Sat Nov 29 03:53:00 EST 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 2 |
| Keywords | porous materials metal–organic frameworks chemical crystallography crystalline sponge method |
| Language | English |
| License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c631t-d2bc4e6175f447d62ba05d070d233eb17d1c9188e61a67fdabb483e60ce13ed23 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
| OpenAccessLink | https://doaj.org/article/f5b5151b67fd4a2495f5c98436a227f5 |
| PMID | 27006777 |
| PQID | 1764917545 |
| PQPubID | 2035043 |
| PageCount | 13 |
| ParticipantIDs | doaj_primary_oai_doaj_org_article_f5b5151b67fd4a2495f5c98436a227f5 pubmedcentral_primary_oai_pubmedcentral_nih_gov_4775162 proquest_miscellaneous_1864560596 proquest_miscellaneous_1775631006 proquest_journals_1764917545 gale_infotracacademiconefile_A449197474 pubmed_primary_27006777 crossref_primary_10_1107_S2052252515024379 crossref_citationtrail_10_1107_S2052252515024379 |
| PublicationCentury | 2000 |
| PublicationDate | 2016-03-01 |
| PublicationDateYYYYMMDD | 2016-03-01 |
| PublicationDate_xml | – month: 03 year: 2016 text: 2016-03-01 day: 01 |
| PublicationDecade | 2010 |
| PublicationPlace | England |
| PublicationPlace_xml | – name: England – name: Chester |
| PublicationTitle | IUCrJ |
| PublicationTitleAlternate | IUCrJ |
| PublicationYear | 2016 |
| Publisher | International Union of Crystallography |
| Publisher_xml | – name: International Union of Crystallography |
| References | Vinogradova (de5035_bb42) 2014; 53 Toda (de5035_bb40) 1987; 140 Sheldrick (de5035_bb34) 2015; 71 Inokuma (de5035_bb14) 2010; 2 Hooft (de5035_bb12) 2010; 43 Sheldrick (de5035_bb33) 2008; 64 Vishweshwar (de5035_bb43) 2006; 95 Tashiro (de5035_bb39) 2012; 134 Ohmori (de5035_bb26) 2005; 44 Singharoy (de5035_bb35) 2015; 137 Yaghi (de5035_bb44) 1995; 117 Fujita (de5035_bb9) 1994; 116 Desiraju (de5035_bb8) 2007; 46 Kondo (de5035_bb20) 1997; 36 Ramadhar (de5035_bb30) 2015; 71 Li (de5035_bb23) 2009; 325 Mori (de5035_bb24) 1997 Turega (de5035_bb41) 2014; 136 Batten (de5035_bb1) 1998; 37 Biradha (de5035_bb2) 2002; 41 Ohmori (de5035_bb27) 2004; 126 Suh (de5035_bb38) 2002; 124 Heine (de5035_bb10) 2011; 133 Deiters (de5035_bb7) 2005 Parsons (de5035_bb29) 2013; 69 Burla (de5035_bb5) 2015; 48 Inokuma (de5035_bb15) 2013; 495 Kawano (de5035_bb19) 2008; 47 Yoshioka (de5035_bb45) 2015; 6 Sanna (de5035_bb32) 2015; 6 Subramanian (de5035_bb37) 1995; 34 Zhou (de5035_bb48) 2012; 112 Zhou (de5035_bb47) 2014; 43 de5035_bb4 Corey (de5035_bb6) 1955; 77 Kamimura (de5035_bb16) 2013; 15 Kusukawa (de5035_bb22) 1998; 37 O'Brien (de5035_bb25) 2014; 53 Palatinus (de5035_bb28) 2007; 40 Yoshizawa (de5035_bb46) 2009; 48 Biradha (de5035_bb3) 2002; 41 Spek (de5035_bb36) 2015; 71 Kawano (de5035_bb18) 2007; 251 Kubota (de5035_bb21) 2014; 6 Zigon (de5035_bb49) 2015; 54 Ramadhar (de5035_bb31) 2015; 51 Hoskins (de5035_bb13) 1989; 111 |
| References_xml | – volume: 37 start-page: 1460 year: 1998 ident: de5035_bb1 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z – volume: 495 start-page: 461 year: 2013 ident: de5035_bb15 publication-title: Nature doi: 10.1038/nature11990 – volume: 6 start-page: 3765 year: 2015 ident: de5035_bb45 publication-title: Chem. Sci. doi: 10.1039/C5SC01681A – volume: 54 start-page: 9033 year: 2015 ident: de5035_bb49 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201502302 – volume: 53 start-page: 11868 year: 2014 ident: de5035_bb25 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201407948 – volume: 112 start-page: 637 year: 2012 ident: de5035_bb48 publication-title: Chem. Rev. – start-page: 3906 year: 2005 ident: de5035_bb7 publication-title: Chem. Commun. doi: 10.1039/b508135c – volume: 116 start-page: 1151 year: 1994 ident: de5035_bb9 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00082a055 – start-page: 1219 year: 1997 ident: de5035_bb24 publication-title: Chem. Lett. doi: 10.1246/cl.1997.1219 – volume: 53 start-page: 3125 year: 2014 ident: de5035_bb42 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201310897 – volume: 117 start-page: 10401 year: 1995 ident: de5035_bb44 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00146a033 – volume: 126 start-page: 16292 year: 2004 ident: de5035_bb27 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja046478a – volume: 124 start-page: 10976 year: 2002 ident: de5035_bb38 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja017560y – volume: 111 start-page: 5962 year: 1989 ident: de5035_bb13 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00197a079 – volume: 95 start-page: 499 year: 2006 ident: de5035_bb43 publication-title: J. Pharm. Sci. doi: 10.1002/jps.20578 – volume: 41 start-page: 3392 year: 2002 ident: de5035_bb2 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/1521-3773(20020916)41:18<3392::AID-ANIE3392>3.0.CO;2-V – volume: 69 start-page: 249 year: 2013 ident: de5035_bb29 publication-title: Acta Cryst. B doi: 10.1107/S2052519213010014 – volume: 48 start-page: 306 year: 2015 ident: de5035_bb5 publication-title: J. Appl. Cryst. doi: 10.1107/S1600576715001132 – volume: 2 start-page: 780 year: 2010 ident: de5035_bb14 publication-title: Nat. Chem. doi: 10.1038/nchem.742 – volume: 40 start-page: 786 year: 2007 ident: de5035_bb28 publication-title: J. Appl. Cryst. doi: 10.1107/S0021889807029238 – volume: 48 start-page: 3418 year: 2009 ident: de5035_bb46 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200805340 – volume: 15 start-page: 5122 year: 2013 ident: de5035_bb16 publication-title: Org. Lett. doi: 10.1021/ol402563v – volume: 51 start-page: 11252 year: 2015 ident: de5035_bb31 publication-title: Chem. Commun. doi: 10.1039/C5CC03840E – volume: 6 start-page: 5466 year: 2015 ident: de5035_bb32 publication-title: Chem. Sci. doi: 10.1039/C5SC01838B – volume: 71 start-page: 3 year: 2015 ident: de5035_bb34 publication-title: Acta Cryst. A doi: 10.1107/S2053273314026370 – volume: 64 start-page: 112 year: 2008 ident: de5035_bb33 publication-title: Acta Cryst. A doi: 10.1107/S0108767307043930 – volume: 71 start-page: 9 year: 2015 ident: de5035_bb36 publication-title: Acta Cryst. C doi: 10.1107/S2053229614024929 – volume: 44 start-page: 1962 year: 2005 ident: de5035_bb26 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200462201 – volume: 137 start-page: 8810 year: 2015 ident: de5035_bb35 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.5b04407 – volume: 46 start-page: 8342 year: 2007 ident: de5035_bb8 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200700534 – volume: 43 start-page: 665 year: 2010 ident: de5035_bb12 publication-title: J. Appl. Cryst. doi: 10.1107/S0021889810018601 – volume: 36 start-page: 1725 year: 1997 ident: de5035_bb20 publication-title: Angew. Chem. Int. Ed. Engl. doi: 10.1002/anie.199717251 – volume: 77 start-page: 1044 year: 1955 ident: de5035_bb6 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01609a076 – volume: 134 start-page: 2461 year: 2012 ident: de5035_bb39 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja209422m – volume: 41 start-page: 3395 year: 2002 ident: de5035_bb3 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/1521-3773(20020916)41:18<3395::AID-ANIE3395>3.0.CO;2-D – volume: 43 start-page: 5415 year: 2014 ident: de5035_bb47 publication-title: Chem. Soc. Rev. doi: 10.1039/C4CS90059F – volume: 37 start-page: 3142 year: 1998 ident: de5035_bb22 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/(SICI)1521-3773(19981204)37:22<3142::AID-ANIE3142>3.0.CO;2-9 – volume: 47 start-page: 1269 year: 2008 ident: de5035_bb19 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200704809 – ident: de5035_bb4 doi: 10.1093/acprof:oso/9780199219469.003.0003 – volume: 6 start-page: 913 year: 2014 ident: de5035_bb21 publication-title: Nat. Chem. doi: 10.1038/nchem.2044 – volume: 136 start-page: 8475 year: 2014 ident: de5035_bb41 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja504269m – volume: 34 start-page: 2127 year: 1995 ident: de5035_bb37 publication-title: Angew. Chem. Int. Ed. Engl. doi: 10.1002/anie.199521271 – volume: 71 start-page: 46 year: 2015 ident: de5035_bb30 publication-title: Acta Cryst. A doi: 10.1107/S2053273314019573 – volume: 251 start-page: 2592 year: 2007 ident: de5035_bb18 publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2007.07.022 – volume: 325 start-page: 855 year: 2009 ident: de5035_bb23 publication-title: Science doi: 10.1126/science.1175441 – volume: 140 start-page: 43 year: 1987 ident: de5035_bb40 publication-title: Top. Curr. Chem. doi: 10.1007/BFb0003836 – volume: 133 start-page: 10018 year: 2011 ident: de5035_bb10 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja2030273 |
| SSID | ssj0001125741 |
| Score | 2.4567404 |
| Snippet | Crystalline sponges are porous metal complexes that can absorb and orient common organic molecules in their pores and make them observable by conventional... The protocols of the crystalline sponge method, particularly those in the soaking, data collection and refinement processes, are considerably improved to give... |
| SourceID | doaj pubmedcentral proquest gale pubmed crossref |
| SourceType | Open Website Open Access Repository Aggregation Database Index Database Enrichment Source |
| StartPage | 139 |
| SubjectTerms | chemical crystallography Chemical properties Chemical synthesis Crystal structure crystalline sponge method Crystallography Crystals Data acquisition metal–organic frameworks Methods porous materials Research Papers Soaking Solvents Sponges Test procedures X-rays |
| SummonAdditionalLinks | – databaseName: ProQuest Central dbid: BENPR link: http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1La9wwEB7aTQ_toekzdZsUF1oKBRPL1sM-lSQk9FCW0Be5Cb2cBoJ3u49C_31nbO1mTWAvuVoj7PFoXtLoG4D3lXGy5rzMvBeMruTwrK5tnjXKNg7D2zJ0Tft-fVXjcXVxUZ_HDbd5LKtc2cTOUPuJoz3yQ6Ykx9QCHf7n6Z-MukbR6WpsoXEfdgipjI9g5_h0fP7tZpcF_Tf6zHicianO4fcix5BDoFsXPRjfwCF1uP23rfOGexqWTm74orPdu3LxBB7HKDQ96pfNU7gX2mfwaAOb8Dl8wAWUutk_jB4JtjukVEt7GdK-5XS6nNJWgX8BP89Of5x8yWJPhczJki0yX1jHA4YtouFceVlYkwuPeu-LskS7rTxzNasqJDFSNd5Yy1FgMneBlQGJXsKonbThFaTUtxjTW2mZM9wFX_siVw1aiIAjTV4lkK9-rHYRcJz6XlzrLvHIlb4liwQ-radMe7SNbcTHJK01IQFldw8ms0sd9U43wuIEZokXbqjRdiNcXfFSmqJQjUjgI8lakzrjxzkTbyUgiwSMpY84yotyLp7A_kqkOur5XN_IM4F362HUUDp2MW2YLIlGCUnnKHILTSUxkqVWSAns9StszReVBkilVAJqsPYGjA9H2qvfHVI4x1czWbze_ulv4CGGgbKvrNuH0WK2DAfwwP1dXM1nb6NK_QcCTiZk priority: 102 providerName: ProQuest |
| Title | The crystalline sponge method updated |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/27006777 https://www.proquest.com/docview/1764917545 https://www.proquest.com/docview/1775631006 https://www.proquest.com/docview/1864560596 https://pubmed.ncbi.nlm.nih.gov/PMC4775162 https://doaj.org/article/f5b5151b67fd4a2495f5c98436a227f5 |
| Volume | 3 |
| WOSCitedRecordID | wos000371619700009&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVAON databaseName: DOAJ Directory of Open Access Journals customDbUrl: eissn: 2052-2525 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0001125741 issn: 2052-2525 databaseCode: DOA dateStart: 20140101 isFulltext: true titleUrlDefault: https://www.doaj.org/ providerName: Directory of Open Access Journals – providerCode: PRVHPJ databaseName: ROAD: Directory of Open Access Scholarly Resources customDbUrl: eissn: 2052-2525 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0001125741 issn: 2052-2525 databaseCode: M~E dateStart: 20140101 isFulltext: true titleUrlDefault: https://road.issn.org providerName: ISSN International Centre – providerCode: PRVPQU databaseName: Materials Science Database customDbUrl: eissn: 2052-2525 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0001125741 issn: 2052-2525 databaseCode: KB. dateStart: 20140101 isFulltext: true titleUrlDefault: http://search.proquest.com/materialsscijournals providerName: ProQuest – providerCode: PRVPQU databaseName: ProQuest Central customDbUrl: eissn: 2052-2525 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0001125741 issn: 2052-2525 databaseCode: BENPR dateStart: 20140101 isFulltext: true titleUrlDefault: https://www.proquest.com/central providerName: ProQuest – providerCode: PRVPQU databaseName: Publicly Available Content Database customDbUrl: eissn: 2052-2525 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0001125741 issn: 2052-2525 databaseCode: PIMPY dateStart: 20140101 isFulltext: true titleUrlDefault: http://search.proquest.com/publiccontent providerName: ProQuest – providerCode: PRVPQU databaseName: UK & Ireland Database customDbUrl: eissn: 2052-2525 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0001125741 issn: 2052-2525 databaseCode: EHMNL dateStart: 20140101 isFulltext: true titleUrlDefault: https://search.proquest.com/ukireland providerName: ProQuest |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1Lb9NAEB5B4UAPiHcNbWQkEBKSqXe9D_vYoFYgIIp4KZws74tWqtwqTZD498ys3chWpfbCJYfdiZIdz3i-8a6_D-BV2VhVCVFkzklGr-SIrKpMngVtgkV4W_go2vfzs57NysWimg-kvuhMWEcP3DluP0iDJZcZpYMTDSklB2mrUhSq4VyHyF6KqGfQTMWnK1i3dZSt5LnkGZdc9lua2O7sf6NBGkM0FAn5RkUpcvdfvUMPStT4-OSgHh09gPs9kEwPugU8hFu-fQTbA3rBx_AaYyC1y78IAIl526d0HPa3TzvV6HR9Tt2-ewI_jg6_v_-Q9bIImVUFW2WOGys8Ig8ZhNBOcdPk0mHqOl4UeOvVjtmKlSWaNOS1xhiBPle59azwaPQUttqz1u9AStLD2KEqw2wjrHeV47kOmOQeZ0JeJpBf-qW2PWc4SVec1rF3yHV9xZUJvN185bwjzLjOeErO3hgS13UcwAio-wiob4qABN7QpaopI_HP2aZ_sQCXSNxW9YEQFaO2SSSwe3k16z5VL2qmFc5rRJIJvNxMY5LRzknT-rM12WipaCtEXWNTKgSjpGaUwLMuQDbrot19pbVOQI9CZ7Tw8Ux7chzJvgX-NFP8-f_w1Au4h3hPdUfodmFrtVz7Pbhr_6xOLpYTuK0X5QTuTA9n86-TmE_4-Wn6DsfmH7_Mf_0DoAIdOg |
| linkProvider | Directory of Open Access Journals |
| linkToHtml | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMw1V1ba9RAFD6UraA-eNdGq0awCEJoMpnMJA8i9VK6dLssWKU-jZlLaqFk170o_VP-Rs_JZbuhsG998DVzQmYy35zLzJnzAbxOcyMyzuPA2iSiKzk8yDIdBoXUhUH3NnYVad-3gRwO05OTbLQBf9u7MJRW2erESlHbsaE98t1ICo6hBRr895NfAbFG0elqS6FRw-LQXfzBkG32rv8J53eHsf3Pxx8PgoZVIDAijuaBZdpwh4Y7KTiXVjCdh4lF5FsWx6i5pI1MFqUpiuRCFjbXmmOXRWhcFDtLhQ5Q5W9yBHvag81R_2j0_XJXB_0FtNHN8SmGVrtfWIguToJuRFIX_-sYwIon4Ko1WDGH3VTNFdu3f_d_-2v34E7jZft79bK4DxuufAC3V2ovPoQdXCC-mV6gd0xlyZ1PucKnzq8ptf3FhLZC7CP4ei39fAy9cly6LfCJlxnDd6Ejk3PjbGZZKAvUgA5bijD1IGwnUpmmoDrxepyrKrAKpboy9x68Xb4yqauJrBP-QOhYClIh8OrBeHqqGr2iikTjC5GmsfCciMSLxGQpj0XOmCwSD94QthSpK-ycyZtbFzhEKvyl9jjig2JK7sF2CyHV6LGZusSPB6-WzaiB6FgpL914QTIyEXROJNbIpAI9daJ68uBJjejluCj1QUgpPZAdrHcG3m0pz35WldA5fjoS7On6rr-EmwfHRwM16A8Pn8EtdHlFnUW4Db35dOGeww3ze342m75olrMPP657LfwDmFOEFA |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=The+crystalline+sponge+method+updated&rft.jtitle=IUCrJ&rft.au=Hoshino%2C+Manabu&rft.au=Khutia%2C+Anupam&rft.au=Xing%2C+Hongzhu&rft.au=Inokuma%2C+Yasuhide&rft.date=2016-03-01&rft.pub=International+Union+of+Crystallography&rft.issn=2052-2525&rft.eissn=2052-2525&rft.spage=139&rft_id=info:doi/10.1107%2FS2052252515024379&rft.externalDocID=A449197474 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2052-2525&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2052-2525&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2052-2525&client=summon |