Bio-Based Nitriles from the Heterogeneously Catalyzed Oxidative Decarboxylation of Amino Acids

The oxidative decarboxylation of amino acids to nitriles was achieved in aqueous solution by in situ halide oxidation using catalytic amounts of tungstate exchanged on a [Ni,Al] layered double hydroxide (LDH), NH4Br, and H2O2 as the terminal oxidant. Both halide oxidation and oxidative decarboxylati...

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Bibliographic Details
Published in:	ChemSusChem Vol. 8; no. 2; pp. 345 - 352
Main Authors:	Claes, Laurens, Matthessen, Roman, Rombouts, Ine, Stassen, Ivo, De Baerdemaeker, Trees, Depla, Diederik, Delcour, Jan A., Lagrain, Bert, De Vos, Dirk E.
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 01.01.2015 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Subjects:	Amino acids Amino Acids - chemistry Aqueous solutions biomass Catalysis Decarboxylation Glutens - chemistry heterogeneous catalysis Hydrolysis Nitriles - chemistry oxidation Oxidation-Reduction Triticum - chemistry tungsten oxidation biomass tungsten heterogeneous catalysis amino acids
ISSN:	1864-5631, 1864-564X, 1864-564X
Online Access:	Get full text
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