Copolymerization as a Strategy to Combine Epoxidized Linseed Oil and Furfuryl Alcohol: The Design of a Fully Bio-Based Thermoset

Epoxidized linseed oil and furfuryl alcohol are bio‐sourced monomers known for their high‐potential applications in materials science. In this work, we propose the association of these monomers through copolymerization reactions with the target to design fully bio‐based thermosets. Herein, investiga...

Celý popis

Uložené v:
Podrobná bibliografia
Vydané v:ChemSusChem Ročník 8; číslo 24; s. 4149 - 4161
Hlavní autori: Pin, Jean-Mathieu, Guigo, Nathanaël, Vincent, Luc, Sbirrazzuoli, Nicolas, Mija, Alice
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: Germany Blackwell Publishing Ltd 21.12.2015
Wiley Subscription Services, Inc
ChemPubSoc Europe/Wiley
Predmet:
Alcohol
Biomass
Chemical Sciences
epoxidized vegetable oil
Epoxy Compounds - chemistry
Furans - chemistry
furfuryl alcohol
Linseed Oil - chemistry
Material chemistry
mechanical properties
Polymerization
renewable resources
Temperature
Tensile Strength
furfuryl alcohol
polymerization
renewable resources
mechanical properties
epoxidized vegetable oil
ISSN:1864-5631, 1864-564X, 1864-564X
On-line prístup:Získať plný text
Tagy: Pridať tag
Žiadne tagy, Buďte prvý, kto otaguje tento záznam!
Popis
Shrnutí:Epoxidized linseed oil and furfuryl alcohol are bio‐sourced monomers known for their high‐potential applications in materials science. In this work, we propose the association of these monomers through copolymerization reactions with the target to design fully bio‐based thermosets. Herein, investigations on cationic polymerization reactivity have been explored using differential scanning calorimetry. The obtained structures have been confirmed by IR spectroscopy and 2 D NMR spectroscopy, which revealed the principal chain connections. In spite of the multiple capabilities of chemical connections, which include copolymerization and cross‐linking, the obtained networks are homogeneous as confirmed by dynamic mechanical analysis and SEM. Furthermore, the copolymer demonstrates a semiductile behavior if subjected to tensile measurements (tensile strain at break ≈40 %), which is a significant advance in terms of its applications as a furanic bio‐based thermoset material. Oil on troubled waters: An original combination of epoxidized linseed oil and furfuryl alcohol as bio‐based monomers is proposed to design fully bio‐based materials with tailored mechanical properties.
Bibliografia:ark:/67375/WNG-JX3BXHPS-6
ArticleID:CSSC201501259
SICOMIN Composites Company
istex:E6550C343358D770C71461851F70CC639EA25FD1
PACA region
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
content type line 23
ISSN:1864-5631
1864-564X
1864-564X
DOI:10.1002/cssc.201501259