Engineering Spin States of Isolated Copper Species in a Metal–Organic Framework Improves Urea Electrosynthesis

Highlights The single-atom Cu species with S = 0 spin ground state in Cu III -HHTP have been fabricated. The Cu III -HHTP exhibits remarkable performance with a high urea yield of 7.780 mmol h −1 g −1 with the corresponding Faradaic efficiency of 23.09% at − 0.6 V (vs. RHE). Low spin state and emp...

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Bibliographic Details
Published in:	Nano-micro letters Vol. 15; no. 1; pp. 158 - 14
Main Authors:	Gao, Yuhang, Wang, Jingnan, Yang, Yijun, Wang, Jian, Zhang, Chuang, Wang, Xi, Yao, Jiannian
Format:	Journal Article
Language:	English
Published:	Singapore Springer Nature Singapore 01.12.2023 Springer Nature B.V SpringerOpen
Subjects:	Carbon dioxide Catalysis Copper Coupling C–N coupling Efficiency Electrocatalysis Electrodes Electron microscopes Electron states Engineering Fourier transforms Ground state Metal-organic frameworks Metal–organic framework Nanoscale Science and Technology Nanotechnology Nanotechnology and Microengineering Radiation Science Single electrons Spin catalysis Urea Urea synthesis X-rays Urea synthesis Spin catalysis Electrocatalysis Metal–organic framework C–N coupling
ISSN:	2311-6706, 2150-5551, 2150-5551
Online Access:	Get full text
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