Surface Grafting via Photo-Induced Copper-Mediated Radical Polymerization at Extremely Low Catalyst Concentrations

Surface‐initiated photo‐induced copper‐mediated radical polymerization is employed to graft a wide range of polyacrylate brushes from silicon substrates at extremely low catalyst concentrations. This is the first time that the controlled nature of the reported process is demonstrated via block copol...

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Veröffentlicht in:	Macromolecular rapid communications. Jg. 36; H. 18; S. 1681 - 1686
Hauptverfasser:	Laun, Joachim, Vorobii, Mariia, de los Santos Pereira, Andres, Pop-Georgievski, Ognen, Trouillet, Vanessa, Welle, Alexander, Barner-Kowollik, Christopher, Rodriguez-Emmenegger, Cesar, Junkers, Thomas
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	Germany Blackwell Publishing Ltd 01.09.2015 Wiley Subscription Services, Inc
Schlagworte:	Acrylic resins Block copolymers Catalysis Catalysts Copper Copper - chemistry copper-mediated polymerization Film thickness Formations Grafting Light photo-induced polymerization Polyacrylate Polyacrylates polymer brushes Polymerization Polymers - chemistry Radicals reversible deactivation radical polymerization Silicon substrates spatial control Thickness photo-induced polymerization copper-mediated polymerization spatial control polymer brushes reversible deactivation radical polymerization
ISSN:	1022-1336, 1521-3927, 1521-3927
Online-Zugang:	Volltext
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