Transition‐Metal‐Free Cleavage of CO

Tertiary silane 1H, 2‐[(diphenylsilyl)methyl]‐6‐methylpyridine, reacts with tris(pentafluorophenyl)borane (BCF) to form the intramolecular pyridine‐stabilized silylium 1+‐HBCF. The corresponding 2‐[(diphenylsilyl)methyl]pyridine, lacking the methyl‐group on the pyridine ring, forms classic N(py)→B a...

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Vydané v:	Chemistry : a European journal Ročník 23; číslo 55; s. 13628 - 13632
Hlavní autori:	Devillard, Marc, de Bruin, Bas, Siegler, Maxime A., van der Vlugt, J. I.
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	WEINHEIM Wiley 04.10.2017 Wiley Subscription Services, Inc Wiley-VCH Verlag John Wiley and Sons Inc
Predmet:	Aromatic compounds boron Carbon monoxide Chemical bonds Chemical Sciences Chemistry Chemistry, Multidisciplinary Cleavage Communication Communications C−C bond formation Deoxygenation Ductile-brittle transition Fracture mechanics Physical Sciences Pyridines Science & Technology silicon small molecule activation INSERTION SMALL MOLECULES FRUSTRATED LEWIS-PAIR COMPLEXES COORDINATION CO BORANE H BOND ACTIVATION silicon C-C bond formation REDUCTION CARBON-MONOXIDE SI-H small molecule activation boron C−C bond formation
ISSN:	0947-6539, 1521-3765, 1521-3765
On-line prístup:	Získať plný text
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