Synthesis and Characterization of Ru‐Loaded Anodized Aluminum Oxide for Hydrogenation Catalysis
Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM analysis of the as‐synthesized AAOs reveal uniform, ordered nanotubes with pore diameters of 18 nm, which are further characterized with Kr physisorpti...
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| Vydané v: | ChemistryOpen (Weinheim) Ročník 8; číslo 4; s. 532 - 538 |
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| Hlavní autori: | , , , , , , , , |
| Médium: | Journal Article |
| Jazyk: | English |
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Germany
John Wiley & Sons, Inc
01.04.2019
John Wiley and Sons Inc Wiley-VCH |
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| ISSN: | 2191-1363, 2191-1363 |
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| Abstract | Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM analysis of the as‐synthesized AAOs reveal uniform, ordered nanotubes with pore diameters of 18 nm, which are further characterized with Kr physisorption, XRD and FTIR spectroscopy. After impregnation of the AAOs with Ru, the presence of Ru nanoparticles inside the tubular pores is evidenced clearly for the first time via HAADF‐STEM‐EDX. The Ru−AAOs have been tested for catalytic activity, which showed high conversion and selectivity for the hydrogenation of toluene and butanal.
Ru ready for this? Anodized aluminum oxide (AAO) platelets are synthesized and thoroughly characterized. The platelets are loaded with Ru and the presence of Ru inside the pores is clearly evidenced via HAADF‐STEM‐EDX. Hydrogenations of butanal and toluene are successfully carried out with the Ru−AAO catalyst, which can be easily removed from the reaction mixture and fast diffusion of substrate and products through the mesopores is ensured. |
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| AbstractList | Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM analysis of the as‐synthesized AAOs reveal uniform, ordered nanotubes with pore diameters of 18 nm, which are further characterized with Kr physisorption, XRD and FTIR spectroscopy. After impregnation of the AAOs with Ru, the presence of Ru nanoparticles inside the tubular pores is evidenced clearly for the first time via HAADF‐STEM‐EDX. The Ru−AAOs have been tested for catalytic activity, which showed high conversion and selectivity for the hydrogenation of toluene and butanal. Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM analysis of the as-synthesized AAOs reveal uniform, ordered nanotubes with pore diameters of 18 nm, which are further characterized with Kr physisorption, XRD and FTIR spectroscopy. After impregnation of the AAOs with Ru, the presence of Ru nanoparticles inside the tubular pores is evidenced clearly for the first time via HAADF-STEM-EDX. The Ru-AAOs have been tested for catalytic activity, which showed high conversion and selectivity for the hydrogenation of toluene and butanal.Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM analysis of the as-synthesized AAOs reveal uniform, ordered nanotubes with pore diameters of 18 nm, which are further characterized with Kr physisorption, XRD and FTIR spectroscopy. After impregnation of the AAOs with Ru, the presence of Ru nanoparticles inside the tubular pores is evidenced clearly for the first time via HAADF-STEM-EDX. The Ru-AAOs have been tested for catalytic activity, which showed high conversion and selectivity for the hydrogenation of toluene and butanal. Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM analysis of the as‐synthesized AAOs reveal uniform, ordered nanotubes with pore diameters of 18 nm, which are further characterized with Kr physisorption, XRD and FTIR spectroscopy. After impregnation of the AAOs with Ru, the presence of Ru nanoparticles inside the tubular pores is evidenced clearly for the first time via HAADF‐STEM‐EDX. The Ru−AAOs have been tested for catalytic activity, which showed high conversion and selectivity for the hydrogenation of toluene and butanal. Ru ready for this? Anodized aluminum oxide (AAO) platelets are synthesized and thoroughly characterized. The platelets are loaded with Ru and the presence of Ru inside the pores is clearly evidenced via HAADF‐STEM‐EDX. Hydrogenations of butanal and toluene are successfully carried out with the Ru−AAO catalyst, which can be easily removed from the reaction mixture and fast diffusion of substrate and products through the mesopores is ensured. Abstract Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM analysis of the as‐synthesized AAOs reveal uniform, ordered nanotubes with pore diameters of 18 nm, which are further characterized with Kr physisorption, XRD and FTIR spectroscopy. After impregnation of the AAOs with Ru, the presence of Ru nanoparticles inside the tubular pores is evidenced clearly for the first time via HAADF‐STEM‐EDX. The Ru−AAOs have been tested for catalytic activity, which showed high conversion and selectivity for the hydrogenation of toluene and butanal. Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM analysis of the as-synthesized AAOs reveal uniform, ordered nanotubes with pore diameters of 18 nm, which are further characterized with Kr physisorption, XRD and FTIR spectroscopy. After impregnation of the AAOs with Ru, the presence of Ru nanoparticles inside the tubular pores is evidenced clearly for the first time via HAADF-STEM-EDX. The Ru-AAOs have been tested for catalytic activity, which showed high conversion and selectivity for the hydrogenation of toluene and butanal. |
| Author | De Vos, Dirk E. Glas, Daan Negahdar, Leila Weckhuysen, Bert M. Meirer, Florian Vandekerkhove, Annelies Meeldijk, Johannes D. Stassen, Ivo Matveev, Serguei |
| AuthorAffiliation | 1 Department of Microbial and Molecular Systems, Centre for Surface Chemistry and Catalysis KU Leuven Celestijnenlaan 200F, P.O. 2461 3001 Heverlee Belgium 2 Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands |
| AuthorAffiliation_xml | – name: 2 Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands – name: 1 Department of Microbial and Molecular Systems, Centre for Surface Chemistry and Catalysis KU Leuven Celestijnenlaan 200F, P.O. 2461 3001 Heverlee Belgium |
| Author_xml | – sequence: 1 givenname: Annelies orcidid: 0000-0003-0171-4825 surname: Vandekerkhove fullname: Vandekerkhove, Annelies organization: KU Leuven – sequence: 2 givenname: Leila surname: Negahdar fullname: Negahdar, Leila organization: Utrecht University – sequence: 3 givenname: Daan surname: Glas fullname: Glas, Daan organization: KU Leuven – sequence: 4 givenname: Ivo surname: Stassen fullname: Stassen, Ivo organization: KU Leuven – sequence: 5 givenname: Serguei surname: Matveev fullname: Matveev, Serguei organization: Utrecht University – sequence: 6 givenname: Johannes D. surname: Meeldijk fullname: Meeldijk, Johannes D. organization: Utrecht University – sequence: 7 givenname: Florian surname: Meirer fullname: Meirer, Florian organization: Utrecht University – sequence: 8 givenname: Dirk E. surname: De Vos fullname: De Vos, Dirk E. email: dirk.devos@kuleuven.be organization: KU Leuven – sequence: 9 givenname: Bert M. surname: Weckhuysen fullname: Weckhuysen, Bert M. email: b.m.weckhuysen@uu.nl organization: Utrecht University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31061778$$D View this record in MEDLINE/PubMed |
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| Keywords | anodized aluminum oxide Ru catalysts butanal hydrogenation toluene |
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| Snippet | Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM analysis... Abstract Anodized aluminum oxides (AAOs) are synthesized and used as catalyst support in combination with Ru as metal in hydrogenation catalysis. SEM and TEM... |
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| StartPage | 532 |
| SubjectTerms | Alumina Aluminum Aluminum oxide anodized aluminum oxide butanal Catalysis Catalytic activity Catalytic converters Chemical synthesis Contact angle Hydrogenation Nanoparticles Pore size Ru catalysts Ruthenium Selectivity Solvents Toluene |
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| Title | Synthesis and Characterization of Ru‐Loaded Anodized Aluminum Oxide for Hydrogenation Catalysis |
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