Redox-Active Ligand-Induced Homolytic Bond Activation

Coordination of the novel redox‐active phosphine‐appended aminophenol pincer ligand (PNOH2) to PdII generates a paramagnetic complex with a persistent ligand‐centered radical. The complex undergoes fully reversible single‐electron oxidation and reduction. Homolytic bond activation of diphenyldisulfi...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 54; no. 5; pp. 1516 - 1520
Main Authors:	Broere, Daniël L. J., Metz, Lotte L., de Bruin, Bas, Reek, Joost N. H., Siegler, Maxime A., van der Vlugt, Jarl Ivar
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 26.01.2015 WILEY‐VCH Verlag Wiley Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	Activation bond activation Bonding Chemistry Chemistry, Multidisciplinary Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Crystallography, X-Ray Disulfides - chemistry Electron Spin Resonance Spectroscopy Electron Transport Ligands mixed valency Molecular Conformation Oxidation-Reduction Palladium Palladium - chemistry phosphane ligands Phosphines Physical Sciences Radicals redox-active ligands Reduction Science & Technology Strategy mixed valency CATALYSIS TRANSITION-METAL-COMPLEXES bond activation REACTIVITY IRON OXIDATIVE ADDITION ELECTRONIC-STRUCTURES phosphane ligands MONONUCLEAR redox-active ligands RUTHENIUM COMPLEXES palladium THIYL RADICALS PALLADIUM(II)
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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