Redox-Active Ligand-Induced Homolytic Bond Activation

Coordination of the novel redox‐active phosphine‐appended aminophenol pincer ligand (PNOH2) to PdII generates a paramagnetic complex with a persistent ligand‐centered radical. The complex undergoes fully reversible single‐electron oxidation and reduction. Homolytic bond activation of diphenyldisulfi...

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