A Metal-Ligand Cooperative Pathway for Intermolecular Oxa-Michael Additions to Unsaturated Nitriles

An unprecedented catalytic pathway for oxa‐Michael addition reactions of alcohols to unsaturated nitriles has been revealed using a PNN pincer ruthenium catalyst with a dearomatized pyridine backbone. The isolation of a catalytically competent Ru–dieneamido complex from the reaction between the Ru c...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 54; no. 14; pp. 4236 - 4240
Main Authors:	Perdriau, Sébastien, Zijlstra, Douwe S., Heeres, Hero J., de Vries, Johannes G., Otten, Edwin
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 27.03.2015 WILEY‐VCH Verlag Wiley Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	Activation Alcohols Ambient temperature Catalysis Catalysts Chemistry Chemistry, Multidisciplinary Conjugates homogeneous catalysis Ligands Michael addition Nitriles Nitriles - chemistry non-innocent ligands Pathways Physical Sciences pincer ligands Ruthenium Ruthenium - chemistry Science & Technology Unsaturated Michael addition RU N-H BOND FORMATION pincer ligands non-innocent ligands AMINE ALCOHOLS ruthenium ACTIVATED ALKENES homogeneous catalysis PINCER COMPLEXES HYDROALKOXYLATION OLEFINS CONJUGATE ADDITIONS
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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