A Metal-Ligand Cooperative Pathway for Intermolecular Oxa-Michael Additions to Unsaturated Nitriles

An unprecedented catalytic pathway for oxa‐Michael addition reactions of alcohols to unsaturated nitriles has been revealed using a PNN pincer ruthenium catalyst with a dearomatized pyridine backbone. The isolation of a catalytically competent Ru–dieneamido complex from the reaction between the Ru c...

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Vydané v:	Angewandte Chemie International Edition Ročník 54; číslo 14; s. 4236 - 4240
Hlavní autori:	Perdriau, Sébastien, Zijlstra, Douwe S., Heeres, Hero J., de Vries, Johannes G., Otten, Edwin
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	Weinheim WILEY-VCH Verlag 27.03.2015 WILEY‐VCH Verlag Wiley Wiley Subscription Services, Inc
Vydanie:	International ed. in English
Predmet:	Activation Alcohols Ambient temperature Catalysis Catalysts Chemistry Chemistry, Multidisciplinary Conjugates homogeneous catalysis Ligands Michael addition Nitriles Nitriles - chemistry non-innocent ligands Pathways Physical Sciences pincer ligands Ruthenium Ruthenium - chemistry Science & Technology Unsaturated Michael addition RU N-H BOND FORMATION pincer ligands non-innocent ligands AMINE ALCOHOLS ruthenium ACTIVATED ALKENES homogeneous catalysis PINCER COMPLEXES HYDROALKOXYLATION OLEFINS CONJUGATE ADDITIONS
ISSN:	1433-7851, 1521-3773, 1521-3773
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