Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries

Lithium-ion (Li-ion) batteries that rely on cationic redox reactions are the primary energy source for portable electronics. One pathway toward greater energy density is through the use of Li-rich layered oxides. The capacity of this class of materials (>270 milliampere hours per gram) has been s...

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Vydané v:	Science (American Association for the Advancement of Science) Ročník 350; číslo 6267; s. 1516 - 1521
Hlavní autori:	McCalla, Eric, Abakumov, Artem M, Saubanère, Matthieu, Foix, Dominique, Berg, Erik J, Rousse, Gwenaelle, Doublet, Marie-Liesse, Gonbeau, Danielle, Novák, Petr, Van Tendeloo, Gustaaf, Dominko, Robert, Tarascon, Jean-Marie
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	United States 18.12.2015
ISSN:	1095-9203
On-line prístup:	Zistit podrobnosti o prístupe
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Abstract	Lithium-ion (Li-ion) batteries that rely on cationic redox reactions are the primary energy source for portable electronics. One pathway toward greater energy density is through the use of Li-rich layered oxides. The capacity of this class of materials (>270 milliampere hours per gram) has been shown to be nested in anionic redox reactions, which are thought to form peroxo-like species. However, the oxygen-oxygen (O-O) bonding pattern has not been observed in previous studies, nor has there been a satisfactory explanation for the irreversible changes that occur during first delithiation. By using Li2IrO3 as a model compound, we visualize the O-O dimers via transmission electron microscopy and neutron diffraction. Our findings establish the fundamental relation between the anionic redox process and the evolution of the O-O bonding in layered oxides.
AbstractList	Lithium-ion (Li-ion) batteries that rely on cationic redox reactions are the primary energy source for portable electronics. One pathway toward greater energy density is through the use of Li-rich layered oxides. The capacity of this class of materials (>270 milliampere hours per gram) has been shown to be nested in anionic redox reactions, which are thought to form peroxo-like species. However, the oxygen-oxygen (O-O) bonding pattern has not been observed in previous studies, nor has there been a satisfactory explanation for the irreversible changes that occur during first delithiation. By using Li2IrO3 as a model compound, we visualize the O-O dimers via transmission electron microscopy and neutron diffraction. Our findings establish the fundamental relation between the anionic redox process and the evolution of the O-O bonding in layered oxides.
Author	Berg, Erik J Novák, Petr McCalla, Eric Tarascon, Jean-Marie Saubanère, Matthieu Abakumov, Artem M Van Tendeloo, Gustaaf Foix, Dominique Doublet, Marie-Liesse Gonbeau, Danielle Dominko, Robert Rousse, Gwenaelle
Author_xml	– sequence: 1 givenname: Eric surname: McCalla fullname: McCalla, Eric organization: Collège de France, Chimie du Solide et de l'Energie, FRE 3677, 11 Place Marcelin Berthelot, 75231 Paris Cedex 05, France. ALISTORE-European Research Institute, FR CNRS 3104, 80039 Amiens, France. Réseau sur le Stockage Electrochimique de l'Energie (RS2E), FR CNRS 3459, France. National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana, Slovenia – sequence: 2 givenname: Artem M surname: Abakumov fullname: Abakumov, Artem M organization: Electron Microscopy for Materials Science (EMAT), University of Antwerp, Groenenborgerlaan 171, B-2020, Antwerp, Belgium. Center for Electrochemical Energy Storage, Skolkovo Institute of Science and Technology, 3 Nobel Street, 143026 Moscow, Russia – sequence: 3 givenname: Matthieu surname: Saubanère fullname: Saubanère, Matthieu organization: ALISTORE-European Research Institute, FR CNRS 3104, 80039 Amiens, France. Réseau sur le Stockage Electrochimique de l'Energie (RS2E), FR CNRS 3459, France. Institut Charles Gerhardt, CNRS UMR 5253, Université Montpellier, Place Eugène Bataillon, 34 095 Montpellier, France – sequence: 4 givenname: Dominique surname: Foix fullname: Foix, Dominique organization: ALISTORE-European Research Institute, FR CNRS 3104, 80039 Amiens, France. Réseau sur le Stockage Electrochimique de l'Energie (RS2E), FR CNRS 3459, France. IPREM/ECP (UMR 5254), University of Pau, 2 Avenue Pierre Angot, 64053 Pau Cedex 9, France – sequence: 5 givenname: Erik J surname: Berg fullname: Berg, Erik J organization: Electrochemistry Laboratory, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland – sequence: 6 givenname: Gwenaelle surname: Rousse fullname: Rousse, Gwenaelle organization: Collège de France, Chimie du Solide et de l'Energie, FRE 3677, 11 Place Marcelin Berthelot, 75231 Paris Cedex 05, France. Réseau sur le Stockage Electrochimique de l'Energie (RS2E), FR CNRS 3459, France. Sorbonne Universités-UPMC Univ Paris 06, 4 Place Jussieu, F-75005 Paris, France – sequence: 7 givenname: Marie-Liesse surname: Doublet fullname: Doublet, Marie-Liesse organization: ALISTORE-European Research Institute, FR CNRS 3104, 80039 Amiens, France. Réseau sur le Stockage Electrochimique de l'Energie (RS2E), FR CNRS 3459, France. Institut Charles Gerhardt, CNRS UMR 5253, Université Montpellier, Place Eugène Bataillon, 34 095 Montpellier, France – sequence: 8 givenname: Danielle surname: Gonbeau fullname: Gonbeau, Danielle organization: ALISTORE-European Research Institute, FR CNRS 3104, 80039 Amiens, France. Réseau sur le Stockage Electrochimique de l'Energie (RS2E), FR CNRS 3459, France. IPREM/ECP (UMR 5254), University of Pau, 2 Avenue Pierre Angot, 64053 Pau Cedex 9, France – sequence: 9 givenname: Petr surname: Novák fullname: Novák, Petr organization: Electrochemistry Laboratory, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland – sequence: 10 givenname: Gustaaf surname: Van Tendeloo fullname: Van Tendeloo, Gustaaf organization: Electron Microscopy for Materials Science (EMAT), University of Antwerp, Groenenborgerlaan 171, B-2020, Antwerp, Belgium – sequence: 11 givenname: Robert surname: Dominko fullname: Dominko, Robert organization: National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana, Slovenia – sequence: 12 givenname: Jean-Marie surname: Tarascon fullname: Tarascon, Jean-Marie email: jean-marie.tarascon@college-de-france.fr organization: Collège de France, Chimie du Solide et de l'Energie, FRE 3677, 11 Place Marcelin Berthelot, 75231 Paris Cedex 05, France. ALISTORE-European Research Institute, FR CNRS 3104, 80039 Amiens, France. Réseau sur le Stockage Electrochimique de l'Energie (RS2E), FR CNRS 3459, France. Sorbonne Universités-UPMC Univ Paris 06, 4 Place Jussieu, F-75005 Paris, France. jean-marie.tarascon@college-de-france.fr
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Snippet	Lithium-ion (Li-ion) batteries that rely on cationic redox reactions are the primary energy source for portable electronics. One pathway toward greater energy...
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Title	Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries
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