A cross-dehydrogenative C(sp3)−H heteroarylation via photo-induced catalytic chlorine radical generation

Hydrogen atom abstraction (HAT) from C( sp 3 )–H bonds of naturally abundant alkanes for alkyl radical generation represents a promising yet underexplored strategy in the alkylation reaction designs since involving stoichiometric oxidants, excessive alkane loading, and limited scope are common drawb...

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Bibliographic Details
Published in:	Nature communications Vol. 12; no. 1; pp. 4010 - 9
Main Authors:	Huang, Chia-Yu, Li, Jianbin, Li, Chao-Jun
Format:	Journal Article
Language:	English
Published:	London Nature Publishing Group UK 29.06.2021 Nature Publishing Group Nature Portfolio
Subjects:	639/638/549/933 639/638/77/888 Alkanes Alkylation Catalysts Chemistry Chlorides Chlorine Cobalt Couplings Dehydrogenation Design Humanities and Social Sciences Hydrogen Hydrogen bonds Hydrogen evolution Ligands multidisciplinary Oxidants Oxidation Oxidizing agents Radicals Science Science (multidisciplinary) Solvents Substrates
ISSN:	2041-1723, 2041-1723
Online Access:	Get full text
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