Molecular Cobalt Clusters as Precursors of Distinct Active Species in Electrochemical, Photochemical, and Photoelectrochemical Water Oxidation Reactions in Phosphate Electrolytes

Three cobalt model molecular compounds, Co‐cubane ([Co4(µ3‐O)4(µ‐OAc)4py4]), Co‐trimer ([Co3(μ3‐O)(µ‐OAc)6py3]PF6), and Co‐dimer ([Co2(μ‐OH)2(µ‐OAc)(OAc)2py4]PF6), are investigated as water oxidation reaction (WOR) catalysts, using electrochemical, photochemical, and photoelectrochemical methodologi...

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Vydané v:	Chemistry : a European journal Ročník 21; číslo 46; s. 16578 - 16584
Hlavní autori:	Li, Xiaobo, Clatworthy, Edwin B., Masters, Anthony F., Maschmeyer, Thomas
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	Weinheim WILEY-VCH Verlag 09.11.2015 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Predmet:	Carbon dioxide Catalysis Catalysts Catalytic activity Chemical reactions Chemistry Cobalt Cobalt compounds cobalt oxide Cubane Dimers Electrochemistry Electrolytes Oxidation oxygen evolution Photochemical Photochemicals Precursors Species Trimers water oxidation cobalt electrochemistry water oxidation oxygen evolution cobalt oxide cubane
ISSN:	0947-6539, 1521-3765
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Abstract	Three cobalt model molecular compounds, Co‐cubane ([Co4(µ3‐O)4(µ‐OAc)4py4]), Co‐trimer ([Co3(μ3‐O)(µ‐OAc)6py3]PF6), and Co‐dimer ([Co2(μ‐OH)2(µ‐OAc)(OAc)2py4]PF6), are investigated as water oxidation reaction (WOR) catalysts, using electrochemical, photochemical, and photoelectrochemical methodologies in phosphate electrolyte. The actual species contributing to the catalytic activity observed in the WOR are derived from the transformation of these cobalt compounds. The catalytic activity observed is highly dependent on the initial compound structure and on the particular WOR methodology used. Co‐cubane shows no activity in the electrochemical WOR and negligible activity in the photochemical WOR, but is active in the photoelectrochemical WOR, in which it behaves as a precursor to catalytically active species. Co‐dimer also shows no activity in the electrochemical WOR, but behaves as a precursor to catalytically active species in both the photochemical and photoelectrochemical WOR experiments. Co‐trimer behaves as a precursor to catalytically active species in all three of the WOR methodologies. Cobalt catalysts: The cobalt species derived in situ from the three molecular cobalt compounds, Co‐cubane, Co‐trimer, and Co‐dimer, are found to be the actual catalytic species for the observed water oxidation activity in three water oxidation methodologies (electrochemical, photochemical, and photoelectrochemical). However, the ability to form active species from the cobalt precursors is highly dependent on their structure and the water oxidation reaction (WOR) protocols, as shown in the figure.
AbstractList	Three cobalt model molecular compounds, Co‐cubane ([Co4(µ3‐O)4(µ‐OAc)4py4]), Co‐trimer ([Co3(μ3‐O)(µ‐OAc)6py3]PF6), and Co‐dimer ([Co2(μ‐OH)2(µ‐OAc)(OAc)2py4]PF6), are investigated as water oxidation reaction (WOR) catalysts, using electrochemical, photochemical, and photoelectrochemical methodologies in phosphate electrolyte. The actual species contributing to the catalytic activity observed in the WOR are derived from the transformation of these cobalt compounds. The catalytic activity observed is highly dependent on the initial compound structure and on the particular WOR methodology used. Co‐cubane shows no activity in the electrochemical WOR and negligible activity in the photochemical WOR, but is active in the photoelectrochemical WOR, in which it behaves as a precursor to catalytically active species. Co‐dimer also shows no activity in the electrochemical WOR, but behaves as a precursor to catalytically active species in both the photochemical and photoelectrochemical WOR experiments. Co‐trimer behaves as a precursor to catalytically active species in all three of the WOR methodologies. Cobalt catalysts: The cobalt species derived in situ from the three molecular cobalt compounds, Co‐cubane, Co‐trimer, and Co‐dimer, are found to be the actual catalytic species for the observed water oxidation activity in three water oxidation methodologies (electrochemical, photochemical, and photoelectrochemical). However, the ability to form active species from the cobalt precursors is highly dependent on their structure and the water oxidation reaction (WOR) protocols, as shown in the figure. Three cobalt model molecular compounds, Co‐cubane ([Co 4 (µ 3 ‐O) 4 (µ‐OAc) 4 py 4 ]), Co‐trimer ([Co 3 (μ 3 ‐O)(µ‐OAc) 6 py 3 ]PF 6 ), and Co‐dimer ([Co 2 (μ‐OH) 2 (µ‐OAc)(OAc) 2 py 4 ]PF 6 ), are investigated as water oxidation reaction (WOR) catalysts, using electrochemical, photochemical, and photoelectrochemical methodologies in phosphate electrolyte. The actual species contributing to the catalytic activity observed in the WOR are derived from the transformation of these cobalt compounds. The catalytic activity observed is highly dependent on the initial compound structure and on the particular WOR methodology used. Co‐cubane shows no activity in the electrochemical WOR and negligible activity in the photochemical WOR, but is active in the photoelectrochemical WOR, in which it behaves as a precursor to catalytically active species. Co‐dimer also shows no activity in the electrochemical WOR, but behaves as a precursor to catalytically active species in both the photochemical and photoelectrochemical WOR experiments. Co‐trimer behaves as a precursor to catalytically active species in all three of the WOR methodologies. Three cobalt model molecular compounds, Co-cubane ([Co4 (µ3 -O)4 (µ-OAc)4 py4 ]), Co-trimer ([Co3 (μ3 -O)(µ-OAc)6 py3 ]PF6 ), and Co-dimer ([Co2 (μ-OH)2 (µ-OAc)(OAc)2 py4 ]PF6 ), are investigated as water oxidation reaction (WOR) catalysts, using electrochemical, photochemical, and photoelectrochemical methodologies in phosphate electrolyte. The actual species contributing to the catalytic activity observed in the WOR are derived from the transformation of these cobalt compounds. The catalytic activity observed is highly dependent on the initial compound structure and on the particular WOR methodology used. Co-cubane shows no activity in the electrochemical WOR and negligible activity in the photochemical WOR, but is active in the photoelectrochemical WOR, in which it behaves as a precursor to catalytically active species. Co-dimer also shows no activity in the electrochemical WOR, but behaves as a precursor to catalytically active species in both the photochemical and photoelectrochemical WOR experiments. Co-trimer behaves as a precursor to catalytically active species in all three of the WOR methodologies. Three cobalt model molecular compounds, Co-cubane ([Co4(µ3-O)4(µ-OAc)4py4]), Co-trimer ([Co3(µ3-O)(µ-OAc)6py3]PF6), and Co-dimer ([Co2(µ-OH)2(µ-OAc)(OAc)2py4]PF6), are investigated as water oxidation reaction (WOR) catalysts, using electrochemical, photochemical, and photoelectrochemical methodologies in phosphate electrolyte. The actual species contributing to the catalytic activity observed in the WOR are derived from the transformation of these cobalt compounds. The catalytic activity observed is highly dependent on the initial compound structure and on the particular WOR methodology used. Co-cubane shows no activity in the electrochemical WOR and negligible activity in the photochemical WOR, but is active in the photoelectrochemical WOR, in which it behaves as a precursor to catalytically active species. Co-dimer also shows no activity in the electrochemical WOR, but behaves as a precursor to catalytically active species in both the photochemical and photoelectrochemical WOR experiments. Co-trimer behaves as a precursor to catalytically active species in all three of the WOR methodologies. Three cobalt model molecular compounds, Co-cubane ([Co sub(4)( mu sub(3)-O) sub(4)( mu -OAc) sub(4)py sub(4)]), Co-trimer ([Co sub(3)( mu sub(3)-O)( mu -OAc) sub(6)py sub(3)]PF sub(6)), and Co-dimer ([Co sub(2)( mu -OH) sub(2)( mu -OAc)(OAc) sub(2)py sub(4)] PF sub(6)), are investigated as water oxidation reaction (WOR) catalysts, using electrochemical, photochemical, and photoelectrochemical methodologies in phosphate electrolyte. The actual species contributing to the catalytic activity observed in the WOR are derived from the transformation of these cobalt compounds. The catalytic activity observed is highly dependent on the initial compound structure and on the particular WOR methodology used. Co-cubane shows no activity in the electrochemical WOR and negligible activity in the photochemical WOR, but is active in the photoelectrochemical WOR, in which it behaves as a precursor to catalytically active species. Co-dimer also shows no activity in the electrochemical WOR, but behaves as a precursor to catalytically active species in both the photochemical and photoelectrochemical WOR experiments. Co-trimer behaves as a precursor to catalytically active species in all three of the WOR methodologies. Cobalt catalysts: The cobalt species derived insitu from the three molecular cobalt compounds, Co-cubane, Co-trimer, and Co-dimer, are found to be the actual catalytic species for the observed water oxidation activity in three water oxidation methodologies (electrochemical, photochemical, and photoelectrochemical). However, the ability to form active species from the cobalt precursors is highly dependent on their structure and the water oxidation reaction (WOR) protocols, as shown in the figure. Three cobalt model molecular compounds, Co‐cubane ([Co4(µ3‐O)4(µ‐OAc)4py4]), Co‐trimer ([Co3(μ3‐O)(µ‐OAc)6py3]PF6), and Co‐dimer ([Co2(μ‐OH)2(µ‐OAc)(OAc)2py4]PF6), are investigated as water oxidation reaction (WOR) catalysts, using electrochemical, photochemical, and photoelectrochemical methodologies in phosphate electrolyte. The actual species contributing to the catalytic activity observed in the WOR are derived from the transformation of these cobalt compounds. The catalytic activity observed is highly dependent on the initial compound structure and on the particular WOR methodology used. Co‐cubane shows no activity in the electrochemical WOR and negligible activity in the photochemical WOR, but is active in the photoelectrochemical WOR, in which it behaves as a precursor to catalytically active species. Co‐dimer also shows no activity in the electrochemical WOR, but behaves as a precursor to catalytically active species in both the photochemical and photoelectrochemical WOR experiments. Co‐trimer behaves as a precursor to catalytically active species in all three of the WOR methodologies.
Author	Clatworthy, Edwin B. Maschmeyer, Thomas Masters, Anthony F. Li, Xiaobo
Author_xml	– sequence: 1 givenname: Xiaobo surname: Li fullname: Li, Xiaobo organization: Laboratory of Advanced Catalysis for Sustainability, School of Chemistry, University of Sydney, Sydney NSW, 2006 (Australia), Fax: (+61) 2-9351-3329 – sequence: 2 givenname: Edwin B. surname: Clatworthy fullname: Clatworthy, Edwin B. organization: Laboratory of Advanced Catalysis for Sustainability, School of Chemistry, University of Sydney, Sydney NSW, 2006 (Australia), Fax: (+61) 2-9351-3329 – sequence: 3 givenname: Anthony F. surname: Masters fullname: Masters, Anthony F. organization: Laboratory of Advanced Catalysis for Sustainability, School of Chemistry, University of Sydney, Sydney NSW, 2006 (Australia), Fax: (+61) 2-9351-3329 – sequence: 4 givenname: Thomas surname: Maschmeyer fullname: Maschmeyer, Thomas email: th.maschmeyer@chem.usyd.edu.au organization: Laboratory of Advanced Catalysis for Sustainability, School of Chemistry, University of Sydney, Sydney NSW, 2006 (Australia), Fax: (+61) 2-9351-3329
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Cites_doi	10.1126/science.1185372 10.1002/anie.201107625 10.1021/ic402720p 10.1038/nchem.1049 10.1016/0277-5387(95)00489-0 10.1021/cr4004874 10.1039/C2CS35225G 10.1021/cm5025074 10.1021/ar900249x 10.1021/ic0345525 10.1021/ja412886e 10.1002/ange.200801132 10.1038/nature09913 10.1039/C2CS35287G 10.1021/ja00329a022 10.1016/S0277-5387(96)00498-6 10.1021/cr400572f 10.1002/ange.201107625 10.1021/ja203877y 10.1021/ja900023k 10.1021/ja0005587 10.1002/anie.200801132 10.1016/S0277-5387(97)00300-8 10.1039/C1FD00093D 10.1021/ja205569j 10.1126/science.1162018 10.1021/ja3000084 10.1021/jp511805x 10.1039/C2CS35334B 10.1021/ja1023767 10.1021/ja5110393 10.1021/ja303951z 10.1021/ja4024868 10.1021/ja109681d 10.1021/cs401109u 10.1021/ic00281a004 10.1021/ja4053448 10.1021/ic7011759
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Keywords	cobalt electrochemistry water oxidation oxygen evolution cobalt oxide cubane
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References	B. Zhang, F. Li, F. Yu, X. Wang, X. Zhou, H. Li, Y. Jiang, L. Sun, ACS Catal. 2014, 4, 804-809. G. P. Gardner, Y. B. Go, D. M. Robinson, P. F. Smith, J. Hadermann, A. Abakumov, M. Greenblatt, G. C. Dismukes, Angew. Chem. Int. Ed. 2012, 51, 1616-1619 Angew. Chem. 2008, 120, 7445-7448 X. Li, P. E. M. Siegbahn, J. Am. Chem. Soc. 2013, 135, 13804-13813 J. K. Beattie, T. W. Hambley, J. A. Klepetko, A. F. Masters, P. Turner, Polyhedron 1997, 16, 2109-2112. Y. Umena, K. Kawakami, J. R. Shen, N. Kamiya, Nature 2011, 473, 55-U65 R. K. Hocking, R. Brimblecombe, L.-Y. Chang, A. Singh, M. H. Cheah, C. Glover, W. H. Casey, L. Spiccia, Nat. Chem. 2011, 3, 461-466. X.-B. Han, Z.-M. Zhang, T. Zhang, Y.-G. Li, W. Lin, W. You, Z.-M. Su, E.-B. Wang, J. Am. Chem. Soc. 2014, 136, 5359-5366 Z. Huang, Z. Luo, Y. V. Geletii, J. W. Vickers, Q. Yin, D. Wu, Y. Hou, Y. Ding, J. Song, D. G. Musaev, C. L. Hill, T. Lian, J. Am. Chem. Soc. 2011, 133, 2068-2071 R. Chakrabarty, S. J. Bora, B. K. Das, Inorg. Chem. 2007, 46, 9450-9462 J. K. Beattie, T. W. Hambley, J. A. Klepetko, A. F. Masters, P. Turner, Polyhedron 1996, 15, 2141-2150. Y. Surendranath, D. A. Lutterman, Y. Liu, D. G. Nocera, J. Am. Chem. Soc. 2012, 134, 6326-6336. Q. S. Yin, J. M. Tan, C. Besson, Y. V. Geletii, D. G. Musaev, A. E. Kuznetsov, Z. Luo, K. I. Hardcastle, C. L. Hill, Science 2010, 328, 342-345 M. D. Kärkäs, O. Verho, E. V. Johnston, B. Åkermark, Chem. Rev. 2014, 114, 11863-12001. P. K. Ghosh, B. S. Brunschwig, M. Chou, C. Creutz, N. Sutin, J. Am. Chem. Soc. 1984, 106, 4772-4783. A. M. Ullman, Y. Liu, M. Huynh, D. K. Bediako, H. Wang, B. L. Anderson, D. C. Powers, J. J. Breen, H. D. Abruña, D. G. Nocera, J. Am. Chem. Soc. 2014, 136, 17681-17688 V. Artero, M. Fontecave, Chem. Soc. Rev. 2013, 42, 2338-2356 W. Ruettinger, M. Yagi, K. Wolf, S. Bernasek, G. C. Dismukes, J. Am. Chem. Soc. 2000, 122, 10353-10357 S. Berardi, G. La Ganga, M. Natali, I. Bazzan, F. Puntoriero, A. Sartorel, F. Scandola, S. Campagna, M. Bonchio, J. Am. Chem. Soc. 2012, 134, 11104-11107 J. K. Beattie, C. U. Beck, P. A. Lay, A. F. Masters, Inorg. Chem. 2003, 42, 8366-8370. M. W. Kanan, D. G. Nocera, Science 2008, 321, 1072-1075. C. E. Sumner, Inorg. Chem. 1988, 27, 1320-1327 J. K. Beattie, T. W. Hambley, J. A. Klepetko, A. F. Masters, P. Turner, Polyhedron 1998, 17, 1343-1354. D. A. Lutterman, Y. Surendranath, D. G. Nocera, J. Am. Chem. Soc. 2009, 131, 3838-3939. G. La Ganga, F. Puntoriero, S. Campagna, I. Bazzan, S. Berardi, M. Bonchio, A. Sartorel, M. Natali, F. Scandola, Faraday Discuss. 2012, 155, 177-190 N. S. McCool, D. M. Robinson, J. E. Sheats, G. C. Dismukes, J. Am. Chem. Soc. 2011, 133, 11446-11449 Angew. Chem. 2012, 124, 1648-1651 J. J. Stracke, R. G. Finke, J. Am. Chem. Soc. 2011, 133, 14872-14875 A. R. Parent, R. H. Crabtree, G. W. Brudvig, Chem. Soc. Rev. 2013, 42, 2247-2252. J. W. Vickers, H. Lv, J. M. Sumliner, G. Zhu, Z. Luo, D. G. Musaev, Y. V. Geletii, C. L. Hill, J. Am. Chem. Soc. 2013, 135, 14110-14118. A. Fernando, C. M. Aikens, J. Phys. Chem. C 2015, 119, 11072-11085. R. Brimblecombe, G. F. Swiegers, G. C. Dismukes, L. Spiccia, Angew. Chem. Int. Ed. 2008, 47, 7335-7338 J. Yano, V. Yachandra, Chem. Rev. 2014, 114, 4175-4205. A. Sartorel, M. Bonchio, S. Campagna, F. Scandola, Chem. Soc. Rev. 2013, 42, 2262-2280 P. F. Smith, C. Kaplan, J. E. Sheats, D. M. Robinson, N. S. McCool, N. Mezle, G. C. Dismukes, Inorg. Chem. 2014, 53, 2113-2121. G. C. Dismukes, R. Brimblecombe, G. A. N. Felton, R. S. Pryadun, J. E. Sheats, L. Spiccia, G. F. Swiegers, Acc. Chem. Res. 2009, 42, 1935-1943 J. K. Cooper, S. Gul, F. M. Toma, L. Chen, P.-A. Glans, J. Guo, J. W. Ager, J. Yano, I. D. Sharp, Chem. Mater. 2014, 26, 5365-5373. M. W. Kanan, J. Yano, Y. Surendranath, M. Dinca, V. K. Yachandra, D. G. Nocera, J. Am. Chem. Soc. 2010, 132, 13692-13701. 2009; 42 2010; 328 1984; 106 2013; 42 2014; 26 2008 2008; 47 120 2009; 131 2008; 321 2011; 3 1996; 15 2014; 114 2014; 136 2011; 133 2011; 473 1998; 17 2012; 155 2014; 4 2012; 134 2012 2012; 51 124 1988; 27 2010; 132 2013; 135 1997; 16 2015; 119 2000; 122 2007; 46 2003; 42 2014; 53 e_1_2_5_26_2 e_1_2_5_27_2 e_1_2_5_24_2 e_1_2_5_24_3 e_1_2_5_25_2 e_1_2_5_22_2 e_1_2_5_23_2 e_1_2_5_44_2 e_1_2_5_20_2 e_1_2_5_43_2 e_1_2_5_21_2 e_1_2_5_42_2 e_1_2_5_28_2 e_1_2_5_29_2 e_1_2_5_41_2 e_1_2_5_40_2 e_1_2_5_14_2 e_1_2_5_37_2 e_1_2_5_13_2 e_1_2_5_38_2 e_1_2_5_9_2 e_1_2_5_16_2 e_1_2_5_35_2 e_1_2_5_7_3 e_1_2_5_8_2 e_1_2_5_15_2 e_1_2_5_36_2 e_1_2_5_7_2 e_1_2_5_10_2 e_1_2_5_33_2 e_1_2_5_6_2 e_1_2_5_34_2 e_1_2_5_5_2 e_1_2_5_12_2 e_1_2_5_31_2 e_1_2_5_4_2 e_1_2_5_11_2 e_1_2_5_32_2 e_1_2_5_3_2 e_1_2_5_2_2 e_1_2_5_1_2 e_1_2_5_18_2 e_1_2_5_17_2 e_1_2_5_39_2 e_1_2_5_19_2 e_1_2_5_30_2
References_xml	– reference: Angew. Chem. 2012, 124, 1648-1651; – reference: M. W. Kanan, D. G. Nocera, Science 2008, 321, 1072-1075. – reference: M. W. Kanan, J. Yano, Y. Surendranath, M. Dinca, V. K. Yachandra, D. G. Nocera, J. Am. Chem. Soc. 2010, 132, 13692-13701. – reference: J. W. Vickers, H. Lv, J. M. Sumliner, G. Zhu, Z. Luo, D. G. Musaev, Y. V. Geletii, C. L. Hill, J. Am. Chem. Soc. 2013, 135, 14110-14118. – reference: A. R. Parent, R. H. Crabtree, G. W. Brudvig, Chem. Soc. Rev. 2013, 42, 2247-2252. – reference: X. Li, P. E. M. Siegbahn, J. Am. Chem. Soc. 2013, 135, 13804-13813; – reference: J. K. Beattie, T. W. Hambley, J. A. Klepetko, A. F. Masters, P. Turner, Polyhedron 1997, 16, 2109-2112. – reference: N. S. McCool, D. M. Robinson, J. E. Sheats, G. C. Dismukes, J. Am. Chem. Soc. 2011, 133, 11446-11449; – reference: Z. Huang, Z. Luo, Y. V. Geletii, J. W. Vickers, Q. Yin, D. Wu, Y. Hou, Y. Ding, J. Song, D. G. Musaev, C. L. Hill, T. Lian, J. Am. Chem. Soc. 2011, 133, 2068-2071; – reference: G. C. Dismukes, R. Brimblecombe, G. A. N. Felton, R. S. Pryadun, J. E. Sheats, L. Spiccia, G. F. Swiegers, Acc. Chem. Res. 2009, 42, 1935-1943; – reference: V. Artero, M. Fontecave, Chem. Soc. Rev. 2013, 42, 2338-2356; – reference: G. P. Gardner, Y. B. Go, D. M. Robinson, P. F. Smith, J. Hadermann, A. Abakumov, M. Greenblatt, G. C. Dismukes, Angew. Chem. Int. Ed. 2012, 51, 1616-1619; – reference: R. K. Hocking, R. Brimblecombe, L.-Y. Chang, A. Singh, M. H. Cheah, C. Glover, W. H. Casey, L. Spiccia, Nat. Chem. 2011, 3, 461-466. – reference: J. J. Stracke, R. G. Finke, J. Am. Chem. Soc. 2011, 133, 14872-14875; – reference: J. K. Cooper, S. Gul, F. M. Toma, L. Chen, P.-A. Glans, J. Guo, J. W. Ager, J. Yano, I. D. Sharp, Chem. Mater. 2014, 26, 5365-5373. – reference: P. F. Smith, C. Kaplan, J. E. Sheats, D. M. Robinson, N. S. McCool, N. Mezle, G. C. Dismukes, Inorg. Chem. 2014, 53, 2113-2121. – reference: Q. S. Yin, J. M. Tan, C. Besson, Y. V. Geletii, D. G. Musaev, A. E. Kuznetsov, Z. Luo, K. I. Hardcastle, C. L. Hill, Science 2010, 328, 342-345; – reference: X.-B. Han, Z.-M. Zhang, T. Zhang, Y.-G. Li, W. Lin, W. You, Z.-M. Su, E.-B. Wang, J. Am. Chem. Soc. 2014, 136, 5359-5366; – reference: D. A. Lutterman, Y. Surendranath, D. G. Nocera, J. Am. Chem. Soc. 2009, 131, 3838-3939. – reference: Angew. Chem. 2008, 120, 7445-7448; – reference: W. Ruettinger, M. Yagi, K. Wolf, S. Bernasek, G. C. Dismukes, J. Am. Chem. Soc. 2000, 122, 10353-10357; – reference: A. M. Ullman, Y. Liu, M. Huynh, D. K. Bediako, H. Wang, B. L. Anderson, D. C. Powers, J. J. Breen, H. D. Abruña, D. G. Nocera, J. Am. Chem. Soc. 2014, 136, 17681-17688; – reference: R. Chakrabarty, S. J. Bora, B. K. Das, Inorg. Chem. 2007, 46, 9450-9462; – reference: J. Yano, V. Yachandra, Chem. Rev. 2014, 114, 4175-4205. – reference: J. K. Beattie, T. W. Hambley, J. A. Klepetko, A. F. Masters, P. Turner, Polyhedron 1996, 15, 2141-2150. – reference: J. K. Beattie, C. U. Beck, P. A. Lay, A. F. Masters, Inorg. Chem. 2003, 42, 8366-8370. – reference: J. K. Beattie, T. W. Hambley, J. A. Klepetko, A. F. Masters, P. Turner, Polyhedron 1998, 17, 1343-1354. – reference: C. E. Sumner, Inorg. Chem. 1988, 27, 1320-1327; – reference: A. Sartorel, M. Bonchio, S. Campagna, F. Scandola, Chem. Soc. Rev. 2013, 42, 2262-2280; – reference: R. Brimblecombe, G. F. Swiegers, G. C. Dismukes, L. Spiccia, Angew. Chem. Int. Ed. 2008, 47, 7335-7338; – reference: G. La Ganga, F. Puntoriero, S. Campagna, I. Bazzan, S. Berardi, M. Bonchio, A. Sartorel, M. Natali, F. Scandola, Faraday Discuss. 2012, 155, 177-190; – reference: A. Fernando, C. M. Aikens, J. Phys. Chem. C 2015, 119, 11072-11085. – reference: P. K. Ghosh, B. S. Brunschwig, M. Chou, C. Creutz, N. Sutin, J. Am. Chem. Soc. 1984, 106, 4772-4783. – reference: Y. Umena, K. Kawakami, J. R. Shen, N. Kamiya, Nature 2011, 473, 55-U65; – reference: S. Berardi, G. La Ganga, M. Natali, I. Bazzan, F. Puntoriero, A. Sartorel, F. Scandola, S. Campagna, M. Bonchio, J. Am. Chem. Soc. 2012, 134, 11104-11107; – reference: M. D. Kärkäs, O. Verho, E. V. Johnston, B. Åkermark, Chem. Rev. 2014, 114, 11863-12001. – reference: Y. Surendranath, D. A. Lutterman, Y. Liu, D. G. Nocera, J. Am. Chem. Soc. 2012, 134, 6326-6336. – reference: B. Zhang, F. Li, F. Yu, X. Wang, X. Zhou, H. Li, Y. Jiang, L. Sun, ACS Catal. 2014, 4, 804-809. – volume: 133 start-page: 11446 year: 2011 end-page: 11449 publication-title: J. Am. Chem. Soc. – volume: 328 start-page: 342 year: 2010 end-page: 345 publication-title: Science – volume: 133 start-page: 2068 year: 2011 end-page: 2071 publication-title: J. Am. Chem. Soc. – volume: 42 start-page: 8366 year: 2003 end-page: 8370 publication-title: Inorg. Chem. – volume: 135 start-page: 13804 year: 2013 end-page: 13813 publication-title: J. Am. Chem. Soc. – volume: 42 start-page: 1935 year: 2009 end-page: 1943 publication-title: Acc. Chem. Res. – volume: 46 start-page: 9450 year: 2007 end-page: 9462 publication-title: Inorg. Chem. – volume: 17 start-page: 1343 year: 1998 end-page: 1354 publication-title: Polyhedron – volume: 136 start-page: 5359 year: 2014 end-page: 5366 publication-title: J. Am. Chem. Soc. – volume: 51 124 start-page: 1616 1648 year: 2012 2012 end-page: 1619 1651 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 47 120 start-page: 7335 7445 year: 2008 2008 end-page: 7338 7448 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 42 start-page: 2262 year: 2013 end-page: 2280 publication-title: Chem. Soc. Rev. – volume: 131 start-page: 3838 year: 2009 end-page: 3939 publication-title: J. Am. Chem. Soc. – volume: 135 start-page: 14110 year: 2013 end-page: 14118 publication-title: J. Am. Chem. Soc. – volume: 134 start-page: 11104 year: 2012 end-page: 11107 publication-title: J. Am. Chem. Soc. – volume: 42 start-page: 2338 year: 2013 end-page: 2356 publication-title: Chem. Soc. Rev. – volume: 321 start-page: 1072 year: 2008 end-page: 1075 publication-title: Science – volume: 132 start-page: 13692 year: 2010 end-page: 13701 publication-title: J. Am. Chem. Soc. – volume: 114 start-page: 11863 year: 2014 end-page: 12001 publication-title: Chem. Rev. – volume: 473 start-page: 55 year: 2011 end-page: 65 publication-title: Nature – volume: 133 start-page: 14872 year: 2011 end-page: 14875 publication-title: J. Am. Chem. Soc. – volume: 3 start-page: 461 year: 2011 end-page: 466 publication-title: Nat. Chem. – volume: 134 start-page: 6326 year: 2012 end-page: 6336 publication-title: J. Am. Chem. Soc. – volume: 16 start-page: 2109 year: 1997 end-page: 2112 publication-title: Polyhedron – volume: 136 start-page: 17681 year: 2014 end-page: 17688 publication-title: J. Am. Chem. Soc. – volume: 106 start-page: 4772 year: 1984 end-page: 4783 publication-title: J. Am. Chem. Soc. – volume: 4 start-page: 804 year: 2014 end-page: 809 publication-title: ACS Catal. – volume: 53 start-page: 2113 year: 2014 end-page: 2121 publication-title: Inorg. Chem. – volume: 42 start-page: 2247 year: 2013 end-page: 2252 publication-title: Chem. Soc. Rev. – volume: 26 start-page: 5365 year: 2014 end-page: 5373 publication-title: Chem. Mater. – volume: 114 start-page: 4175 year: 2014 end-page: 4205 publication-title: Chem. Rev. – volume: 15 start-page: 2141 year: 1996 end-page: 2150 publication-title: Polyhedron – volume: 119 start-page: 11072 year: 2015 end-page: 11085 publication-title: J. Phys. Chem. C – volume: 122 start-page: 10353 year: 2000 end-page: 10357 publication-title: J. Am. Chem. Soc. – volume: 155 start-page: 177 year: 2012 end-page: 190 publication-title: Faraday Discuss. – volume: 27 start-page: 1320 year: 1988 end-page: 1327 publication-title: Inorg. Chem. – ident: e_1_2_5_19_2 – ident: e_1_2_5_6_2 doi: 10.1126/science.1185372 – ident: e_1_2_5_24_2 doi: 10.1002/anie.201107625 – ident: e_1_2_5_25_2 doi: 10.1021/ic402720p – ident: e_1_2_5_17_2 doi: 10.1038/nchem.1049 – ident: e_1_2_5_32_2 doi: 10.1016/0277-5387(95)00489-0 – ident: e_1_2_5_3_2 doi: 10.1021/cr4004874 – ident: e_1_2_5_39_2 doi: 10.1039/C2CS35225G – ident: e_1_2_5_41_2 doi: 10.1021/cm5025074 – ident: e_1_2_5_9_2 doi: 10.1021/ar900249x – ident: e_1_2_5_33_2 doi: 10.1021/ic0345525 – ident: e_1_2_5_8_2 doi: 10.1021/ja412886e – ident: e_1_2_5_7_3 doi: 10.1002/ange.200801132 – ident: e_1_2_5_2_2 doi: 10.1038/nature09913 – ident: e_1_2_5_5_2 doi: 10.1039/C2CS35287G – ident: e_1_2_5_40_2 doi: 10.1021/ja00329a022 – ident: e_1_2_5_35_2 doi: 10.1016/S0277-5387(96)00498-6 – ident: e_1_2_5_26_2 – ident: e_1_2_5_14_2 doi: 10.1021/cr400572f – ident: e_1_2_5_24_3 doi: 10.1002/ange.201107625 – ident: e_1_2_5_21_2 doi: 10.1021/ja203877y – ident: e_1_2_5_29_2 – ident: e_1_2_5_37_2 doi: 10.1021/ja900023k – ident: e_1_2_5_23_2 – ident: e_1_2_5_1_2 – ident: e_1_2_5_10_2 doi: 10.1021/ja0005587 – ident: e_1_2_5_7_2 doi: 10.1002/anie.200801132 – ident: e_1_2_5_18_2 doi: 10.1016/S0277-5387(97)00300-8 – ident: e_1_2_5_20_2 doi: 10.1039/C1FD00093D – ident: e_1_2_5_27_2 doi: 10.1021/ja205569j – ident: e_1_2_5_15_2 – ident: e_1_2_5_36_2 doi: 10.1126/science.1162018 – ident: e_1_2_5_34_2 doi: 10.1021/ja3000084 – ident: e_1_2_5_42_2 – ident: e_1_2_5_44_2 doi: 10.1021/jp511805x – ident: e_1_2_5_11_2 doi: 10.1039/C2CS35334B – ident: e_1_2_5_38_2 doi: 10.1021/ja1023767 – ident: e_1_2_5_16_2 doi: 10.1021/ja5110393 – ident: e_1_2_5_13_2 doi: 10.1021/ja303951z – ident: e_1_2_5_28_2 doi: 10.1021/ja4024868 – ident: e_1_2_5_12_2 doi: 10.1021/ja109681d – ident: e_1_2_5_22_2 doi: 10.1021/cs401109u – ident: e_1_2_5_31_2 doi: 10.1021/ic00281a004 – ident: e_1_2_5_43_2 doi: 10.1021/ja4053448 – ident: e_1_2_5_4_2 – ident: e_1_2_5_30_2 doi: 10.1021/ic7011759
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Snippet	Three cobalt model molecular compounds, Co‐cubane ([Co4(µ3‐O)4(µ‐OAc)4py4]), Co‐trimer ([Co3(μ3‐O)(µ‐OAc)6py3]PF6), and Co‐dimer... Three cobalt model molecular compounds, Co‐cubane ([Co 4 (µ 3 ‐O) 4 (µ‐OAc) 4 py 4 ]), Co‐trimer ([Co 3 (μ 3 ‐O)(µ‐OAc) 6 py 3 ]PF 6 ), and Co‐dimer ([Co 2... Three cobalt model molecular compounds, Co-cubane ([Co4 (µ3 -O)4 (µ-OAc)4 py4 ]), Co-trimer ([Co3 (μ3 -O)(µ-OAc)6 py3 ]PF6 ), and Co-dimer ([Co2 (μ-OH)2... Three cobalt model molecular compounds, Co-cubane ([Co4(µ3-O)4(µ-OAc)4py4]), Co-trimer ([Co3(µ3-O)(µ-OAc)6py3]PF6), and Co-dimer... Three cobalt model molecular compounds, Co-cubane ([Co sub(4)( mu sub(3)-O) sub(4)( mu -OAc) sub(4)py sub(4)]), Co-trimer ([Co sub(3)( mu sub(3)-O)( mu -OAc)...
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SubjectTerms	Carbon dioxide Catalysis Catalysts Catalytic activity Chemical reactions Chemistry Cobalt Cobalt compounds cobalt oxide Cubane Dimers Electrochemistry Electrolytes Oxidation oxygen evolution Photochemical Photochemicals Precursors Species Trimers water oxidation
Title	Molecular Cobalt Clusters as Precursors of Distinct Active Species in Electrochemical, Photochemical, and Photoelectrochemical Water Oxidation Reactions in Phosphate Electrolytes
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