Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM‐5

Non‐oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The application of this reaction in practical technology is hindered by a lack of understanding about the mechanism and nature of the active sites in be...

Full description

Saved in:

Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 57; no. 4; pp. 1016 - 1020
Main Authors:	Kosinov, Nikolay, Wijpkema, Alexandra S. G., Uslamin, Evgeny, Rohling, Roderigh, Coumans, Ferdy J. A. G., Mezari, Brahim, Parastaev, Alexander, Poryvaev, Artem S., Fedin, Matvey V., Pidko, Evgeny A., Hensen, Emiel J. M.
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 22.01.2018 John Wiley and Sons Inc
Edition:	International ed. in English
Subjects:	Benzene Catalysis Catalysts Communication Communications Deactivation dehydroaromatization Hydrocarbons Methane Mo/ZSM-5 Natural gas organocatalysis Spectroscopy Zeolites organocatalysis methane Mo/ZSM-5 dehydroaromatization hydrocarbons
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Abstract	Non‐oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The application of this reaction in practical technology is hindered by a lack of understanding about the mechanism and nature of the active sites in benchmark zeolite‐based Mo/ZSM‐5 catalysts, which precludes the solution of problems such as rapid catalyst deactivation. By applying spectroscopy and microscopy, it is shown that the active centers in Mo/ZSM‐5 are partially reduced single‐atom Mo sites stabilized by the zeolite framework. By combining a pulse reaction technique with isotope labeling of methane, MDA is shown to be governed by a hydrocarbon pool mechanism in which benzene is derived from secondary reactions of confined polyaromatic carbon species with the initial products of methane activation. Combined pulse reaction experiments, spectroscopy, microscopy, and isotopic labeling were carried out on zeolite Mo/ZSM‐5. It was shown that a hydrocarbon pool of polyaromatics confined in the zeolite pores is involved in the aromatization of methane over single‐site Mo/ZSM‐5 catalysts.
AbstractList	Non‐oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The application of this reaction in practical technology is hindered by a lack of understanding about the mechanism and nature of the active sites in benchmark zeolite‐based Mo/ZSM‐5 catalysts, which precludes the solution of problems such as rapid catalyst deactivation. By applying spectroscopy and microscopy, it is shown that the active centers in Mo/ZSM‐5 are partially reduced single‐atom Mo sites stabilized by the zeolite framework. By combining a pulse reaction technique with isotope labeling of methane, MDA is shown to be governed by a hydrocarbon pool mechanism in which benzene is derived from secondary reactions of confined polyaromatic carbon species with the initial products of methane activation. Non-oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The application of this reaction in practical technology is hindered by a lack of understanding about the mechanism and nature of the active sites in benchmark zeolite-based Mo/ZSM-5 catalysts, which precludes the solution of problems such as rapid catalyst deactivation. By applying spectroscopy and microscopy, it is shown that the active centers in Mo/ZSM-5 are partially reduced single-atom Mo sites stabilized by the zeolite framework. By combining a pulse reaction technique with isotope labeling of methane, MDA is shown to be governed by a hydrocarbon pool mechanism in which benzene is derived from secondary reactions of confined polyaromatic carbon species with the initial products of methane activation.Non-oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The application of this reaction in practical technology is hindered by a lack of understanding about the mechanism and nature of the active sites in benchmark zeolite-based Mo/ZSM-5 catalysts, which precludes the solution of problems such as rapid catalyst deactivation. By applying spectroscopy and microscopy, it is shown that the active centers in Mo/ZSM-5 are partially reduced single-atom Mo sites stabilized by the zeolite framework. By combining a pulse reaction technique with isotope labeling of methane, MDA is shown to be governed by a hydrocarbon pool mechanism in which benzene is derived from secondary reactions of confined polyaromatic carbon species with the initial products of methane activation. Non‐oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The application of this reaction in practical technology is hindered by a lack of understanding about the mechanism and nature of the active sites in benchmark zeolite‐based Mo/ZSM‐5 catalysts, which precludes the solution of problems such as rapid catalyst deactivation. By applying spectroscopy and microscopy, it is shown that the active centers in Mo/ZSM‐5 are partially reduced single‐atom Mo sites stabilized by the zeolite framework. By combining a pulse reaction technique with isotope labeling of methane, MDA is shown to be governed by a hydrocarbon pool mechanism in which benzene is derived from secondary reactions of confined polyaromatic carbon species with the initial products of methane activation. Combined pulse reaction experiments, spectroscopy, microscopy, and isotopic labeling were carried out on zeolite Mo/ZSM‐5. It was shown that a hydrocarbon pool of polyaromatics confined in the zeolite pores is involved in the aromatization of methane over single‐site Mo/ZSM‐5 catalysts.
Author	Fedin, Matvey V. Rohling, Roderigh Coumans, Ferdy J. A. G. Parastaev, Alexander Mezari, Brahim Poryvaev, Artem S. Pidko, Evgeny A. Kosinov, Nikolay Hensen, Emiel J. M. Wijpkema, Alexandra S. G. Uslamin, Evgeny
AuthorAffiliation	1 Laboratory of Inorganic Materials Chemistry Eindhoven University of Technology PO Box 513, 5600 MB Eindhoven The Netherlands 2 International Tomography Center SB RAS and Novosibirsk State University Novosibirsk 630090 Russia
AuthorAffiliation_xml	– name: 2 International Tomography Center SB RAS and Novosibirsk State University Novosibirsk 630090 Russia – name: 1 Laboratory of Inorganic Materials Chemistry Eindhoven University of Technology PO Box 513, 5600 MB Eindhoven The Netherlands
Author_xml	– sequence: 1 givenname: Nikolay orcidid: 0000-0001-8520-4886 surname: Kosinov fullname: Kosinov, Nikolay email: N.A.Kosinov@tue.nl organization: Eindhoven University of Technology – sequence: 2 givenname: Alexandra S. G. surname: Wijpkema fullname: Wijpkema, Alexandra S. G. organization: Eindhoven University of Technology – sequence: 3 givenname: Evgeny orcidid: 0000-0001-5454-9582 surname: Uslamin fullname: Uslamin, Evgeny organization: Eindhoven University of Technology – sequence: 4 givenname: Roderigh surname: Rohling fullname: Rohling, Roderigh organization: Eindhoven University of Technology – sequence: 5 givenname: Ferdy J. A. G. orcidid: 0000-0002-9949-3057 surname: Coumans fullname: Coumans, Ferdy J. A. G. organization: Eindhoven University of Technology – sequence: 6 givenname: Brahim surname: Mezari fullname: Mezari, Brahim organization: Eindhoven University of Technology – sequence: 7 givenname: Alexander surname: Parastaev fullname: Parastaev, Alexander organization: Eindhoven University of Technology – sequence: 8 givenname: Artem S. surname: Poryvaev fullname: Poryvaev, Artem S. organization: Novosibirsk State University – sequence: 9 givenname: Matvey V. orcidid: 0000-0002-0537-5755 surname: Fedin fullname: Fedin, Matvey V. organization: Novosibirsk State University – sequence: 10 givenname: Evgeny A. orcidid: 0000-0001-9242-9901 surname: Pidko fullname: Pidko, Evgeny A. organization: Eindhoven University of Technology – sequence: 11 givenname: Emiel J. M. orcidid: 0000-0002-9754-2417 surname: Hensen fullname: Hensen, Emiel J. M. email: E.J.M.Hensen@tue.nl organization: Eindhoven University of Technology
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/29181863$$D View this record in MEDLINE/PubMed
BookMark	eNqFkU1v1DAQhi1URD_gyhFF4sIlW48dJ84FqVpaWKlbDsCFi-Uk466rrF2cbKvtqT-B38gvYcqWLVRCHCx_zPOOZ-bdZzshBmTsJfAJcC4ObfA4ERwqAF7rJ2wPlIBcVpXcoXMhZV5pBbtsfxguiNeal8_YrqhBgy7lHptNY3A-YJdNbWpiyObYeTv6cJ69w8W6S9GmuKSHG1oUjo6IcWEDZvEKUzaPh18_zX_cflfP2VNn-wFf3O8H7MvJ8efph_z04_vZ9Og0b1UFOkdVFA1KXlioGqEV76Sz0NbQliVqLTveONGBdLp1rpRNB40t6I5Yybp0Vh6wt5u8l6tmiV2LYUy2N5fJL21am2i9-TsS_MKcxyujtOCVEpTgzX2CFL-tcBjN0g8t9j01FVeDgbqsa0EjBEJfP0Iv4ioFao8oTUSppCbq1Z8VbUv5PWUCJhugTXEYErotAtzc2WjubDRbG0lQPBK0fvxlAHXk-3_L6o3s2ve4_s8n5uhsdvyg_QnRP7L1
CitedBy_id	crossref_primary_10_1002_cctc_201901166 crossref_primary_10_1002_adma_202002927 crossref_primary_10_1002_slct_202303226 crossref_primary_10_1039_C8CY01391H crossref_primary_10_1039_D2CY00502F crossref_primary_10_1016_j_apcatb_2025_125655 crossref_primary_10_1016_j_fuel_2023_127906 crossref_primary_10_1038_s41467_023_41192_y crossref_primary_10_1016_j_jcat_2019_01_013 crossref_primary_10_1039_D5CE00156K crossref_primary_10_57634_RCR5079 crossref_primary_10_1016_j_fuel_2025_136325 crossref_primary_10_1016_j_jmst_2025_05_016 crossref_primary_10_1002_anie_201902730 crossref_primary_10_1021_acs_energyfuels_5c00885 crossref_primary_10_1021_acscatal_5c01349 crossref_primary_10_1016_j_molstruc_2020_128720 crossref_primary_10_1016_j_fuel_2022_126946 crossref_primary_10_1039_D0CY00449A crossref_primary_10_1016_j_apcata_2024_119892 crossref_primary_10_1016_j_fuel_2024_134040 crossref_primary_10_1002_anie_202007283 crossref_primary_10_1039_C9QI01051C crossref_primary_10_1016_j_apcatb_2021_120377 crossref_primary_10_1016_j_cattod_2022_05_005 crossref_primary_10_1016_j_apcatb_2019_118360 crossref_primary_10_1016_j_cep_2023_109398 crossref_primary_10_1039_D5CY00687B crossref_primary_10_1002_ange_201809433 crossref_primary_10_1007_s11144_024_02734_7 crossref_primary_10_1039_D2CY01758J crossref_primary_10_1016_j_jcat_2023_06_034 crossref_primary_10_1002_ange_201902730 crossref_primary_10_1016_j_apcata_2021_118019 crossref_primary_10_1002_cctc_201800880 crossref_primary_10_1016_j_apcatb_2022_121274 crossref_primary_10_1002_anie_202017074 crossref_primary_10_1016_j_cej_2025_160527 crossref_primary_10_1002_ange_202111111 crossref_primary_10_1016_j_jcat_2024_115619 crossref_primary_10_1021_jacs_9b02936 crossref_primary_10_3390_catal9100867 crossref_primary_10_1002_ange_202007283 crossref_primary_10_1002_cctc_201902366 crossref_primary_10_1002_advs_202001335 crossref_primary_10_1016_j_fuel_2024_132327 crossref_primary_10_1016_j_jcat_2019_06_002 crossref_primary_10_1002_ange_202017074 crossref_primary_10_1007_s11705_024_2505_2 crossref_primary_10_1007_s11172_023_3802_2 crossref_primary_10_1002_ente_201900555 crossref_primary_10_3390_catal11020282 crossref_primary_10_1016_j_cattod_2020_04_021 crossref_primary_10_1002_er_4697 crossref_primary_10_1002_adma_202002565 crossref_primary_10_1134_S0023158421080048 crossref_primary_10_1002_anie_202111111 crossref_primary_10_1016_j_apcata_2019_01_022 crossref_primary_10_1038_s41929_020_0459_4 crossref_primary_10_1039_D0CY00484G crossref_primary_10_1016_S1872_2067_23_64440_7 crossref_primary_10_1039_C9CY02108F crossref_primary_10_1039_D1RE00044F crossref_primary_10_1002_anie_201809433 crossref_primary_10_1039_C9CY01932D crossref_primary_10_1016_j_apcata_2019_117247 crossref_primary_10_1016_j_jksues_2020_07_014 crossref_primary_10_1016_j_micromeso_2024_113227 crossref_primary_10_1016_j_apcatb_2021_120960 crossref_primary_10_1021_jacs_3c04284 crossref_primary_10_3390_molecules25215048 crossref_primary_10_1002_cctc_201901655 crossref_primary_10_36962_PAHTEI36012024_234 crossref_primary_10_1016_j_apcata_2020_117430 crossref_primary_10_1016_j_apcatb_2018_09_042 crossref_primary_10_1038_s41929_022_00874_4 crossref_primary_10_1039_D3CY00103B crossref_primary_10_1021_acs_energyfuels_4c03491 crossref_primary_10_1021_jacs_9b09710 crossref_primary_10_1016_j_enconman_2024_119390 crossref_primary_10_1016_j_cej_2024_148862 crossref_primary_10_1039_D0RA03365K crossref_primary_10_1016_j_nanoen_2023_108404 crossref_primary_10_3390_app11125465 crossref_primary_10_1016_j_micromeso_2023_112485 crossref_primary_10_1134_S0023158422040061 crossref_primary_10_1016_j_fuproc_2023_107739 crossref_primary_10_1016_j_fuel_2021_121497 crossref_primary_10_1016_j_apcata_2020_117602 crossref_primary_10_1016_S1872_2067_24_60267_6 crossref_primary_10_1007_s13203_020_00245_9 crossref_primary_10_1007_s11356_024_33031_4 crossref_primary_10_1016_j_apcata_2023_119184 crossref_primary_10_1016_j_apcatb_2022_121194 crossref_primary_10_1016_j_jiec_2023_10_041 crossref_primary_10_1016_j_cattod_2022_06_001 crossref_primary_10_1007_s10934_022_01294_2 crossref_primary_10_1016_j_memsci_2023_121588 crossref_primary_10_1002_chem_202103894 crossref_primary_10_1134_S0965544122010017 crossref_primary_10_1016_j_ces_2022_118289 crossref_primary_10_1016_j_ces_2023_119431 crossref_primary_10_1016_j_mencom_2021_09_002
Cites_doi	10.1021/ja0041167 10.1006/jcat.2000.2908 10.1016/j.jcat.2009.11.016 10.1021/acs.chemrev.6b00715 10.1002/anie.201601357 10.1006/jcat.1999.2704 10.1002/ange.201203280 10.1002/anie.200604045 10.1126/science.1253150 10.1002/ange.201103657 10.1002/ange.201307935 10.1002/ange.201609442 10.1021/acscatal.6b00004 10.1016/j.jcat.2012.12.014 10.1039/b810981h 10.1039/b104011c 10.1006/jcat.2002.3540 10.1016/j.jcat.2016.12.006 10.1023/A:1019087313679 10.1002/anie.200902199 10.1039/C5CY01236H 10.1002/anie.201203280 10.1002/ange.201601357 10.1016/S1387-1811(99)00245-0 10.1007/BF00958092 10.1038/nature18284 10.1002/anie.201103657 10.1002/anie.201307935 10.1002/anie.201609442 10.1126/science.aag0274 10.1021/acscatal.6b00428 10.1016/j.apcata.2005.08.011 10.1023/A:1019099607029 10.1126/science.aaa7048 10.1002/ange.200604045 10.1021/acscatal.6b02497 10.1002/ange.200902199 10.1021/ja7110916 10.1126/science.1226840
ContentType	Journal Article
Copyright	2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Copyright_xml	– notice: 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. – notice: 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. – notice: 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
DBID	24P AAYXX CITATION NPM 7TM K9. 7X8 5PM
DOI	10.1002/anie.201711098
DatabaseName	Wiley Online Library Open Access CrossRef PubMed Nucleic Acids Abstracts ProQuest Health & Medical Complete (Alumni) MEDLINE - Academic PubMed Central (Full Participant titles)
DatabaseTitle	CrossRef PubMed ProQuest Health & Medical Complete (Alumni) Nucleic Acids Abstracts MEDLINE - Academic
DatabaseTitleList	CrossRef MEDLINE - Academic PubMed ProQuest Health & Medical Complete (Alumni)
Database_xml	– sequence: 1 dbid: 24P name: Wiley Online Library Open Access url: https://authorservices.wiley.com/open-science/open-access/browse-journals.html sourceTypes: Publisher – sequence: 2 dbid: NPM name: PubMed url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 3 dbid: 7X8 name: MEDLINE - Academic url: https://search.proquest.com/medline sourceTypes: Aggregation Database
DeliveryMethod	fulltext_linktorsrc
Discipline	Chemistry
EISSN	1521-3773
Edition	International ed. in English
EndPage	1020
ExternalDocumentID	PMC5820752 29181863 10_1002_anie_201711098 ANIE201711098
Genre	shortCommunication Research Support, Non-U.S. Gov't Journal Article
GroupedDBID	--- -DZ -~X .3N .GA 05W 0R~ 10A 1L6 1OB 1OC 1ZS 23M 24P 33P 3SF 3WU 4.4 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5GY 5RE 5VS 66C 6TJ 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AAHQN AAMNL AANLZ AAONW AASGY AAXRX AAYCA AAZKR ABCQN ABCUV ABEML ABIJN ABLJU ABPPZ ABPVW ACAHQ ACCFJ ACCZN ACFBH ACGFS ACIWK ACNCT ACPOU ACPRK ACSCC ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN ADZOD AEEZP AEIGN AEIMD AEQDE AEUQT AEUYR AFBPY AFFNX AFFPM AFGKR AFPWT AFRAH AFWVQ AFZJQ AHBTC AHMBA AITYG AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN ALVPJ AMBMR AMYDB ATUGU AUFTA AZBYB AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BTSUX BY8 CS3 D-E D-F D0L DCZOG DPXWK DR1 DR2 DRFUL DRSTM EBS EJD F00 F01 F04 F5P G-S G.N GNP GODZA H.T H.X HBH HGLYW HHY HHZ HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LW6 LYRES M53 MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OIG P2P P2W P2X P4D PQQKQ Q.N Q11 QB0 QRW R.K RNS ROL RWI RX1 RYL SUPJJ TN5 UB1 UPT V2E VQA W8V W99 WBFHL WBKPD WH7 WIB WIH WIK WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XPP XSW XV2 YZZ ZZTAW ~IA ~KM ~WT AAYXX ABDBF ABJNI ABUFD AEYWJ AGHNM AGYGG CITATION O8X NPM 7TM K9. 7X8 5PM AETEA
ID	FETCH-LOGICAL-c5718-e544be304a17b2850d3fa1c91c66e883d0bf2d13f8cff63bd1ba4d13ee7396fa3
IEDL.DBID	24P
ISICitedReferencesCount	136
ISICitedReferencesURI	http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000428208700026&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
ISSN	1433-7851 1521-3773
IngestDate	Tue Nov 04 01:56:41 EST 2025 Thu Jul 10 22:51:59 EDT 2025 Sat Nov 29 14:27:57 EST 2025 Mon Jul 21 05:41:56 EDT 2025 Sat Nov 29 03:44:13 EST 2025 Tue Nov 18 22:11:21 EST 2025 Wed Jan 22 16:21:36 EST 2025
IsDoiOpenAccess	true
IsOpenAccess	true
IsPeerReviewed	true
IsScholarly	true
Issue	4
Keywords	organocatalysis methane Mo/ZSM-5 dehydroaromatization hydrocarbons
Language	English
License	Attribution-NonCommercial-NoDerivs http://creativecommons.org/licenses/by-nc-nd/4.0 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
LinkModel	DirectLink
MergedId	FETCHMERGED-LOGICAL-c5718-e544be304a17b2850d3fa1c91c66e883d0bf2d13f8cff63bd1ba4d13ee7396fa3
Notes	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23
ORCID	0000-0001-5454-9582 0000-0002-9949-3057 0000-0001-9242-9901 0000-0002-0537-5755 0000-0001-8520-4886 0000-0002-9754-2417
OpenAccessLink	https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.201711098
PMID	29181863
PQID	1987716538
PQPubID	946352
PageCount	5
ParticipantIDs	pubmedcentral_primary_oai_pubmedcentral_nih_gov_5820752 proquest_miscellaneous_1969923771 proquest_journals_1987716538 pubmed_primary_29181863 crossref_primary_10_1002_anie_201711098 crossref_citationtrail_10_1002_anie_201711098 wiley_primary_10_1002_anie_201711098_ANIE201711098
PublicationCentury	2000
PublicationDate	January 22, 2018
PublicationDateYYYYMMDD	2018-01-22
PublicationDate_xml	– month: 01 year: 2018 text: January 22, 2018 day: 22
PublicationDecade	2010
PublicationPlace	Germany
PublicationPlace_xml	– name: Germany – name: Weinheim – name: Hoboken
PublicationTitle	Angewandte Chemie International Edition
PublicationTitleAlternate	Angew Chem Int Ed Engl
PublicationYear	2018
Publisher	Wiley Subscription Services, Inc John Wiley and Sons Inc
Publisher_xml	– name: Wiley Subscription Services, Inc – name: John Wiley and Sons Inc
References	2017; 7 2001; 123 2005; 295 2009 2009; 48 121 2000; 66 2010; 269 2000; 194 2015; 348 2008 2008; 47 120 2008; 1 2017; 117 2013 2013; 52 125 2016; 6 2016 2016; 55 128 2012 2012; 51 124 1999; 57 2013; 299 2016; 353 2016; 535 2000; 35–36 2002; 208 2000; 189 2001; 11 1989; 38 2012; 338 2008; 130 2017; 346 2014; 344 e_1_2_2_25_1 e_1_2_2_4_2 e_1_2_2_5_1 e_1_2_2_24_1 e_1_2_2_4_3 e_1_2_2_6_1 e_1_2_2_23_1 e_1_2_2_21_2 e_1_2_2_22_1 e_1_2_2_20_2 e_1_2_2_1_1 e_1_2_2_2_1 e_1_2_2_40_1 e_1_2_2_41_2 e_1_2_2_28_3 e_1_2_2_29_2 e_1_2_2_7_2 e_1_2_2_8_2 e_1_2_2_9_1 e_1_2_2_28_2 e_1_2_2_27_2 e_1_2_2_25_2 e_1_2_2_26_1 e_1_2_2_37_1 e_1_2_2_12_2 e_1_2_2_13_1 e_1_2_2_38_1 e_1_2_2_11_2 e_1_2_2_10_2 e_1_2_2_39_2 e_1_2_2_39_3 e_1_2_2_30_1 e_1_2_2_19_2 e_1_2_2_18_2 e_1_2_2_31_2 e_1_2_2_16_3 e_1_2_2_32_2 e_1_2_2_33_1 Olivos Suarez A. I. (e_1_2_2_3_2) 2016; 6 e_1_2_2_16_2 e_1_2_2_17_1 e_1_2_2_34_1 e_1_2_2_14_3 e_1_2_2_15_2 e_1_2_2_34_2 e_1_2_2_35_1 e_1_2_2_14_2 e_1_2_2_36_1
References_xml	– volume: 346 start-page: 125 year: 2017 end-page: 133 publication-title: J. Catal. – volume: 6 start-page: 2448 year: 2016 end-page: 2451 publication-title: ACS Catal. – volume: 117 start-page: 8497 year: 2017 end-page: 8520 publication-title: Chem. Rev. – volume: 6 start-page: 2965 year: 2016 end-page: 2981 publication-title: ACS Catal. – volume: 353 start-page: 563 year: 2016 end-page: 566 publication-title: Science – volume: 344 start-page: 616 year: 2014 end-page: 619 publication-title: Science – volume: 47 120 start-page: 452 460 year: 2008 2008 end-page: 483 492 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 123 start-page: 4749 year: 2001 end-page: 4754 publication-title: J. Am. Chem. Soc. – volume: 1 start-page: 526 year: 2008 end-page: 541 publication-title: Energy Environ. Sci. – volume: 52 125 start-page: 13794 14039 year: 2013 2013 end-page: 13797 14042 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 6 start-page: 363 year: 2016 end-page: 378 publication-title: Catal. Sci. Technol. – volume: 11 start-page: 3094 year: 2001 end-page: 3098 publication-title: J. Mater. Chem. – volume: 57 start-page: 95 year: 1999 end-page: 102 publication-title: Catal. Lett. – volume: 189 start-page: 314 year: 2000 end-page: 325 publication-title: J. Catal. – volume: 55 128 start-page: 15086 15310 year: 2016 2016 end-page: 15090 15314 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 130 start-page: 3722 year: 2008 end-page: 3723 publication-title: J. Am. Chem. Soc. – volume: 269 start-page: 329 year: 2010 end-page: 339 publication-title: J. Catal. – volume: 299 start-page: 240 year: 2013 end-page: 248 publication-title: J. Catal. – volume: 55 128 start-page: 5215 5301 year: 2016 2016 end-page: 5219 5305 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 7 start-page: 520 year: 2017 end-page: 529 publication-title: ACS Catal. – volume: 295 start-page: 79 year: 2005 end-page: 88 publication-title: Appl. Catal. A – volume: 338 start-page: 340 year: 2012 end-page: 342 publication-title: Science – volume: 66 start-page: 155 year: 2000 end-page: 160 publication-title: Catal. Lett. – volume: 48 121 start-page: 6678 6806 year: 2009 2009 end-page: 6682 6810 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 194 start-page: 105 year: 2000 end-page: 114 publication-title: J. Catal. – volume: 51 124 start-page: 5810 5910 year: 2012 2012 end-page: 5831 5933 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 35–36 start-page: 495 year: 2000 end-page: 509 publication-title: Microporous Mesoporous Mater. – volume: 51 124 start-page: 10712 10870 year: 2012 2012 end-page: 10723 10881 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 348 start-page: 686 year: 2015 end-page: 690 publication-title: Science – volume: 535 start-page: 131 year: 2016 end-page: 135 publication-title: Nature – volume: 38 start-page: 680 year: 1989 end-page: 680 publication-title: Bull. Acad. Sci. USSR Div. Chem. Sci. – volume: 208 start-page: 260 year: 2002 end-page: 269 publication-title: J. Catal. – ident: e_1_2_2_23_1 doi: 10.1021/ja0041167 – ident: e_1_2_2_10_2 doi: 10.1006/jcat.2000.2908 – ident: e_1_2_2_29_2 doi: 10.1016/j.jcat.2009.11.016 – ident: e_1_2_2_8_2 doi: 10.1021/acs.chemrev.6b00715 – ident: e_1_2_2_40_1 – ident: e_1_2_2_25_1 doi: 10.1002/anie.201601357 – ident: e_1_2_2_35_1 doi: 10.1006/jcat.1999.2704 – ident: e_1_2_2_4_3 doi: 10.1002/ange.201203280 – ident: e_1_2_2_39_2 doi: 10.1002/anie.200604045 – ident: e_1_2_2_41_2 doi: 10.1126/science.1253150 – ident: e_1_2_2_28_3 doi: 10.1002/ange.201103657 – ident: e_1_2_2_14_3 doi: 10.1002/ange.201307935 – ident: e_1_2_2_16_3 doi: 10.1002/ange.201609442 – ident: e_1_2_2_38_1 – ident: e_1_2_2_12_2 doi: 10.1021/acscatal.6b00004 – ident: e_1_2_2_33_1 doi: 10.1016/j.jcat.2012.12.014 – ident: e_1_2_2_7_2 doi: 10.1039/b810981h – ident: e_1_2_2_37_1 doi: 10.1039/b104011c – ident: e_1_2_2_11_2 doi: 10.1006/jcat.2002.3540 – ident: e_1_2_2_24_1 doi: 10.1016/j.jcat.2016.12.006 – ident: e_1_2_2_31_2 doi: 10.1023/A:1019087313679 – ident: e_1_2_2_34_1 doi: 10.1002/anie.200902199 – ident: e_1_2_2_27_2 doi: 10.1039/C5CY01236H – ident: e_1_2_2_26_1 – ident: e_1_2_2_4_2 doi: 10.1002/anie.201203280 – ident: e_1_2_2_25_2 doi: 10.1002/ange.201601357 – ident: e_1_2_2_32_2 doi: 10.1016/S1387-1811(99)00245-0 – ident: e_1_2_2_5_1 doi: 10.1007/BF00958092 – ident: e_1_2_2_36_1 doi: 10.1038/nature18284 – ident: e_1_2_2_28_2 doi: 10.1002/anie.201103657 – ident: e_1_2_2_14_2 doi: 10.1002/anie.201307935 – ident: e_1_2_2_16_2 doi: 10.1002/anie.201609442 – ident: e_1_2_2_17_1 – ident: e_1_2_2_15_2 doi: 10.1126/science.aag0274 – ident: e_1_2_2_30_1 – ident: e_1_2_2_13_1 – volume: 6 start-page: 2965 year: 2016 ident: e_1_2_2_3_2 publication-title: ACS Catal. doi: 10.1021/acscatal.6b00428 – ident: e_1_2_2_19_2 doi: 10.1016/j.apcata.2005.08.011 – ident: e_1_2_2_18_2 doi: 10.1023/A:1019099607029 – ident: e_1_2_2_21_2 doi: 10.1126/science.aaa7048 – ident: e_1_2_2_2_1 – ident: e_1_2_2_6_1 – ident: e_1_2_2_39_3 doi: 10.1002/ange.200604045 – ident: e_1_2_2_22_1 doi: 10.1021/acscatal.6b02497 – ident: e_1_2_2_34_2 doi: 10.1002/ange.200902199 – ident: e_1_2_2_9_1 – ident: e_1_2_2_20_2 doi: 10.1021/ja7110916 – ident: e_1_2_2_1_1 doi: 10.1126/science.1226840
SSID	ssj0028806
Score	2.603826
Snippet	Non‐oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The... Non-oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The...
SourceID	pubmedcentral proquest pubmed crossref wiley
SourceType	Open Access Repository Aggregation Database Index Database Enrichment Source Publisher
StartPage	1016
SubjectTerms	Benzene Catalysis Catalysts Communication Communications Deactivation dehydroaromatization Hydrocarbons Methane Mo/ZSM-5 Natural gas organocatalysis Spectroscopy Zeolites
Title	Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM‐5
URI	https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.201711098 https://www.ncbi.nlm.nih.gov/pubmed/29181863 https://www.proquest.com/docview/1987716538 https://www.proquest.com/docview/1969923771 https://pubmed.ncbi.nlm.nih.gov/PMC5820752
Volume	57
WOSCitedRecordID	wos000428208700026&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
journalDatabaseRights	– providerCode: PRVWIB databaseName: Wiley Online Library - Journals customDbUrl: eissn: 1521-3773 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0028806 issn: 1433-7851 databaseCode: DRFUL dateStart: 19980101 isFulltext: true titleUrlDefault: https://onlinelibrary.wiley.com providerName: Wiley-Blackwell
link	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1La9wwEB7SpNBe0nfqNg0OFHoSaz1sy8ewydJAdglNA0svRpIlEih28CaF3voT-hvzSzpj77pZQim0F2OjkR-jkfRJnvkG4H3qERcLnjGT2IQp7zyzxhLvrcO1jwk8BNslm8hnMz2fF6d3ovh7fohhw416RjdeUwc3djH6TRpKEdjkmpUTZ6Z-AFucS03JG4Q6HZZcaJ19fJGUjNLQr2gbEzFar78-Ld3DmvddJu9C2W4umjz5_694CttLHBof9IbzDDZ8_RwejVfp317AMcUC4u2reGxa29TxtEvqgTNdfOgvvldtY9qG4G4fxxk3ASVoH97H5BUaT5vRl7Pp7Y-f6Us4nxx9Hn9ky7wLzKU4VTGfKmW9TJThuRU6TSoZDHcFd1nmtZZVYoOouAzahZBJW3FrFF57n8siC0a-gs26qf1riH3qRHAq0ybLVYHYwuCK2CKs8DzYQoUI2ErtpVuSklNujK9lT6csSlJQOSgogg-D_FVPx_FHyd1VK5bLbrkoaYcFF4g4yEewPxSjYukvCSqouSGZrEDUi3IR7PSNPjxKFJwYAGUE-Zo5DAJE1r1eUl9edKTdKUKtPBURiM4c_vL25cHs-Gi4evMvld7CYzwnT0UmxC5sXrc3_h08dN-uLxftXtdN8JjP9R5sHX6anJ_8AodlFlo
linkProvider	Wiley-Blackwell
linkToHtml	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1bS91AEB6qLdiXtlZt01pNQfBpOdlLbo9yqnio5yBUQXwJu5tdjiBJiVroW39Cf2N_SWeSnNiDFKH0cZPZXGZnM99uZr4B2Isd4mLBE6YjEzHlrGNGG-K9tbj20Z57b9piE-lsll1c5Kd9NCHlwnT8EMOGG82M9ntNE5w2pEf3rKGUgk2xWSmRZmYr8FShqyFTF-p0WHOheXYJRlIyqkO_4G2MxGi5_7JfegA2H8ZM_ollW2d09PI_vMYreNEj0fCgM511eOKq17A2XhSA24AJZQPi9ctwrBtTV-G0LeuBvi785Obfy6bWTU2At8vkDGuPErQT70KKCw2n9ejyy_TXj5_xJpwfHZ6Nj1lfeYHZGJ0Vc7FSxslIaZ4akcVRKb3mNuc2SVyWyTIyXpRc-sx6n0hTcqMVtp1LZZ54Lbdgtaor9xZCF1vhrUoynaQqR3ShcU1sEFg47k2ufABsoffC9rTkVB3juugIlUVBCioGBQWwP8h_7Qg5_iq5vRjGop-YNwXtseASET_zAXwcTqNi6T8JKqi-I5kkR9yLcgG86UZ9uJXIOXEAygDSJXsYBIiue_lMdTVvabtjBFtpLAIQrT088vTFwWxyOLTe_UunXVg7PpueFCeT2ef38ByPU9wiE2IbVm-bO_cBntlvt1c3zU47Z34D1MgXvQ
linkToPdf	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1ba9RAFD7oVrQvXquNrRpB8GnYzCW3x7LbxcXuUtRC8SXMTGZoQZKSXqBv_gR_o7_Ec5Js6lJEEB8nczJJzty-MznnOwDvYoe4WPCE6chETDnrmNGGeG8t2j7ac-9Nm2wiXS6z4-P8sPcmpFiYjh9iOHCjmdGu1zTB3VnpxzesoRSCTb5ZKZFmZndhQ1EmmRFsTD_Njg4GqwsHaBdiJCWjTPQr5sZIjNdbWN-ZbsHN216Tv6PZdjuaPfoPH_IYHvZYNNzrBs8TuOOqp_BgskoB9wzmFA-I7ZfhRDemrsJFm9gDd7tw6k6uy6bWTU2Qt4vlDGuPEnQW70LyDA0X9fjr58XP7z_iLTia7X-ZfGB97gVmY9yumIuVMk5GSvPUiCyOSuk1tzm3SeKyTJaR8aLk0mfW-0SakhutsOxcKvPEa_kcRlVduW0IXWyFtyrJdJKqHPGFRqvYILRw3Jtc-QDYSu-F7YnJKT_Gt6KjVBYFKagYFBTA-0H-rKPk-KPk7qobi35qnhd0yoJGIi70AbwdqlGx9KcEFVRfkkySI_JFuQBedL0-PErknFgAZQDp2ngYBIiwe72mOj1pibtjhFtpLAIQ7Xj4y9sXe8v5_lB6-S83vYH7h9NZcTBfftyBTbxMjotMiF0YXTSX7hXcs1cXp-fN637S_AJZhBjT
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Confined+Carbon+Mediating+Dehydroaromatization+of+Methane+over+Mo%2FZSM%E2%80%905&rft.jtitle=Angewandte+Chemie+International+Edition&rft.au=Kosinov%2C+Nikolay&rft.au=Wijpkema%2C+Alexandra+S.+G.&rft.au=Uslamin%2C+Evgeny&rft.au=Rohling%2C+Roderigh&rft.date=2018-01-22&rft.pub=John+Wiley+and+Sons+Inc&rft.issn=1433-7851&rft.eissn=1521-3773&rft.volume=57&rft.issue=4&rft.spage=1016&rft.epage=1020&rft_id=info:doi/10.1002%2Fanie.201711098&rft_id=info%3Apmid%2F29181863&rft.externalDocID=PMC5820752
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1433-7851&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1433-7851&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1433-7851&client=summon