Mechanism of the Dehydrogenative Phenothiazination of Phenols

The straightforward capture of oxidized phenothiazines with phenols under aerobic conditions represents a unique cross‐dehydrogenative C−N bond‐forming reaction in terms of operational simplicity. The mechanism of this cross‐dehydrogenative N‐arylation of phenothiazines with phenols has been the obj...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 24; no. 46; pp. 11936 - 11943
Main Authors:	Goswami, Monalisa, Konkel, Alexander, Rahimi, Maryam, Louillat‐Habermeyer, Marie‐Laure, Kelm, Harald, Jin, Rongwei, de Bruin, Bas, Patureau, Frederic W.
Format:	Journal Article
Language:	English
Published:	WEINHEIM Wiley 14.08.2018 Wiley Subscription Services, Inc John Wiley and Sons Inc
Subjects:	Aerobic conditions Chemistry Chemistry, Multidisciplinary click chemistry cross dehydrogenative couplings Dehydrogenation Density functional theory Electron paramagnetic resonance homolytic aromatic substitution oxidative amination Phenols Phenothiazines Physical Sciences radicals Reaction mechanisms Science & Technology Spectroscopy Substrates radicals C-N ARYLATION click chemistry TRANSFER RADICAL POLYMERIZATION cross dehydrogenative couplings HYDROGEN-ATOM ABSTRACTIONS homolytic aromatic substitution FUNCTIONALIZATION AMINATION BOND-DISSOCIATION ENERGIES oxidative amination SUBSTITUTED PHENOLS H BONDS DERIVATIVES
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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