The Kinetic Isotope Effect as a Probe of Spin Crossover in the CH Activation of Methane by the FeO+ Cation

Two‐state reactivity (TSR) is often used to explain the reaction of transition‐metal–oxo reagents in the bare form or in the complex form. The evidence of the TSR model typically comes from quantum‐mechanical calculations for energy profiles with a spin crossover in the rate‐limiting step. To prove...

Full description

Bibliographic Details

Published in:	Angewandte Chemie International Edition Vol. 54; no. 13; pp. 3946 - 3951
Main Authors:	Mai, Binh Khanh, Kim, Yongho
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 23.03.2015 WILEY‐VCH Verlag
Subjects:	hydrogen atom transfer kinetic isotope effect spin crossover two-state reactivity variational transition-state theory kinetic isotope effect spin crossover hydrogen atom transfer variational transition-state theory two-state reactivity
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!