The Mosaic Structure of Zeolite Crystals

Zeolites are widely used in many commercial processes, mostly as catalysts or adsorbents. Understanding their intimate structure at the nanoscale is the key to control their properties and design the best materials for their ever increasing uses. Herein, we report a new and controllable fluoride tre...

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Vydáno v:	Angewandte Chemie International Edition Ročník 55; číslo 48; s. 15049 - 15052
Hlavní autoři:	Qin, Zhengxing, Melinte, Georgian, Gilson, Jean-Pierre, Jaber, Maguy, Bozhilov, Krassimir, Boullay, Philippe, Mintova, Svetlana, Ersen, Ovidiu, Valtchev, Valentin
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	Germany Blackwell Publishing Ltd 21.11.2016 Wiley Subscription Services, Inc Wiley-VCH Verlag
Vydání:	International ed. in English
Témata:	Adsorbents Cations Chemical Sciences crystal engineering Crystals fluoride etching nanostructures Zeolites fluoride etching zeolites crystal engineering nanostructures Crystal engineering Nanostructures Fluoride etching Zeolites
ISSN:	1433-7851, 1521-3773, 1521-3773
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Abstract	Zeolites are widely used in many commercial processes, mostly as catalysts or adsorbents. Understanding their intimate structure at the nanoscale is the key to control their properties and design the best materials for their ever increasing uses. Herein, we report a new and controllable fluoride treatment for the non‐discriminate extraction of zeolite framework cations. This sheds new light on the sub‐structure of commercially relevant zeolite crystals: they are segmented along defect zones exposing numerous nanometer‐sized crystalline domains, separated by low‐angle boundaries, in what were apparent single‐crystals. The concentration, morphology, and distribution of such domains analyzed by electron tomography indicate that this is a common phenomenon in zeolites, independent of their structure and chemical composition. This is a milestone to better understand their growth mechanism and rationally design superior catalysts and adsorbents. Etch it out: A controlled fluoride medium treatment is used to expose the local structure of zeolite crystals. Unexpectedly high concentrations of nanometer‐sized crystalline domains, separated by low‐angle boundaries, were discovered.
AbstractList	Zeolites are widely used in many commercial processes, mostly as catalysts or adsorbents. Understanding their intimate structure at the nanoscale is the key to control their properties and design the best materials for their ever increasing uses. Herein, we report a new and controllable fluoride treatment for the non-discriminate extraction of zeolite framework cations. This sheds new light on the sub-structure of commercially relevant zeolite crystals: they are segmented along defect zones exposing numerous nanometer-sized crystalline domains, separated by low-angle boundaries, in what were apparent single-crystals. The concentration, morphology, and distribution of such domains analyzed by electron tomography indicate that this is a common phenomenon in zeolites, independent of their structure and chemical composition. This is a milestone to better understand their growth mechanism and rationally design superior catalysts and adsorbents. Zeolites are widely used in many commercial processes, mostly as catalysts or adsorbents. Understanding their intimate structure at the nanoscale is the key to control their properties and design the best materials for their ever increasing uses. Herein, we report a new and controllable fluoride treatment for the non-discriminate extraction of zeolite framework cations. This sheds new light on the sub-structure of commercially relevant zeolite crystals: they are segmented along defect zones exposing numerous nanometer-sized crystalline domains, separated by low-angle boundaries, in what were apparent single-crystals. The concentration, morphology, and distribution of such domains analyzed by electron tomography indicate that this is a common phenomenon in zeolites, independent of their structure and chemical composition. This is a milestone to better understand their growth mechanism and rationally design superior catalysts and adsorbents.Zeolites are widely used in many commercial processes, mostly as catalysts or adsorbents. Understanding their intimate structure at the nanoscale is the key to control their properties and design the best materials for their ever increasing uses. Herein, we report a new and controllable fluoride treatment for the non-discriminate extraction of zeolite framework cations. This sheds new light on the sub-structure of commercially relevant zeolite crystals: they are segmented along defect zones exposing numerous nanometer-sized crystalline domains, separated by low-angle boundaries, in what were apparent single-crystals. The concentration, morphology, and distribution of such domains analyzed by electron tomography indicate that this is a common phenomenon in zeolites, independent of their structure and chemical composition. This is a milestone to better understand their growth mechanism and rationally design superior catalysts and adsorbents. Zeolites are widely used in many commercial processes, mostly as catalysts or adsorbents. Understanding their intimate structure at the nanoscale is the key to control their properties and design the best materials for their ever increasing uses. Herein, we report a new and controllable fluoride treatment for the non‐discriminate extraction of zeolite framework cations. This sheds new light on the sub‐structure of commercially relevant zeolite crystals: they are segmented along defect zones exposing numerous nanometer‐sized crystalline domains, separated by low‐angle boundaries, in what were apparent single‐crystals. The concentration, morphology, and distribution of such domains analyzed by electron tomography indicate that this is a common phenomenon in zeolites, independent of their structure and chemical composition. This is a milestone to better understand their growth mechanism and rationally design superior catalysts and adsorbents. Etch it out: A controlled fluoride medium treatment is used to expose the local structure of zeolite crystals. Unexpectedly high concentrations of nanometer‐sized crystalline domains, separated by low‐angle boundaries, were discovered.
Author	Qin, Zhengxing Melinte, Georgian Ersen, Ovidiu Jaber, Maguy Gilson, Jean-Pierre Bozhilov, Krassimir Boullay, Philippe Valtchev, Valentin Mintova, Svetlana
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Keywords	fluoride etching zeolites crystal engineering nanostructures Crystal engineering Nanostructures Fluoride etching Zeolites
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Snippet	Zeolites are widely used in many commercial processes, mostly as catalysts or adsorbents. Understanding their intimate structure at the nanoscale is the key to...
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SubjectTerms	Adsorbents Cations Chemical Sciences crystal engineering Crystals fluoride etching nanostructures Zeolites
Title	The Mosaic Structure of Zeolite Crystals
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