Synthetically Important Alkali-Metal Utility Amides: Lithium, Sodium, and Potassium Hexamethyldisilazides, Diisopropylamides, and Tetramethylpiperidides

Most synthetic chemists will have at some point utilized a sterically demanding secondary amide (R2N−). The three most important examples, lithium 1,1,1,3,3,3‐hexamethyldisilazide (LiHMDS), lithium diisopropylamide (LiDA), and lithium 2,2,6,6‐tetramethylpiperidide (LiTMP)—the “utility amides”—have l...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 52; no. 44; pp. 11470 - 11487
Main Authors:	Mulvey, Robert E., Robertson, Stuart D.
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 25.10.2013 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	Acidity Alkali metals Amides Chemists Congeners heterometallic compounds Lithium molecular structure Potassium secondary amide Sodium solution state Solvents Utilities molecular structure heterometallic compounds secondary amide solution state alkali metals
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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