Correlated Coordination and Redox Activity of a Hemilabile Noninnocent Ligand in Nickel Complexes

The compound [Ni(QM)2], QM=4,6‐di‐tert‐butyl‐N‐(2‐methylthiomethylphenyl)‐o‐iminobenzoquinone, is a singlet diradical species with approximately planar configuration at the tetracoordinate metal atom and without any NiS bonding interaction. One‐electron oxidation results in additional twofold NiS...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 20; no. 18; pp. 5414 - 5422
Main Authors:	Paretzki, Alexa, Bubrin, Martina, Fiedler, Jan, Záliš, Stanislav, Kaim, Wolfgang
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 25.04.2014 WILEY‐VCH Verlag Wiley Wiley Subscription Services, Inc
Subjects:	Absorption Anisotropy Binding Cations Charge transfer Chemistry Chemistry, Multidisciplinary coordination change Coordination compounds hemilabile ligands Ligands Nickel noninnocent ligands Oxidation Physical Sciences redox chemistry Science & Technology nickel coordination change TRANSITION-METAL-COMPLEXES APPROXIMATION BEHAVIOR OXIDATIVE ADDITION redox chemistry ELECTRONIC-STRUCTURES MONONUCLEAR noninnocent ligands CHEMISTRY SYSTEMATICS ATOMS hemilabile ligands 4-COORDINATE
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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