An Isolated Nitridyl Radical-Bridged {Rh(N.)Rh} Complex

Photochemical activation of [(PNNH)Rh(N3)] (PNNH=6‐di‐(tert‐butyl)phosphinomethyl‐2,2′‐bipyridine) complex 2 produced the paramagnetic (S=1/2), [(PNN)RhN.‐Rh(PNN)] complex 3 (PNN−=methylene‐deprotonated PNNH), which could be crystallographically characterized. Spectroscopic investigation of 3 indic...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 53; no. 26; pp. 6814 - 6818
Main Authors:	Gloaguen, Yann, Rebreyend, Christophe, Lutz, Martin, Kumar, Pravin, Huber, Martina, van der Vlugt, Jarl Ivar, Schneider, Sven, de Bruin, Bas
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 23.06.2014 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	Activation Carbon Monoxide Computation Coordination Complexes - chemistry Crystallography Crystallography, X-Ray Electron Spin Resonance Spectroscopy EPR spectroscopy Free Radicals - chemistry Humidity Iridium - chemistry Magnetics Molecular Conformation nitrogen donors non-innocent ligands Photochemical Photochemicals Pyridines - chemistry Radicals rhodium Rhodium - chemistry Spectroscopy radicals non-innocent ligands EPR spectroscopy nitrogen donors rhodium
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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