Electric control of magnetic exchange in a molecular spin triangle
Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a mechanism independent of spin-orbit interaction, here we report the detection of a spin-electric effect in the [Cu 3 (saltag)(py) 6 ]ClO 4 spin triangle....
Saved in:
| Published in: | Nature communications Vol. 16; no. 1; pp. 6564 - 9 |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
London
Nature Publishing Group UK
16.07.2025
Nature Publishing Group Nature Portfolio |
| Subjects: | |
| ISSN: | 2041-1723, 2041-1723 |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a mechanism independent of spin-orbit interaction, here we report the detection of a spin-electric effect in the [Cu
3
(saltag)(py)
6
]ClO
4
spin triangle. The effect is investigated by electron paramagnetic resonance under electric field modulation on single crystals. The anisotropy of the magnetic response to the electric field is addressed, and comprehensive ab initio calculations are performed to elucidate its origin. We demonstrate that when the electric field is applied in the plane of the triangle, the dominant contribution to the observed spin-electric signal arises from a variation of the isotropic exchange interaction. Our combined theoretical and experimental approach demonstrates that, in our system, there is no evidence of antisymmetric exchange (Dzyaloshinskii-Moriya) interaction, confirming that electric-field control of magnetic exchange is achievable in the absence of significant spin–orbit coupling. Moreover, we underscore the crucial role of the bridging ligand, which opens new avenues for chemically optimizing spin–electric coupling.
Electric control of magnetic interactions in a molecular spin-frustrated triangle is demonstrated through experiments and supported by ab initio calculations. This result opens new pathways for scalability by local control of qubit–qubit coupling. |
|---|---|
| AbstractList | Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a mechanism independent of spin-orbit interaction, here we report the detection of a spin-electric effect in the [Cu
(saltag)(py)
]ClO
spin triangle. The effect is investigated by electron paramagnetic resonance under electric field modulation on single crystals. The anisotropy of the magnetic response to the electric field is addressed, and comprehensive ab initio calculations are performed to elucidate its origin. We demonstrate that when the electric field is applied in the plane of the triangle, the dominant contribution to the observed spin-electric signal arises from a variation of the isotropic exchange interaction. Our combined theoretical and experimental approach demonstrates that, in our system, there is no evidence of antisymmetric exchange (Dzyaloshinskii-Moriya) interaction, confirming that electric-field control of magnetic exchange is achievable in the absence of significant spin-orbit coupling. Moreover, we underscore the crucial role of the bridging ligand, which opens new avenues for chemically optimizing spin-electric coupling. Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a mechanism independent of spin-orbit interaction, here we report the detection of a spin-electric effect in the [Cu 3 (saltag)(py) 6 ]ClO 4 spin triangle. The effect is investigated by electron paramagnetic resonance under electric field modulation on single crystals. The anisotropy of the magnetic response to the electric field is addressed, and comprehensive ab initio calculations are performed to elucidate its origin. We demonstrate that when the electric field is applied in the plane of the triangle, the dominant contribution to the observed spin-electric signal arises from a variation of the isotropic exchange interaction. Our combined theoretical and experimental approach demonstrates that, in our system, there is no evidence of antisymmetric exchange (Dzyaloshinskii-Moriya) interaction, confirming that electric-field control of magnetic exchange is achievable in the absence of significant spin–orbit coupling. Moreover, we underscore the crucial role of the bridging ligand, which opens new avenues for chemically optimizing spin–electric coupling. Electric control of magnetic interactions in a molecular spin-frustrated triangle is demonstrated through experiments and supported by ab initio calculations. This result opens new pathways for scalability by local control of qubit–qubit coupling. Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a mechanism independent of spin-orbit interaction, here we report the detection of a spin-electric effect in the [Cu3(saltag)(py)6]ClO4 spin triangle. The effect is investigated by electron paramagnetic resonance under electric field modulation on single crystals. The anisotropy of the magnetic response to the electric field is addressed, and comprehensive ab initio calculations are performed to elucidate its origin. We demonstrate that when the electric field is applied in the plane of the triangle, the dominant contribution to the observed spin-electric signal arises from a variation of the isotropic exchange interaction. Our combined theoretical and experimental approach demonstrates that, in our system, there is no evidence of antisymmetric exchange (Dzyaloshinskii-Moriya) interaction, confirming that electric-field control of magnetic exchange is achievable in the absence of significant spin-orbit coupling. Moreover, we underscore the crucial role of the bridging ligand, which opens new avenues for chemically optimizing spin-electric coupling.Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a mechanism independent of spin-orbit interaction, here we report the detection of a spin-electric effect in the [Cu3(saltag)(py)6]ClO4 spin triangle. The effect is investigated by electron paramagnetic resonance under electric field modulation on single crystals. The anisotropy of the magnetic response to the electric field is addressed, and comprehensive ab initio calculations are performed to elucidate its origin. We demonstrate that when the electric field is applied in the plane of the triangle, the dominant contribution to the observed spin-electric signal arises from a variation of the isotropic exchange interaction. Our combined theoretical and experimental approach demonstrates that, in our system, there is no evidence of antisymmetric exchange (Dzyaloshinskii-Moriya) interaction, confirming that electric-field control of magnetic exchange is achievable in the absence of significant spin-orbit coupling. Moreover, we underscore the crucial role of the bridging ligand, which opens new avenues for chemically optimizing spin-electric coupling. Abstract Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a mechanism independent of spin-orbit interaction, here we report the detection of a spin-electric effect in the [Cu3(saltag)(py)6]ClO4 spin triangle. The effect is investigated by electron paramagnetic resonance under electric field modulation on single crystals. The anisotropy of the magnetic response to the electric field is addressed, and comprehensive ab initio calculations are performed to elucidate its origin. We demonstrate that when the electric field is applied in the plane of the triangle, the dominant contribution to the observed spin-electric signal arises from a variation of the isotropic exchange interaction. Our combined theoretical and experimental approach demonstrates that, in our system, there is no evidence of antisymmetric exchange (Dzyaloshinskii-Moriya) interaction, confirming that electric-field control of magnetic exchange is achievable in the absence of significant spin–orbit coupling. Moreover, we underscore the crucial role of the bridging ligand, which opens new avenues for chemically optimizing spin–electric coupling. Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a mechanism independent of spin-orbit interaction, here we report the detection of a spin-electric effect in the [Cu3(saltag)(py)6]ClO4 spin triangle. The effect is investigated by electron paramagnetic resonance under electric field modulation on single crystals. The anisotropy of the magnetic response to the electric field is addressed, and comprehensive ab initio calculations are performed to elucidate its origin. We demonstrate that when the electric field is applied in the plane of the triangle, the dominant contribution to the observed spin-electric signal arises from a variation of the isotropic exchange interaction. Our combined theoretical and experimental approach demonstrates that, in our system, there is no evidence of antisymmetric exchange (Dzyaloshinskii-Moriya) interaction, confirming that electric-field control of magnetic exchange is achievable in the absence of significant spin–orbit coupling. Moreover, we underscore the crucial role of the bridging ligand, which opens new avenues for chemically optimizing spin–electric coupling. Electric control of magnetic interactions in a molecular spin-frustrated triangle is demonstrated through experiments and supported by ab initio calculations. This result opens new pathways for scalability by local control of qubit–qubit coupling. |
| ArticleNumber | 6564 |
| Author | Sessoli, Roberta Plass, Winfried Fittipaldi, Maria Cini, Alberto Böhme, Michael Perfetti, Mauro Kintzel, Benjamin |
| Author_xml | – sequence: 1 givenname: Alberto orcidid: 0000-0003-4040-5531 surname: Cini fullname: Cini, Alberto organization: Department of Physics and Astronomy, University of Florence and INSTM UdR – sequence: 2 givenname: Michael surname: Böhme fullname: Böhme, Michael organization: Institut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität Jena, Humboldtstraße 8 – sequence: 3 givenname: Benjamin orcidid: 0009-0005-9761-6390 surname: Kintzel fullname: Kintzel, Benjamin organization: Institut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität Jena, Humboldtstraße 8 – sequence: 4 givenname: Mauro orcidid: 0000-0001-5649-0449 surname: Perfetti fullname: Perfetti, Mauro organization: Department of Chemistry “Ugo Schiff”, University of Florence and INSTM UdR – sequence: 5 givenname: Winfried orcidid: 0000-0003-3473-9682 surname: Plass fullname: Plass, Winfried email: sekr.plass@uni-jena.de organization: Institut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität Jena, Humboldtstraße 8 – sequence: 6 givenname: Roberta orcidid: 0000-0003-3783-2700 surname: Sessoli fullname: Sessoli, Roberta email: roberta.sessoli@unifi.it organization: Department of Chemistry “Ugo Schiff”, University of Florence and INSTM UdR – sequence: 7 givenname: Maria orcidid: 0000-0002-6254-2003 surname: Fittipaldi fullname: Fittipaldi, Maria email: maria.fittipaldi@unifi.it organization: Department of Physics and Astronomy, University of Florence and INSTM UdR |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/40670338$$D View this record in MEDLINE/PubMed |
| BookMark | eNp9Uk1v1DAUtFARLaV_gAOKxIVLwF9x7BOCqkClSlzgbL3YL9usnHixkwr-Pd5NKW0P9cXWezPjsd-8JEdTnJCQ14y-Z1ToD1kyqdqa8qZWTLK2Vs_ICaeS1azl4uje-Zic5bylZQnDtJQvyLGkqqVC6BPy-SKgm9PgKhenOcVQxb4aYTPhXGr4213DtMFqmCqoxliwS4BU5V0pFFbpBXxFnvcQMp7d7qfk55eLH-ff6qvvXy_PP13VrpFirjV4o5lGbEBxzSkYBsJji33PPIpeK98Z3ntpwCjOQKPuNDaiK0fvGi9OyeWq6yNs7S4NI6Q_NsJgD4WYNhZScR3Qyla4zgvR6R5lrwVw8MhNbyiyTummaH1ctXZLN6J3WN4O4YHow840XNtNvLGMc9UquVd4d6uQ4q8F82zHITsMASaMS7aCC2qokpQV6NtH0G1c0lT-6oBSzMiGF9Sb-5buvPybVQHwFeBSzDlhfwdh1O4zYddM2JIJe8iEVYWkH5HcMMM87IcNQ3iaKlZqLveUEKT_tp9g_QVNyMrV |
| CitedBy_id | crossref_primary_10_1021_jacs_5c10840 |
| Cites_doi | 10.1016/j.jmr.2005.08.013 10.1088/0022-3719/2/3/312 10.1002/anie.202017116 10.1038/nnano.2015.22 10.1103/Physics.2.20 10.1103/PhysRevLett.96.107202 10.1038/s41563-019-0314-7 10.1103/PhysRevLett.101.217201 10.1103/PhysRevB.85.085427 10.1103/PhysRevLett.108.247211 10.1038/natrevmats.2016.46 10.1021/ic503095t 10.1021/ic2020034 10.1063/1.449486 10.1038/s41563-018-0275-2 10.1103/PhysRevB.82.045429 10.1038/s41598-023-29840-1 10.1038/s41563-019-0310-y 10.1038/s41467-025-56453-1 10.1038/s41567-021-01355-4 10.1021/jp031064+ 10.1103/PhysRevB.82.155446 10.1103/PhysRevB.78.024402 10.1088/0022-3719/1/4/307 10.1038/ncomms1904 10.1021/jp0581126 10.1038/s41563-019-0288-5 10.1021/acs.jctc.9b00532 10.1103/PhysRevB.74.165319 10.1088/0953-8984/22/16/164209 10.1002/chem.201803038 10.1088/0022-3719/9/4/014 10.1039/C8CC06741D 10.1103/PhysRevB.109.214407 10.1021/jacs.9b09101 10.1126/science.1113357 10.1016/0003-9861(74)90298-7 10.1093/nsr/nwaa148 10.1038/30156 10.1103/PhysRevLett.122.037202 10.1039/b508541a |
| ContentType | Journal Article |
| Copyright | The Author(s) 2025 2025. The Author(s). The Author(s) 2025. This work is published under http://creativecommons.org/licenses/by-nc-nd/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. The Author(s) 2025 2025 |
| Copyright_xml | – notice: The Author(s) 2025 – notice: 2025. The Author(s). – notice: The Author(s) 2025. This work is published under http://creativecommons.org/licenses/by-nc-nd/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. – notice: The Author(s) 2025 2025 |
| DBID | C6C AAYXX CITATION NPM 3V. 7QL 7QP 7QR 7SN 7SS 7ST 7T5 7T7 7TM 7TO 7X7 7XB 88E 8AO 8FD 8FE 8FG 8FH 8FI 8FJ 8FK ABUWG AEUYN AFKRA ARAPS AZQEC BBNVY BENPR BGLVJ BHPHI C1K CCPQU DWQXO FR3 FYUFA GHDGH GNUQQ H94 HCIFZ K9. LK8 M0S M1P M7P P5Z P62 P64 PHGZM PHGZT PIMPY PJZUB PKEHL PPXIY PQEST PQGLB PQQKQ PQUKI PRINS RC3 SOI 7X8 5PM DOA |
| DOI | 10.1038/s41467-025-61417-6 |
| DatabaseName | SpringerOpen Free (Free internet resource, activated by CARLI) CrossRef PubMed ProQuest Central (Corporate) Bacteriology Abstracts (Microbiology B) Calcium & Calcified Tissue Abstracts Chemoreception Abstracts Ecology Abstracts Entomology Abstracts (Full archive) Environment Abstracts Immunology Abstracts Industrial and Applied Microbiology Abstracts (Microbiology A) Nucleic Acids Abstracts Oncogenes and Growth Factors Abstracts Health & Medical Collection ProQuest Central (purchase pre-March 2016) Medical Database (Alumni Edition) ProQuest Pharma Collection Technology Research Database ProQuest SciTech Collection ProQuest Technology Collection ProQuest Natural Science Journals Hospital Premium Collection Hospital Premium Collection (Alumni Edition) ProQuest Central (Alumni) (purchase pre-March 2016) ProQuest Central (Alumni) One Sustainability ProQuest Central UK/Ireland Advanced Technologies & Computer Science Collection ProQuest Central Essentials - QC Biological Science Collection ProQuest Central ProQuest Technology Collection (LUT) Natural Science Collection Environmental Sciences and Pollution Management ProQuest One Community College ProQuest Central Korea Engineering Research Database Proquest Health Research Premium Collection Health Research Premium Collection (Alumni) ProQuest Central Student AIDS and Cancer Research Abstracts SciTech Premium Collection ProQuest Health & Medical Complete (Alumni) Biological Sciences ProQuest Health & Medical Collection Medical Database Biological Science Database Advanced Technologies & Aerospace Database ProQuest Advanced Technologies & Aerospace Collection Biotechnology and BioEngineering Abstracts Proquest Central Premium ProQuest One Academic Publicly Available Content Database ProQuest Health & Medical Research Collection ProQuest One Academic Middle East (New) One Health & Nursing ProQuest One Academic Eastern Edition (DO NOT USE) One Applied & Life Sciences ProQuest One Academic (retired) ProQuest One Academic UKI Edition ProQuest Central China Genetics Abstracts Environment Abstracts MEDLINE - Academic PubMed Central (Full Participant titles) DOAJ Directory of Open Access Journals |
| DatabaseTitle | CrossRef PubMed Publicly Available Content Database ProQuest Central Student Oncogenes and Growth Factors Abstracts ProQuest Advanced Technologies & Aerospace Collection ProQuest Central Essentials Nucleic Acids Abstracts SciTech Premium Collection ProQuest Central China Environmental Sciences and Pollution Management ProQuest One Applied & Life Sciences ProQuest One Sustainability Health Research Premium Collection Natural Science Collection Health & Medical Research Collection Biological Science Collection Chemoreception Abstracts Industrial and Applied Microbiology Abstracts (Microbiology A) ProQuest Central (New) ProQuest Medical Library (Alumni) Advanced Technologies & Aerospace Collection ProQuest Biological Science Collection ProQuest One Academic Eastern Edition ProQuest Hospital Collection ProQuest Technology Collection Health Research Premium Collection (Alumni) Biological Science Database Ecology Abstracts ProQuest Hospital Collection (Alumni) Biotechnology and BioEngineering Abstracts Entomology Abstracts ProQuest Health & Medical Complete ProQuest One Academic UKI Edition Engineering Research Database ProQuest One Academic Calcium & Calcified Tissue Abstracts ProQuest One Academic (New) Technology Collection Technology Research Database ProQuest One Academic Middle East (New) ProQuest Health & Medical Complete (Alumni) ProQuest Central (Alumni Edition) ProQuest One Community College ProQuest One Health & Nursing ProQuest Natural Science Collection ProQuest Pharma Collection ProQuest Central ProQuest Health & Medical Research Collection Genetics Abstracts Health and Medicine Complete (Alumni Edition) ProQuest Central Korea Bacteriology Abstracts (Microbiology B) AIDS and Cancer Research Abstracts ProQuest SciTech Collection Advanced Technologies & Aerospace Database ProQuest Medical Library Immunology Abstracts Environment Abstracts ProQuest Central (Alumni) MEDLINE - Academic |
| DatabaseTitleList | PubMed MEDLINE - Academic Publicly Available Content Database |
| Database_xml | – sequence: 1 dbid: DOA name: DOAJ Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website – sequence: 2 dbid: NPM name: PubMed url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 3 dbid: PIMPY name: Publicly Available Content Database url: http://search.proquest.com/publiccontent sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Biology |
| EISSN | 2041-1723 |
| EndPage | 9 |
| ExternalDocumentID | oai_doaj_org_article_473cbd33b8fe4f83a2ade29f90e1b685 PMC12267645 40670338 10_1038_s41467_025_61417_6 |
| Genre | Journal Article |
| GrantInformation_xml | – fundername: Ministero dell'Università e Ricerca - Fondo Italiano per la Scienza (Proj. n. FIS00001045) Ministero dell'Università e Ricerca Dipartimenti di Eccellenza 2023-2027 (DICUS 2.0) – fundername: EC | Horizon 2020 Framework Programme (EU Framework Programme for Research and Innovation H2020) grantid: 862893 funderid: https://doi.org/10.13039/100010661 – fundername: European Cooperation in Science and Technology (COST) grantid: 15128 funderid: https://doi.org/10.13039/501100000921 – fundername: EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council) grantid: 101039890 funderid: https://doi.org/10.13039/100010663 – fundername: Banca d'Italia (Bank of Italy) grantid: NAMASSTE-UNIFI funderid: https://doi.org/10.13039/501100003770 – fundername: Istituto Nazionale di Fisica Nucleare Grant NAMASSTE – fundername: Banca d'Italia (Bank of Italy) grantid: NAMASSTE-UNIFI – fundername: EC | Horizon 2020 Framework Programme (EU Framework Programme for Research and Innovation H2020) grantid: 862893 – fundername: EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council) grantid: 101039890 – fundername: European Cooperation in Science and Technology (COST) grantid: 15128 |
| GroupedDBID | --- 0R~ 39C 53G 5VS 70F 7X7 88E 8AO 8FE 8FG 8FH 8FI 8FJ AAHBH AAJSJ AASML ABUWG ACGFO ACGFS ACIWK ACMJI ACPRK ADBBV ADFRT ADMLS ADRAZ AENEX AEUYN AFKRA AFRAH AHMBA ALIPV ALMA_UNASSIGNED_HOLDINGS AMTXH AOIJS ARAPS ASPBG AVWKF AZFZN BBNVY BCNDV BENPR BGLVJ BHPHI BPHCQ BVXVI C6C CCPQU DIK EBLON EBS EE. EMOBN F5P FEDTE FYUFA GROUPED_DOAJ HCIFZ HMCUK HVGLF HYE HZ~ KQ8 LGEZI LK8 LOTEE M1P M7P M~E NADUK NAO NXXTH O9- OK1 P2P P62 PHGZM PHGZT PIMPY PPXIY PQGLB PQQKQ PROAC PSQYO RNS RNT RNTTT RPM SNYQT SV3 TSG UKHRP AAYXX AFFHD CITATION PJZUB NPM 3V. 7QL 7QP 7QR 7SN 7SS 7ST 7T5 7T7 7TM 7TO 7XB 8FD 8FK AZQEC C1K DWQXO FR3 GNUQQ H94 K9. M48 P64 PKEHL PQEST PQUKI PRINS RC3 SOI 7X8 PUEGO 5PM |
| ID | FETCH-LOGICAL-c543t-8ad9818ee5a62820a91a3de7eff1de3f86db92fd49a9621a8e8b8e53b1a8dc5d3 |
| IEDL.DBID | DOA |
| ISICitedReferencesCount | 1 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=001530788700013&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| ISSN | 2041-1723 |
| IngestDate | Fri Oct 03 12:53:44 EDT 2025 Tue Nov 04 02:03:58 EST 2025 Tue Aug 26 09:01:09 EDT 2025 Tue Oct 07 07:24:01 EDT 2025 Wed Jul 23 01:41:27 EDT 2025 Sat Nov 29 07:35:14 EST 2025 Tue Nov 18 21:08:58 EST 2025 Thu Jul 17 02:06:27 EDT 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 1 |
| Language | English |
| License | 2025. The Author(s). Open Access This article is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License, which permits any non-commercial use, sharing, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if you modified the licensed material. You do not have permission under this licence to share adapted material derived from this article or parts of it. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by-nc-nd/4.0/. |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c543t-8ad9818ee5a62820a91a3de7eff1de3f86db92fd49a9621a8e8b8e53b1a8dc5d3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
| ORCID | 0000-0003-3473-9682 0000-0001-5649-0449 0000-0002-6254-2003 0000-0003-4040-5531 0009-0005-9761-6390 0000-0003-3783-2700 |
| OpenAccessLink | https://doaj.org/article/473cbd33b8fe4f83a2ade29f90e1b685 |
| PMID | 40670338 |
| PQID | 3230619452 |
| PQPubID | 546298 |
| PageCount | 9 |
| ParticipantIDs | doaj_primary_oai_doaj_org_article_473cbd33b8fe4f83a2ade29f90e1b685 pubmedcentral_primary_oai_pubmedcentral_nih_gov_12267645 proquest_miscellaneous_3230906401 proquest_journals_3230619452 pubmed_primary_40670338 crossref_primary_10_1038_s41467_025_61417_6 crossref_citationtrail_10_1038_s41467_025_61417_6 springer_journals_10_1038_s41467_025_61417_6 |
| PublicationCentury | 2000 |
| PublicationDate | 2025-07-16 |
| PublicationDateYYYYMMDD | 2025-07-16 |
| PublicationDate_xml | – month: 07 year: 2025 text: 2025-07-16 day: 16 |
| PublicationDecade | 2020 |
| PublicationPlace | London |
| PublicationPlace_xml | – name: London – name: England |
| PublicationTitle | Nature communications |
| PublicationTitleAbbrev | Nat Commun |
| PublicationTitleAlternate | Nat Commun |
| PublicationYear | 2025 |
| Publisher | Nature Publishing Group UK Nature Publishing Group Nature Portfolio |
| Publisher_xml | – name: Nature Publishing Group UK – name: Nature Publishing Group – name: Nature Portfolio |
| References | B Kintzel (61417_CR31) 2021; 60 CA Bates (61417_CR36) 1969; 2 MF Islam (61417_CR14) 2010; 82 BO Roos (61417_CR43) 2004; 108 NA Spaldin (61417_CR1) 2005; 309 LN Bulaevskii (61417_CR15) 2008; 78 61417_CR37 J Van Slageren (61417_CR7) 2019; 18 S Ferrer (61417_CR21) 2012; 51 B Kintzel (61417_CR32) 2018; 54 AE Reed (61417_CR41) 1985; 83 M Fittipaldi (61417_CR30) 2019; 18 61417_CR39 KY Choi (61417_CR22) 2006; 96 D Khomskii (61417_CR2) 2009; 2 M Fiebig (61417_CR4) 2016; 1 NA Spaldin (61417_CR6) 2019; 18 F le Mardelé (61417_CR19) 2025; 16 AK Boudalis (61417_CR25) 2018; 24 A Maisuradze (61417_CR29) 2012; 108 JF Nossa (61417_CR20) 2012; 85 CA Bates (61417_CR35) 1968; 1 M Trif (61417_CR13) 2010; 82 S Stoll (61417_CR34) 2006; 178 DI Khomskii (61417_CR16) 2010; 22 F Matsukura (61417_CR3) 2015; 10 VN Golovach (61417_CR8) 2006; 74 MF Islam (61417_CR18) 2024; 109 61417_CR23 61417_CR45 M Trif (61417_CR12) 2008; 101 BO Roos (61417_CR44) 2005; 109 J Robert (61417_CR26) 2020; 141 F Weigend (61417_CR40) 2005; 7 M Lewkowitz (61417_CR27) 2023; 13 J Peisach (61417_CR38) 1974; 165 J Liu (61417_CR24) 2019; 122 Z Liu (61417_CR9) 2020; 7 BE Kane (61417_CR11) 1998; 393 P Wysling (61417_CR28) 1975; 9 J Liu (61417_CR10) 2021; 17 DI Khomskii (61417_CR17) 2012; 3 I Fdez. Galván (61417_CR42) 2019; 15 61417_CR5 ET Spielberg (61417_CR33) 2015; 54 |
| References_xml | – volume: 178 start-page: 42 year: 2006 ident: 61417_CR34 publication-title: J. Magn. Reson. doi: 10.1016/j.jmr.2005.08.013 – volume: 2 start-page: 476 year: 1969 ident: 61417_CR36 publication-title: J. Phys. C: Solid State Phys. doi: 10.1088/0022-3719/2/3/312 – volume: 60 start-page: 8832 year: 2021 ident: 61417_CR31 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202017116 – volume: 10 start-page: 209 year: 2015 ident: 61417_CR3 publication-title: Nat. Nanotechnol. doi: 10.1038/nnano.2015.22 – volume: 2 start-page: 20 year: 2009 ident: 61417_CR2 publication-title: Physics doi: 10.1103/Physics.2.20 – volume: 96 start-page: 107202 year: 2006 ident: 61417_CR22 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.96.107202 – volume: 18 start-page: 300 year: 2019 ident: 61417_CR7 publication-title: Nat. Mater. doi: 10.1038/s41563-019-0314-7 – ident: 61417_CR45 – volume: 101 start-page: 217201 year: 2008 ident: 61417_CR12 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.101.217201 – ident: 61417_CR39 – volume: 85 start-page: 085427 year: 2012 ident: 61417_CR20 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.85.085427 – volume: 108 start-page: 247211 year: 2012 ident: 61417_CR29 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.108.247211 – volume: 1 start-page: 16046 year: 2016 ident: 61417_CR4 publication-title: Nat. Rev. Mater. doi: 10.1038/natrevmats.2016.46 – volume: 54 start-page: 3432 year: 2015 ident: 61417_CR33 publication-title: Inorg. Chem. doi: 10.1021/ic503095t – volume: 51 start-page: 985 year: 2012 ident: 61417_CR21 publication-title: Inorg. Chem. doi: 10.1021/ic2020034 – volume: 83 start-page: 735 year: 1985 ident: 61417_CR41 publication-title: J. Chem. Phys. doi: 10.1063/1.449486 – volume: 18 start-page: 203 year: 2019 ident: 61417_CR6 publication-title: Nat. Mater. doi: 10.1038/s41563-018-0275-2 – volume: 82 start-page: 045429 year: 2010 ident: 61417_CR13 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.82.045429 – volume: 13 start-page: 2769 year: 2023 ident: 61417_CR27 publication-title: Sci. Rep. doi: 10.1038/s41598-023-29840-1 – ident: 61417_CR5 doi: 10.1038/s41563-019-0310-y – volume: 16 start-page: 1198 year: 2025 ident: 61417_CR19 publication-title: Nat. Commun. doi: 10.1038/s41467-025-56453-1 – ident: 61417_CR37 – volume: 17 start-page: 1205 year: 2021 ident: 61417_CR10 publication-title: Nat. Phys. doi: 10.1038/s41567-021-01355-4 – volume: 108 start-page: 2851 year: 2004 ident: 61417_CR43 publication-title: J. Phys. Chem. A doi: 10.1021/jp031064+ – volume: 82 start-page: 155446 year: 2010 ident: 61417_CR14 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.82.155446 – volume: 78 start-page: 024402 year: 2008 ident: 61417_CR15 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.78.024402 – volume: 1 start-page: 877 year: 1968 ident: 61417_CR35 publication-title: J. Phys. C: Solid State Phys. doi: 10.1088/0022-3719/1/4/307 – volume: 3 year: 2012 ident: 61417_CR17 publication-title: Nat. Commun. doi: 10.1038/ncomms1904 – volume: 109 start-page: 6575 year: 2005 ident: 61417_CR44 publication-title: J. Phys. Chem. A doi: 10.1021/jp0581126 – volume: 18 start-page: 329 year: 2019 ident: 61417_CR30 publication-title: Nat. Mater. doi: 10.1038/s41563-019-0288-5 – volume: 15 start-page: 5925 year: 2019 ident: 61417_CR42 publication-title: J. Chem. Theory Comput doi: 10.1021/acs.jctc.9b00532 – ident: 61417_CR23 – volume: 74 start-page: 165319 year: 2006 ident: 61417_CR8 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.74.165319 – volume: 22 start-page: 164209 year: 2010 ident: 61417_CR16 publication-title: J. Phys. Cond. Matter doi: 10.1088/0953-8984/22/16/164209 – volume: 24 start-page: 14896 year: 2018 ident: 61417_CR25 publication-title: Chem. Eur. J. doi: 10.1002/chem.201803038 – volume: 9 start-page: 635 year: 1975 ident: 61417_CR28 publication-title: J. Phys. C: Solid State Phys. doi: 10.1088/0022-3719/9/4/014 – volume: 54 start-page: 12934 year: 2018 ident: 61417_CR32 publication-title: Chem. Commun. doi: 10.1039/C8CC06741D – volume: 109 start-page: 214407 year: 2024 ident: 61417_CR18 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.109.214407 – volume: 141 start-page: 19765 year: 2020 ident: 61417_CR26 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.9b09101 – volume: 309 start-page: 391 year: 2005 ident: 61417_CR1 publication-title: Science doi: 10.1126/science.1113357 – volume: 165 start-page: 691 year: 1974 ident: 61417_CR38 publication-title: Arch. Biochem. Biophys. doi: 10.1016/0003-9861(74)90298-7 – volume: 7 start-page: 1557 year: 2020 ident: 61417_CR9 publication-title: Natl Sci. Rev. doi: 10.1093/nsr/nwaa148 – volume: 393 start-page: 133 year: 1998 ident: 61417_CR11 publication-title: Nature doi: 10.1038/30156 – volume: 122 start-page: 37202 year: 2019 ident: 61417_CR24 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.122.037202 – volume: 7 start-page: 3297 year: 2005 ident: 61417_CR40 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b508541a |
| SSID | ssj0000391844 |
| Score | 2.4833505 |
| Snippet | Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a mechanism... Abstract Spin-electric effects are crucial for quantum technologies, offering several advantages over standard magnetic field-based spin control. Seeking a... |
| SourceID | doaj pubmedcentral proquest pubmed crossref springer |
| SourceType | Open Website Open Access Repository Aggregation Database Index Database Enrichment Source Publisher |
| StartPage | 6564 |
| SubjectTerms | 119/118 639/638/263 639/638/911 639/766/119/997 Anisotropy Copper Crystals Electric control Electric fields Electron paramagnetic resonance Electron spin resonance Electrons Exchanging Humanities and Social Sciences Investigations Ligands Magnetic fields multidisciplinary Qubits (quantum computing) Science Science (multidisciplinary) Single crystals Spectrum analysis Spin-orbit interactions Symmetry |
| SummonAdditionalLinks | – databaseName: Biological Science Database dbid: M7P link: http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1Jb9QwFH6CAlIv7IVAQUbiBlHj2HHsE6KoFaeqB5B6s7wOI7XJMJlW8O-xHSfVsPTC1Xak57zFz37LB_C20Rp7QVVJsaElJUyV2ghRBtGxGqum0p4nsIn25ISfnYnT_OA25LTKySYmQ217E9_ID0j0lcONu6k_rL6XETUqRlczhMZtuBO7JJCUunc6v7HE7uec0lwrUxF-MNBkGSKGaziXgoFmW-dRatv_N1_zz5TJ3-Km6Tg6fvC_G3kI97Mjij6OkvMIbrnuMdwboSl_PoHDo4SPszQoJ7Oj3qMLtehi0SNyP8aCYbTskEIXE8QuGlZhIAKBdItz9xS-Hh99-fS5zHgLpWko2ZRcWRHOb-caxcJNrFICK2Jd67zH1hHPmdWi9pYKJViNFXdcc9eQwFNuTWPJHux0feeeA-IRwKP2Yb4NLqEioqE6XASpUtap1lQF4OmvS5ObkUdMjHOZguKEy5FTMnBKJk5JVsC7-ZvV2IrjxtWHkZnzythGOw3064XMWilpS4y2hGjuHfWcqDrQVwsvKoc1400B-xMPZdbtQV4zsIA383TQyhhqUZ3rL8c1IgZJcQHPRsmZKaGxNIoQXgDfkqktUrdnuuW31PkbB2e5ZTTQ9X4Sv2u6_v0vXty8jZewW0eNiO1C2T7sbNaX7hXcNVeb5bB-nVTqF7O9J-k priority: 102 providerName: ProQuest |
| Title | Electric control of magnetic exchange in a molecular spin triangle |
| URI | https://link.springer.com/article/10.1038/s41467-025-61417-6 https://www.ncbi.nlm.nih.gov/pubmed/40670338 https://www.proquest.com/docview/3230619452 https://www.proquest.com/docview/3230906401 https://pubmed.ncbi.nlm.nih.gov/PMC12267645 https://doaj.org/article/473cbd33b8fe4f83a2ade29f90e1b685 |
| Volume | 16 |
| WOSCitedRecordID | wos001530788700013&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVAON databaseName: DOAJ Directory of Open Access Journals customDbUrl: eissn: 2041-1723 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000391844 issn: 2041-1723 databaseCode: DOA dateStart: 20150101 isFulltext: true titleUrlDefault: https://www.doaj.org/ providerName: Directory of Open Access Journals – providerCode: PRVHPJ databaseName: ROAD: Directory of Open Access Scholarly Resources customDbUrl: eissn: 2041-1723 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000391844 issn: 2041-1723 databaseCode: M~E dateStart: 20100101 isFulltext: true titleUrlDefault: https://road.issn.org providerName: ISSN International Centre – providerCode: PRVPQU databaseName: Advanced Technologies & Aerospace Database customDbUrl: eissn: 2041-1723 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000391844 issn: 2041-1723 databaseCode: P5Z dateStart: 20100101 isFulltext: true titleUrlDefault: https://search.proquest.com/hightechjournals providerName: ProQuest – providerCode: PRVPQU databaseName: Biological Science Database customDbUrl: eissn: 2041-1723 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000391844 issn: 2041-1723 databaseCode: M7P dateStart: 20100101 isFulltext: true titleUrlDefault: http://search.proquest.com/biologicalscijournals providerName: ProQuest – providerCode: PRVPQU databaseName: Health & Medical Collection customDbUrl: eissn: 2041-1723 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000391844 issn: 2041-1723 databaseCode: 7X7 dateStart: 20100101 isFulltext: true titleUrlDefault: https://search.proquest.com/healthcomplete providerName: ProQuest – providerCode: PRVPQU databaseName: ProQuest Central customDbUrl: eissn: 2041-1723 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000391844 issn: 2041-1723 databaseCode: BENPR dateStart: 20100101 isFulltext: true titleUrlDefault: https://www.proquest.com/central providerName: ProQuest – providerCode: PRVPQU databaseName: Publicly Available Content Database customDbUrl: eissn: 2041-1723 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000391844 issn: 2041-1723 databaseCode: PIMPY dateStart: 20100101 isFulltext: true titleUrlDefault: http://search.proquest.com/publiccontent providerName: ProQuest |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1Lb9QwEB5BAYkL4k1KuzISN4gax3ZiH1m0FRxYRQikhYtlx3a7UputulsE_75jJ7t0KY8LlxxsRxrNjD0zmscH8FJYS4PiJue05Tlnlcltq1SOquMsNaKwQSawiXo6lbOZaq5AfcWasH48cM-4A16z1jrGrAyeB8lMaZwvVVCFp7aSaXopej1Xgqn0BjOFoQsfumQKJg-WPL0JEb0VLRI-zdWWJUoD-3_nZV4vlvwlY5oM0eF9uDd4kORNT_kDuOG7h3Cnx5T88QjGkwRsM2_JUIVOFoGcmqMudisS_73v9CXzjhhyusbGJcszXIgIHt3RiX8Mnw8nn96-yweghLwVnK1yaZxCw-u9MBWGUIVR1DDnax8CdZ4FWTmryuC4MqoqqZFeWukFQ2FI1wrHnsBOt-j8MyAyIm-UAfdr9OUMU4JbjOC4Qa6bui0yoGum6XaYIh7BLE50ymYzqXtGa2S0TozWVQavNv-c9TM0_np6HGWxORnnX6cF1Ao9aIX-l1ZksLeWpB4u5VKzGG5RxUWZwYvNNl6nmCMxnV9c9GdUzG7SDJ72gt9QwmNPE4b0GcgtldgidXunmx-nkd0Uvdy64kjX67X2_KTrz7zY_R-8eA53y6j2cRpotQc7q_MLvw-322-r-fJ8BDfrWZ2-cgS3xpNp83GU7tIolsE2-G3EV9xp3n9ovlwCZY4h2w |
| linkProvider | Directory of Open Access Journals |
| linkToHtml | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMw1V1Jb9QwFH4qBQQX9iVQwEhwgqiJ7ST2ASEKrVq1jHooUm_G6zBSmwwzU6B_it-I7SzVsPTWA9fYiV6Sz2_x83sfwItCqdxxKlOaa5pSUspUac5TDx2jcllkyrFINlGNRuzwkO-vwM--FiYcq-x1YlTUptFhj3ydBF_ZR9wFfjv9mgbWqJBd7Sk0Wljs2tPvPmSbv9n54P_vS4y3Ng_eb6cdq0CqC0oWKZOGeytlbSFLH29kkueSGFtZ53JjiWOlURw7Q7nkJc4ls0wxWxAvOTO6MMQ_9xJc9m4EZvGo4P6wpxO6rTNKu9qcjLD1OY2aKHDGejvoDUK5ZP8iTcDffNs_j2j-lqeN5m_r5v_24W7Bjc7RRu_alXEbVmx9B6621Jund2FjM_L_TDTqDuujxqFjOa5DUSeyP9qCaDSpkUTHPYUwmk_9hUB0Uo-P7D34dCEvcB9W66a2DwGxQFCCnR-vvMsrCS-o8oEuldJYWeksgbz_y0J3zdYD58eRiEl_wkSLDOGRISIyRJnAq-Geadtq5NzZGwE8w8zQJjxeaGZj0WkdQSuilSFEMWepY0RiLx_mjmc2VyUrEljrMSM63TUXZ4BJ4Pkw7LVOSCXJ2jYn7RweksB5Ag9apA6S0FD6RQhLgC1heEnU5ZF68iV2Ns99MFCV1Mv1uof7mVz__haPzn-NZ3Bt--DjntjbGe0-hus4rMbQGrVcg9XF7MQ-gSv622Iynz2NyxnB54teBr8AWvSHpA |
| linkToPdf | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMw1V1Lb9QwEB6V8hAX3o9AASPBiUYbx05iHxCitCuqotUeQOrN2LG9rNQmy2YL9K_x67CdR7U8euuBq-1E4_jzjCeemQ_gRaYUtpzKmOKSxpTkMlYl57GDjlZYZomyLJBNFJMJOzzk0w342efC-LDKXicGRa3r0v8jHxF_VnYed5aObBcWMd0dv1l8jT2DlL9p7ek0WogcmNPvzn1rXu_vurV-mabjvY_v3scdw0BcZpSsYiY1dxbLmEzmzvdIJMeSaFMYa7E2xLJcK55aTbnkeYolM0wxkxE3C6bLTBP33ktwufBFy0PY4HT4v-MrrzNKuzydhLBRQ4NW8vyxziY645Cv2cJAGfC3c-6f4Zq_3dkGUzi--T9_xFtwozuAo7ftjrkNG6a6A1dbSs7Tu7CzF3iB5iXqgvhRbdGxnFU-2ROZH22iNJpXSKLjnloYNQvX4AlQqtmRuQefLmQC92GzqivzEBDzxCWpdf2FOwpLwjOqnANMpdRGFmUSAe5XXJRdEXbPBXIkQjAAYaJFiXAoEQElIo_g1fDMoi1Bcu7oHQ-kYaQvHx4a6uVMdNpI0IKUShOimDXUMiJTJ1_KLU8MVjnLItjq8SM6ndaIM_BE8HzodtrIXzHJytQn7RjuL4dxBA9a1A6SUJ8SRgiLgK3heU3U9Z5q_iVUPMfOSShy6uTa7qF_Jte_v8Wj86fxDK459IsP-5ODx3A99RvTV0zNt2BztTwxT-BK-W01b5ZPw85G8Pmid8EvsBeQYQ |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Electric+control+of+magnetic+exchange+in+a+molecular+spin+triangle&rft.jtitle=Nature+communications&rft.au=Alberto+Cini&rft.au=Michael+B%C3%B6hme&rft.au=Benjamin+Kintzel&rft.au=Mauro+Perfetti&rft.date=2025-07-16&rft.pub=Nature+Portfolio&rft.eissn=2041-1723&rft.volume=16&rft.issue=1&rft.spage=1&rft.epage=9&rft_id=info:doi/10.1038%2Fs41467-025-61417-6&rft.externalDBID=DOA&rft.externalDocID=oai_doaj_org_article_473cbd33b8fe4f83a2ade29f90e1b685 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2041-1723&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2041-1723&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2041-1723&client=summon |