A fast-charging/discharging and long-term stable artificial electrode enabled by space charge storage mechanism
Lithium‐ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast charging/discharging, long-term stable and high energy charge-storage properties can be realized in an artificial electrode made from a mixed electr...
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| Vydáno v: | Nature communications Ročník 15; číslo 1; s. 3778 - 12 |
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| Hlavní autoři: | , , , , , , , , |
| Médium: | Journal Article |
| Jazyk: | angličtina |
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London
Nature Publishing Group UK
06.05.2024
Nature Publishing Group Nature Portfolio |
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| ISSN: | 2041-1723, 2041-1723 |
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| Abstract | Lithium‐ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast charging/discharging, long-term stable and high energy charge-storage properties can be realized in an artificial electrode made from a mixed electronic/ionic conductor material (Fe/Li
x
M, where M = O, F, S, N) enabled by a space charge principle. Particularly, the Fe/Li
2
O electrode is able to be charged/discharged to 126 mAh g
−1
in 6 s at a high current density of up to 50 A g
−1
, and it also shows stable cycling performance for 30,000 cycles at a current density of 10 A g
−1
, with a mass-loading of ~2.5 mg cm
−2
of the electrode materials. This study demonstrates the critical role of the space charge storage mechanism in advancing electrochemical energy storage and provides an unconventional perspective for designing high-performance anode materials for lithium-ion batteries.
Lithium-ion batteries with fast-charging properties are urgently needed for wide adoption of electric vehicles. Here, the authors show a fast charging/discharging and long-term stable electrode made from a mixed electronic/ionic conductor material enabled by a space charge mechanism. |
|---|---|
| AbstractList | Abstract Lithium‐ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast charging/discharging, long-term stable and high energy charge-storage properties can be realized in an artificial electrode made from a mixed electronic/ionic conductor material (Fe/LixM, where M = O, F, S, N) enabled by a space charge principle. Particularly, the Fe/Li2O electrode is able to be charged/discharged to 126 mAh g−1 in 6 s at a high current density of up to 50 A g−1, and it also shows stable cycling performance for 30,000 cycles at a current density of 10 A g−1, with a mass-loading of ~2.5 mg cm−2 of the electrode materials. This study demonstrates the critical role of the space charge storage mechanism in advancing electrochemical energy storage and provides an unconventional perspective for designing high-performance anode materials for lithium-ion batteries. Lithium‐ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast charging/discharging, long-term stable and high energy charge-storage properties can be realized in an artificial electrode made from a mixed electronic/ionic conductor material (Fe/LixM, where M = O, F, S, N) enabled by a space charge principle. Particularly, the Fe/Li2O electrode is able to be charged/discharged to 126 mAh g−1 in 6 s at a high current density of up to 50 A g−1, and it also shows stable cycling performance for 30,000 cycles at a current density of 10 A g−1, with a mass-loading of ~2.5 mg cm−2 of the electrode materials. This study demonstrates the critical role of the space charge storage mechanism in advancing electrochemical energy storage and provides an unconventional perspective for designing high-performance anode materials for lithium-ion batteries. Lithium-ion batteries with fast-charging properties are urgently needed for wide adoption of electric vehicles. Here, the authors show a fast charging/discharging and long-term stable electrode made from a mixed electronic/ionic conductor material enabled by a space charge mechanism. Lithium‐ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast charging/discharging, long-term stable and high energy charge-storage properties can be realized in an artificial electrode made from a mixed electronic/ionic conductor material (Fe/Li x M, where M = O, F, S, N) enabled by a space charge principle. Particularly, the Fe/Li 2 O electrode is able to be charged/discharged to 126 mAh g −1 in 6 s at a high current density of up to 50 A g −1 , and it also shows stable cycling performance for 30,000 cycles at a current density of 10 A g −1 , with a mass-loading of ~2.5 mg cm −2 of the electrode materials. This study demonstrates the critical role of the space charge storage mechanism in advancing electrochemical energy storage and provides an unconventional perspective for designing high-performance anode materials for lithium-ion batteries. Lithium-ion batteries with fast-charging properties are urgently needed for wide adoption of electric vehicles. Here, the authors show a fast charging/discharging and long-term stable electrode made from a mixed electronic/ionic conductor material enabled by a space charge mechanism. Lithium-ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast charging/discharging, long-term stable and high energy charge-storage properties can be realized in an artificial electrode made from a mixed electronic/ionic conductor material (Fe/LixM, where M = O, F, S, N) enabled by a space charge principle. Particularly, the Fe/Li2O electrode is able to be charged/discharged to 126 mAh g-1 in 6 s at a high current density of up to 50 A g-1, and it also shows stable cycling performance for 30,000 cycles at a current density of 10 A g-1, with a mass-loading of ~2.5 mg cm-2 of the electrode materials. This study demonstrates the critical role of the space charge storage mechanism in advancing electrochemical energy storage and provides an unconventional perspective for designing high-performance anode materials for lithium-ion batteries.Lithium-ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast charging/discharging, long-term stable and high energy charge-storage properties can be realized in an artificial electrode made from a mixed electronic/ionic conductor material (Fe/LixM, where M = O, F, S, N) enabled by a space charge principle. Particularly, the Fe/Li2O electrode is able to be charged/discharged to 126 mAh g-1 in 6 s at a high current density of up to 50 A g-1, and it also shows stable cycling performance for 30,000 cycles at a current density of 10 A g-1, with a mass-loading of ~2.5 mg cm-2 of the electrode materials. This study demonstrates the critical role of the space charge storage mechanism in advancing electrochemical energy storage and provides an unconventional perspective for designing high-performance anode materials for lithium-ion batteries. Lithium-ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast charging/discharging, long-term stable and high energy charge-storage properties can be realized in an artificial electrode made from a mixed electronic/ionic conductor material (Fe/Li M, where M = O, F, S, N) enabled by a space charge principle. Particularly, the Fe/Li O electrode is able to be charged/discharged to 126 mAh g in 6 s at a high current density of up to 50 A g , and it also shows stable cycling performance for 30,000 cycles at a current density of 10 A g , with a mass-loading of ~2.5 mg cm of the electrode materials. This study demonstrates the critical role of the space charge storage mechanism in advancing electrochemical energy storage and provides an unconventional perspective for designing high-performance anode materials for lithium-ion batteries. Lithium‐ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast charging/discharging, long-term stable and high energy charge-storage properties can be realized in an artificial electrode made from a mixed electronic/ionic conductor material (Fe/Li x M, where M = O, F, S, N) enabled by a space charge principle. Particularly, the Fe/Li 2 O electrode is able to be charged/discharged to 126 mAh g −1 in 6 s at a high current density of up to 50 A g −1 , and it also shows stable cycling performance for 30,000 cycles at a current density of 10 A g −1 , with a mass-loading of ~2.5 mg cm −2 of the electrode materials. This study demonstrates the critical role of the space charge storage mechanism in advancing electrochemical energy storage and provides an unconventional perspective for designing high-performance anode materials for lithium-ion batteries. |
| ArticleNumber | 3778 |
| Author | Li, Qiang Wang, Tiansheng Zuo, Fengkai Zhu, Yue Zhao, Linyi Ju, Zhengyu Li, Hongsen Yu, Guihua Li, Yuhao |
| Author_xml | – sequence: 1 givenname: Linyi surname: Zhao fullname: Zhao, Linyi organization: College of Physics, Qingdao University – sequence: 2 givenname: Tiansheng surname: Wang fullname: Wang, Tiansheng organization: College of Physics, Qingdao University – sequence: 3 givenname: Fengkai surname: Zuo fullname: Zuo, Fengkai organization: College of Physics, Qingdao University – sequence: 4 givenname: Zhengyu surname: Ju fullname: Ju, Zhengyu organization: Materials Science and Engineering Program and Walker Department of Mechanical Engineering, The University of Texas at Austin – sequence: 5 givenname: Yuhao surname: Li fullname: Li, Yuhao organization: College of Physics, Qingdao University – sequence: 6 givenname: Qiang surname: Li fullname: Li, Qiang organization: College of Physics, Qingdao University – sequence: 7 givenname: Yue orcidid: 0000-0002-7370-1954 surname: Zhu fullname: Zhu, Yue email: zhuyue@ouc.edu.cn organization: Materials Science and Engineering Program and Walker Department of Mechanical Engineering, The University of Texas at Austin, School of Materials Science and Engineering, Ocean University of China – sequence: 8 givenname: Hongsen orcidid: 0000-0001-6453-2135 surname: Li fullname: Li, Hongsen email: hsli@qdu.edu.cn organization: College of Physics, Qingdao University – sequence: 9 givenname: Guihua orcidid: 0000-0002-3253-0749 surname: Yu fullname: Yu, Guihua email: ghyu@austin.utexas.edu organization: Materials Science and Engineering Program and Walker Department of Mechanical Engineering, The University of Texas at Austin |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38710689$$D View this record in MEDLINE/PubMed |
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| Snippet | Lithium‐ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast... Lithium-ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast... Abstract Lithium‐ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that... |
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| Title | A fast-charging/discharging and long-term stable artificial electrode enabled by space charge storage mechanism |
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