[Co(TPP)]‐Catalyzed Formation of Substituted Piperidines

Radical cyclization via cobalt(III)‐carbene radical intermediates is a powerful method for the synthesis of (hetero)cyclic structures. Building on the recently reported synthesis of five‐membered N‐heterocyclic pyrrolidines catalyzed by CoII porphyrins, the [Co(TPP)]‐catalyzed formation of useful si...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 25; no. 22; pp. 5658 - 5663
Main Authors:	Lankelma, Marianne, Olivares, Astrid M., de Bruin, Bas
Format:	Journal Article
Language:	English
Published:	WEINHEIM Wiley 17.04.2019 Wiley Subscription Services, Inc John Wiley and Sons Inc
Subjects:	Aldehydes Alkenes Chemistry Chemistry, Multidisciplinary Cobalt Communication Communications C−C coupling C−H activation homogeneous catalysis Intermediates Mathematical analysis nitrogen heterocycles Physical Sciences Porphyrins radicals Science & Technology C-C coupling CATALYSIS C-H activation homogeneous catalysis radicals nitrogen heterocycles CONSTRUCTION CYCLOPROPANATION COBALT(II) INDOLINES CARBENE RADICALS CYCLIZATION C−C coupling C−H activation
ISSN:	0947-6539, 1521-3765
Online Access:	Get full text
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