Development of dummy molecularly imprinted based on functionalized silica nanoparticles for determination of acrylamide in processed food by matrix solid phase dispersion

The MISNPs-MSPD extraction procedure. [Display omitted] •We develop a new strategy for synthesis novel dummy molecularly imprinted silica nanoparticles.•We employed propanamide as dummy template successfully.•The dummy molecularly imprinted silica nanoparticles were used as sorbent in MSPD.•Improvin...

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Veröffentlicht in:Food chemistry Jg. 210; S. 78 - 84
Hauptverfasser: Arabi, Maryam, Ghaedi, Mehrorang, Ostovan, Abbas
Format: Journal Article
Sprache:Englisch
Veröffentlicht: England Elsevier Ltd 01.11.2016
Schlagworte:
Acrylamide
Acrylamide - analysis
acrylamides
binding capacity
breads
Chromatography, High Pressure Liquid - methods
Dummy template
Food Contamination - analysis
food matrix
high performance liquid chromatography
Matrix solid phase dispersion
Microscopy, Electron, Scanning
molecular imprinting
Molecular Imprinting - methods
Molecularly imprinted
nanoparticles
Nanoparticles - chemistry
processed foods
response surface methodology
scanning electron microscopy
silica
Silica nanoparticles
Silicon Dioxide - chemistry
solid phase extraction
Solid Phase Extraction - methods
solvents
spectroscopy
temperature
transmission electron microscopes
transmission electron microscopy
Silica nanoparticles
Acrylamide
Dummy template
Matrix solid phase dispersion
Molecularly imprinted
ISSN:0308-8146, 1873-7072
Online-Zugang:Volltext
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Zusammenfassung:The MISNPs-MSPD extraction procedure. [Display omitted] •We develop a new strategy for synthesis novel dummy molecularly imprinted silica nanoparticles.•We employed propanamide as dummy template successfully.•The dummy molecularly imprinted silica nanoparticles were used as sorbent in MSPD.•Improving existing method for biscuit and bread analysis in agreement with the green chemistry.•The proposed method has the advantage of facility, simplicity and high-efficiency. A novel technique was applied for the synthesis of dummy molecularly imprinted silica nanoparticles (DMISNPs). DMISNPs were characterized by Fourier transmission infrared spectrometry, scanning electron microscopy and transmission electron microscope. The material was used as dispersant for the analysis of biscuit and bread samples using matrix solid phase dispersion (MSPD). Of advantages of such approach may be counted as the simplicity of synthesis procedure, low consumption of organic solvent, mild working temperature during the synthesis, high binding capacity and affinity. The effect of various parameters such as sample-to-dispersant ratio and eluents volume on extraction recovery was investigated and optimized by central composite design under response surface methodology. It was proven that the proposed dispersant leads to high affinity toward acrylamide even in complicated matrices. Quantification of the acrylamide was carried out by high performance liquid chromatography with UV detection (HPLC-UV).
Bibliographie:ObjectType-Article-1
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ISSN:0308-8146
1873-7072
DOI:10.1016/j.foodchem.2016.04.080