NIR‐Emissive Chromium(0), Molybdenum(0), and Tungsten(0) Complexes in the Solid State at Room Temperature

The development of NIR emitters based on earth‐abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl complexes with a pyridyl‐mesoionic carbene (MIC) based ligand. A detailed photophysical investigation shows that all the complexes exhibit du...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 27; no. 51; pp. 12959 - 12964
Main Authors:	Boden, Pit, Di Martino‐Fumo, Patrick, Bens, Tobias, Steiger, Sophie, Albold, Uta, Niedner‐Schatteburg, Gereon, Gerhards, Markus, Sarkar, Biprajit
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 09.09.2021 John Wiley and Sons Inc
Subjects:	Atomic energy levels Carbonyl compounds carbonyl ligands Carbonyls Chemistry Chromium Communication Communications Density functional theory Emissions Emissivity Emitters mesoionic carbenes Molybdenum NIR II emitters Room temperature step-scan FTIR spectroscopy Triplet state Tungsten X-ray diffraction mesoionic carbenes X-ray diffraction step-scan FTIR spectroscopy NIR II emitters carbonyl ligands
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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