The Interplay between Kinetics and Thermodynamics in Furan Diels–Alder Chemistry for Sustainable Chemicals Production

Biomass‐derived furanic platform molecules have emerged as promising building blocks for renewable chemicals and functional materials. To this aim, the Diels–Alder (DA) cycloaddition stands out as a versatile strategy to convert these renewable resources in highly atom‐efficient ways. Despite nearly...

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Vydáno v:Angewandte Chemie International Edition Ročník 61; číslo 17; s. e202114720 - n/a
Hlavní autoři: Cioc, Răzvan C., Crockatt, Marc, Waal, Jan C., Bruijnincx, Pieter C. A.
Médium: Journal Article
Jazyk:angličtina
Vydáno: Germany Wiley Subscription Services, Inc 19.04.2022
John Wiley and Sons Inc
Vydání:International ed. in English
Témata:
Alkenes
Chemicals
Chemistry
Cycloaddition
Cycloaddition Reaction
Diels-Alder reactions
Diels–Alder reaction
Functional materials
furan
Furans
Furans - chemistry
green chemistry
Kinetics
Pesticides
Renewable resources
Review
Reviews
Sustainable production
Sustainable yield
Thermodynamics
thermodynamics
Diels-Alder reaction
furan
kinetics
green chemistry
ISSN:1433-7851, 1521-3773, 1521-3773
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Shrnutí:Biomass‐derived furanic platform molecules have emerged as promising building blocks for renewable chemicals and functional materials. To this aim, the Diels–Alder (DA) cycloaddition stands out as a versatile strategy to convert these renewable resources in highly atom‐efficient ways. Despite nearly a century worth of examples of furan DA chemistry, clear structure–reactivity–stability relationships are still to be established. Detailed understanding of the intricate interplay between kinetics and thermodynamics in these very particular [4+2] cycloadditions is essential to push further development and truly expand the scope beyond the ubiquitous addend combinations of electron‐rich furans and electron‐deficient olefins. Herein, we provide pertinent examples of DA chemistry, taken from various fields, to highlight trends, establish correlations and answer open questions in the field with the aim to support future efforts in the sustainable chemicals and materials production. The furan Diels–Alder (DA) cycloaddition is a powerful green methodology to upgrade bio‐derived resources into valuable, renewable chemical products. The intricate interplay between kinetics and thermodynamics often complicates the understanding of this chemistry. In this review we provide simple structure–reactivity–stability relationships to guide future efforts in the design of efficient new synthesis routes based on furan DA reactions.
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ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.202114720