Advanced Isoconversional Kinetic Analysis for the Elucidation of Complex Reaction Mechanisms: A New Method for the Identification of Rate-Limiting Steps

Two complex cure mechanisms were simulated. Isoconversional kinetic analysis was applied to the resulting data. The study highlighted correlations between the reaction rate, activation energy dependency, rate constants for the chemically controlled part of the reaction and the diffusion-controlled p...

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Bibliographic Details
Published in:	Molecules (Basel, Switzerland) Vol. 24; no. 9; pp. 1683 - 1699
Main Author:	Sbirrazzuoli, Nicolas
Format:	Journal Article
Language:	English
Published:	Switzerland MDPI AG 30.04.2019 MDPI
Series:	Special Issue “Thermal Analysis Kinetics for Understanding Materials Behavior”
Subjects:	Chemical Sciences curing DSC Energy epoxy Heat isoconversional methods kinetic analysis Kinetics Material chemistry Mathematical functions Methods Molecular weight Polymerization polymerization mechanisms Software thermoanalytical techniques Viscosity isoconversional methods DSC epoxy kinetic analysis curing polymerization mechanisms thermoanalytical techniques
ISSN:	1420-3049, 1420-3049
Online Access:	Get full text
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