Synthesis, characterization and C-H amination reactivity of nickel iminyl complexes

Metalation of the deprotonated dipyrrin ( AdF L)Li with NiCl 2 (py) 2 afforded the divalent Ni product ( AdF L)NiCl(py) 2 ( 1 ) ( AdF L: 1,9-di(1-adamantyl)-5-perfluorophenyldipyrrin; py: pyridine). To generate a reactive synthon on which to explore oxidative group transfer, we used potassium graphi...

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Bibliographic Details
Published in:	Chemical science (Cambridge) Vol. 11; no. 5; pp. 126 - 1268
Main Authors:	Dong, Yuyang, Lukens, James T, Clarke, Ryan M, Zheng, Shao-Liang, Lancaster, Kyle M, Betley, Theodore A
Format:	Journal Article
Language:	English
Published:	CAMBRIDGE Royal Soc Chemistry 05.02.2020 Royal Society of Chemistry Royal Society of Chemistry (RSC) The Royal Society of Chemistry
Subjects:	Adducts Benzene Chemistry Chemistry, Multidisciplinary Coordination compounds Crystallography Electronic structure Energy absorption Hydrocarbons Magnetic measurement Nickel NMR Nuclear magnetic resonance Organic compounds Physical Sciences Room temperature Science & Technology Single crystals Spectrum analysis Substrates Toluene X ray absorption X-ray spectroscopy IMIDO COMPLEXES C(SP)-H BONDS HYDROGEN-ATOM ABSTRACTION BOND AMINATION RADICAL AMINATION SPECIES RELEVANT IRON ABSORPTION NI(III)-IMIDE CO(II)-BASED METALLORADICAL CATALYSIS
ISSN:	2041-6520, 2041-6539
Online Access:	Get full text
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