Biomass to olefins: Cracking of renewable naphtha

► Steam cracking of renewable naphtha was studied in a pilot plant. ► The naphtha was derived from waste fats and greases by catalytic hydrotreatment. ► The pilot plant experiments show that high light olefin yields can be obtained. ► Based on an experimental coking study, high run lengths can be ex...

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Vydáno v:Chemical engineering journal (Lausanne, Switzerland : 1996) Ročník 176; s. 178 - 187
Hlavní autoři: Pyl, Steven P., Schietekat, Carl M., Reyniers, Marie-Françoise, Abhari, Ramin, Marin, Guy. B., Van Geem, Kevin M.
Médium: Journal Article
Jazyk:angličtina
Vydáno: Elsevier B.V 01.12.2011
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ISSN:1385-8947, 1873-3212
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Abstract ► Steam cracking of renewable naphtha was studied in a pilot plant. ► The naphtha was derived from waste fats and greases by catalytic hydrotreatment. ► The pilot plant experiments show that high light olefin yields can be obtained. ► Based on an experimental coking study, high run lengths can be expected. An alternative route for the production of light olefins is proposed starting from low value and waste fats, greases and other renewable fractions. The first step catalytically converts triglycerides and/or fatty acids from bio oils to a high quality paraffinic diesel or jet fuel and renewable naphtha. GC × GC–TOF-MS and GC × GC–FID characterization of the renewable naphtha showed that it mainly consists of n-paraffins (32.6 wt%) and iso-paraffins (60 wt%), with only small amounts of aromatics (0.8 wt%), naphthenics (6.3 wt%) and olefinics (0.3 wt%). No remaining oxygenates are measured, making it a potentially attractive feed for the production of ethylene. Steam cracking of this renewable naphtha in a pilot plant revealed that high light olefin yields can be obtained (ethylene yield of 31 wt% and a propylene yield of 17.5 wt%), while the amount of pyrolysis gasoline (15 wt%) and pyrolysis fuel oil (<1 wt%) produced remains small. An experimental coking study further confirmed the attractive character of this feed. Run length simulations show that higher run lengths can be expected in comparison with the typically used naphtha fractions from fossil resources.
AbstractList An alternative route for the production of light olefins is proposed starting from low value and waste fats, greases and other renewable fractions. The first step catalytically converts triglycerides and/or fatty acids from bio oils to a high quality paraffinic diesel or jet fuel and renewable naphtha. GC x GC-TOF-MS and GC x GC-FID characterization of the renewable naphtha showed that it mainly consists of n-paraffins (32.6 wt%) and iso-paraffins (60 wt%), with only small amounts of aromatics (0.8 wt%), naphthenics (6.3 wt%) and olefinics (0.3 wt%). No remaining oxygenates are measured, making it a potentially attractive feed for the production of ethylene. Steam cracking of this renewable naphtha in a pilot plant revealed that high light olefin yields can be obtained (ethylene yield of 31 wt% and a propylene yield of 17.5 wt%), while the amount of pyrolysis gasoline (15 wt%) and pyrolysis fuel oil (<1 wt%) produced remains small. An experimental coking study further confirmed the attractive character of this feed. Run length simulations show that higher run lengths can be expected in comparison with the typically used naphtha fractions from fossil resources.
An alternative route for the production of light olefins is proposed starting from low value and waste fats, greases and other renewable fractions. The first step catalytically converts triglycerides and/or fatty acids from bio oils to a high quality paraffinic diesel or jet fuel and renewable naphtha. GC×GC–TOF-MS and GC×GC–FID characterization of the renewable naphtha showed that it mainly consists of n-paraffins (32.6wt%) and iso-paraffins (60wt%), with only small amounts of aromatics (0.8wt%), naphthenics (6.3wt%) and olefinics (0.3wt%). No remaining oxygenates are measured, making it a potentially attractive feed for the production of ethylene. Steam cracking of this renewable naphtha in a pilot plant revealed that high light olefin yields can be obtained (ethylene yield of 31wt% and a propylene yield of 17.5wt%), while the amount of pyrolysis gasoline (15wt%) and pyrolysis fuel oil (<1wt%) produced remains small. An experimental coking study further confirmed the attractive character of this feed. Run length simulations show that higher run lengths can be expected in comparison with the typically used naphtha fractions from fossil resources.
► Steam cracking of renewable naphtha was studied in a pilot plant. ► The naphtha was derived from waste fats and greases by catalytic hydrotreatment. ► The pilot plant experiments show that high light olefin yields can be obtained. ► Based on an experimental coking study, high run lengths can be expected. An alternative route for the production of light olefins is proposed starting from low value and waste fats, greases and other renewable fractions. The first step catalytically converts triglycerides and/or fatty acids from bio oils to a high quality paraffinic diesel or jet fuel and renewable naphtha. GC × GC–TOF-MS and GC × GC–FID characterization of the renewable naphtha showed that it mainly consists of n-paraffins (32.6 wt%) and iso-paraffins (60 wt%), with only small amounts of aromatics (0.8 wt%), naphthenics (6.3 wt%) and olefinics (0.3 wt%). No remaining oxygenates are measured, making it a potentially attractive feed for the production of ethylene. Steam cracking of this renewable naphtha in a pilot plant revealed that high light olefin yields can be obtained (ethylene yield of 31 wt% and a propylene yield of 17.5 wt%), while the amount of pyrolysis gasoline (15 wt%) and pyrolysis fuel oil (<1 wt%) produced remains small. An experimental coking study further confirmed the attractive character of this feed. Run length simulations show that higher run lengths can be expected in comparison with the typically used naphtha fractions from fossil resources.
Author Marin, Guy. B.
Van Geem, Kevin M.
Reyniers, Marie-Françoise
Pyl, Steven P.
Schietekat, Carl M.
Abhari, Ramin
Author_xml – sequence: 1
  givenname: Steven P.
  surname: Pyl
  fullname: Pyl, Steven P.
  organization: Laboratory for Chemical Technology, Ghent Univeristy (LCT), Technologiepark 918, B-9052 Gent, Belgium
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  givenname: Carl M.
  surname: Schietekat
  fullname: Schietekat, Carl M.
  organization: Laboratory for Chemical Technology, Ghent Univeristy (LCT), Technologiepark 918, B-9052 Gent, Belgium
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  givenname: Marie-Françoise
  surname: Reyniers
  fullname: Reyniers, Marie-Françoise
  organization: Laboratory for Chemical Technology, Ghent Univeristy (LCT), Technologiepark 918, B-9052 Gent, Belgium
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  givenname: Ramin
  surname: Abhari
  fullname: Abhari, Ramin
  organization: Syntroleum Corporation, Tulsa, OK, USA
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  givenname: Guy. B.
  surname: Marin
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  givenname: Kevin M.
  surname: Van Geem
  fullname: Van Geem, Kevin M.
  email: kevin.vangeem@ugent.be
  organization: Laboratory for Chemical Technology, Ghent Univeristy (LCT), Technologiepark 918, B-9052 Gent, Belgium
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Keywords Biomass conversion
Olefin production
Comprehensive 2D GC
Steam cracking
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Snippet ► Steam cracking of renewable naphtha was studied in a pilot plant. ► The naphtha was derived from waste fats and greases by catalytic hydrotreatment. ► The...
An alternative route for the production of light olefins is proposed starting from low value and waste fats, greases and other renewable fractions. The first...
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StartPage 178
SubjectTerms aromatic compounds
Biomass
Biomass conversion
chemical engineering
Comprehensive 2D GC
cracking
Ethylene
ethylene production
Fats
fatty acids
Fossils
Fracture mechanics
fuel oils
gasoline
Naphtha
olefin
Olefin production
Olefins
propylene
Pyrolysis
steam
Steam cracking
triacylglycerols
Title Biomass to olefins: Cracking of renewable naphtha
URI https://dx.doi.org/10.1016/j.cej.2011.04.062
https://www.proquest.com/docview/1663598797
https://www.proquest.com/docview/1777127750
https://www.proquest.com/docview/918057254
Volume 176
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