A Mononuclear Uranium(IV) Single-Molecule Magnet with an Azobenzene Radical Ligand

A tetravalent uranium compound with a radical azobenzene ligand, namely, [{(SiMe2NPh)3‐tacn}UIV(η2‐N2Ph2.)] (2), was obtained by one‐electron reduction of azobenzene by the trivalent uranium compound [UIII{(SiMe2NPh)3‐tacn}] (1). Compound 2 was characterized by single‐crystal X‐ray diffraction and 1...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 21; no. 49; pp. 17817 - 17826
Main Authors:	Antunes, Maria A., Coutinho, Joana T., Santos, Isabel C., Marçalo, Joaquim, Almeida, Manuel, Baldoví, José J., Pereira, Laura C. J., Gaita-Ariño, Alejandro, Coronado, Eugenio
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 01.12.2015 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Subjects:	azo compounds Chemistry Diffraction Electrostatics Ligands Low temperature Magnetic properties Magnetization N ligands Radicals Reduction Spectrum analysis Uranium Uranium compounds X-ray diffraction N ligands magnetic properties uranium radicals azo compounds
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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