Impact of an SRA (hexylene glycol) on irreversible drying shrinkage and pore solution properties of cement pastes
Cementitious materials shrink when exposed to decreasing relative humidities, which may result in cracking. Shrinkage reducing admixtures (SRAs) can be used to reduce this drying shrinkage. Although many studies have shown that SRAs reduce the surface tension of the pore solution, the effects of SRA...
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| Published in: | Cement and concrete research Vol. 143; p. 106227 |
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| Format: | Journal Article |
| Language: | English |
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Elmsford
Elsevier Ltd
01.05.2021
Elsevier BV Elsevier |
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| ISSN: | 0008-8846, 1873-3948 |
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| Abstract | Cementitious materials shrink when exposed to decreasing relative humidities, which may result in cracking. Shrinkage reducing admixtures (SRAs) can be used to reduce this drying shrinkage. Although many studies have shown that SRAs reduce the surface tension of the pore solution, the effects of SRAs on other pore solution properties and their relationship to drying shrinkage have been poorly characterized. In this work, we investigate the impact of an SRA (hexylene glycol) on the drying and re-humidification of a cement paste over an extended relative humidity range. The reduction in the first drying shrinkage by the SRA depends on relative humidity. The SRA also significantly reduces the irreversible drying shrinkage. We concluded that the SRA impacts drying shrinkage by acting on the capillary forces, by acting on the specific range of relative humidity over which those forces occur, and potentially by acting on the surface stresses through pore wall adsorption.
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| AbstractList | Cementitious materials shrink when exposed to decreasing relative humidities, which may result in cracking. Shrinkage reducing admixtures (SRAs) can be used to reduce this drying shrinkage. Although many studies have shown that SRAs reduce the surface tension of the pore solution, the effects of SRAs on other pore solution properties and their relationship to drying shrinkage have been poorly characterized. In this work, we investigate the impact of an SRA (hexylene glycol) on the drying and re-humidification of a cement paste over an extended relative humidity range. The reduction in the first drying shrinkage by the SRA depends on relative humidity. The SRA also significantly reduces the irreversible drying shrinkage. We concluded that the SRA impacts drying shrinkage by acting on the capillary forces, by acting on the specific range of relative humidity over which those forces occur, and potentially by acting on the surface stresses through pore wall adsorption. Cementitious materials shrink when exposed to decreasing relative humidities, which may result in cracking. Shrinkage reducing admixtures (SRAs) can be used to reduce this drying shrinkage. Although many studies have shown that SRAs reduce the surface tension of the pore solution, the effects of SRAs on other pore solution properties and their relationship to drying shrinkage have been poorly characterized. In this work, we investigate the impact of an SRA (hexylene glycol) on the drying and re-humidification of a cement paste over an extended relative humidity range. The reduction in the first drying shrinkage by the SRA depends on relative humidity. The SRA also significantly reduces the irreversible drying shrinkage. We concluded that the SRA impacts drying shrinkage by acting on the capillary forces, by acting on the specific range of relative humidity over which those forces occur, and potentially by acting on the surface stresses through pore wall adsorption. [Display omitted] |
| ArticleNumber | 106227 |
| Author | Rahoui, Hafsa Vandamme, Matthieu Pereira, Jean-Michel Maruyama, Ippei Mosquet, Martin |
| Author_xml | – sequence: 1 givenname: Hafsa surname: Rahoui fullname: Rahoui, Hafsa organization: Laboratoire Navier, Ecole des Ponts ParisTech, Univ Gustave Eiffel, CNRS, Marne-la-Vallée, France – sequence: 2 givenname: Ippei surname: Maruyama fullname: Maruyama, Ippei email: i.maruyama@nagoya-u.jp organization: Graduate School of Environmental Studies, Nagoya University, Nagoya, Japan – sequence: 3 givenname: Matthieu surname: Vandamme fullname: Vandamme, Matthieu organization: Laboratoire Navier, Ecole des Ponts ParisTech, Univ Gustave Eiffel, CNRS, Marne-la-Vallée, France – sequence: 4 givenname: Jean-Michel surname: Pereira fullname: Pereira, Jean-Michel organization: Laboratoire Navier, Ecole des Ponts ParisTech, Univ Gustave Eiffel, CNRS, Marne-la-Vallée, France – sequence: 5 givenname: Martin surname: Mosquet fullname: Mosquet, Martin organization: LafargeHolcim Innovation Center, Saint-Quentin Fallavier 38291, France |
| BackLink | https://hal.science/hal-03164493$$DView record in HAL https://www.osti.gov/biblio/23206321$$D View this record in Osti.gov |
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| Keywords | Mass change isotherms First drying shrinkage SRA mass change isotherms |
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| SubjectTerms | Admixtures ADSORPTION Cement Cement paste CEMENTS Civil Engineering CRACKING Drying Engineering Sciences First drying shrinkage GLYCOLS Humidification HUMIDITY ISOTHERMS Manufactured products Mass change isotherms Materials MATERIALS SCIENCE Relative humidity SHRINKAGE SRA STRESSES SURFACE TENSION SURFACES Temperature |
| Title | Impact of an SRA (hexylene glycol) on irreversible drying shrinkage and pore solution properties of cement pastes |
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