Surfactant dynamics: hidden variables controlling fluid flows

Surfactants – molecules and particles that preferentially adsorb to fluid interfaces – play a ubiquitous role in the fluids of industry, of nature and of life. Since most surfactants cannot be seen directly, their behaviour must be inferred from their impact on observed flows, like the buoyant rise...

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Veröffentlicht in:Journal of fluid mechanics Jg. 892
Hauptverfasser: Manikantan, Harishankar, Squires, Todd M.
Format: Journal Article
Sprache:Englisch
Veröffentlicht: Cambridge, UK Cambridge University Press 10.06.2020
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ISSN:0022-1120, 1469-7645
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Abstract Surfactants – molecules and particles that preferentially adsorb to fluid interfaces – play a ubiquitous role in the fluids of industry, of nature and of life. Since most surfactants cannot be seen directly, their behaviour must be inferred from their impact on observed flows, like the buoyant rise of a bubble, or the thickness of a coating film. In so doing, however, a difficulty arises: physically distinct surfactant processes can affect measurable flows in qualitatively identical ways, raising the spectre of confusion or even misinterpretation. This Perspective describes, in one coherent piece, both the equilibrium properties and dynamic processes of surfactants, to better enable the fluid mechanics community to understand, interpret and design surfactant/fluid systems. Specifically, we treat the equilibrium thermodynamics of surfactants at interfaces, including surface pressure, isotherms of soluble and insoluble surfactants and surface dilatational moduli (Gibbs and Marangoni). We describe surfactant dynamics in fluid systems, including surfactant transport and interfacial stress boundary conditions, the competition between surface diffusion, advection and adsorption/desorption, Marangoni stresses and flows and surface-excess rheology. We discuss paradigmatic problems from fluid mechanics that are impacted by surfactants, including translating drops and bubbles, surfactant adsorption to clean and oscillating interfaces; capillary wave damping, thin-film dynamics, foam drainage and the dynamics of particles and probes at surfactant-laden interfaces. Finally, we discuss the additional richness and complexity that frequently arise in ‘real’ surfactants, including phase transitions, phase coexistence and polycrystalline phases within surfactant monolayers, and their impact on non-Newtonian surface rheology.
AbstractList Surfactants – molecules and particles that preferentially adsorb to fluid interfaces – play a ubiquitous role in the fluids of industry, of nature, and of life. Since most surfactants cannot be seen directly, their behavior must be inferred from their impact on observed flows, like the buoyant rise of a bubble, or the thickness of a coating film. In so doing, however, a difficulty arises: physically distinct surfactant processes can affect measurable flows in qualitatively identical ways, raising the specter of confusion or even misinterpretation. This Perspective describes, in one coherent piece, both the equilibrium properties and dynamic processes of surfactants, to better enable the fluid mechanics community to understand, interpret, and design surfactant/fluid systems. Specifically, §2 treats the equilibrium thermodynamics of surfactants at interfaces, including surface pressure, isotherms of soluble and insoluble surfactants, and surface dilatational moduli (Gibbs and Marangoni). §3 describes surfactant dynamics in fluid systems, including surfactant transport and interfacial stress boundary conditions, the competition between surface diffusion, advection, and adsorption/desorption, Marangoni stresses and flows, and surface excess rheology. §4 discusses paradigmatic problems from fluid mechanics that are impacted by surfactants, including translating drops and bubbles, surfactant adsorption to clean and oscillating interfaces; capillary wave damping, thin film dynamics, foam drainage, and the dynamics of particles and probes at surfactant-laden interfaces. Finally, §5 discusses the additional richness and complexity that frequently arise in ‘real’ surfactants, including phase transitions, phase coexistence, and polycrystalline phases within surfactant monolayers, and their impact on non-Newtonian surface rheology.
Surfactants - molecules and particles that preferentially adsorb to fluid interfaces - play a ubiquitous role in the fluids of industry, of nature, and of life. Since most surfactants cannot be seen directly, their behavior must be inferred from their impact on observed flows, like the buoyant rise of a bubble, or the thickness of a coating film. In so doing, however, a difficulty arises: physically distinct surfactant processes can affect measurable flows in qualitatively identical ways, raising the specter of confusion or even misinterpretation. This Perspective describes, in one coherent piece, both the equilibrium properties and dynamic processes of surfactants, to better enable the fluid mechanics community to understand, interpret, and design surfactant/fluid systems. Specifically, §2 treats the equilibrium thermodynamics of surfactants at interfaces, including surface pressure, isotherms of soluble and insoluble surfactants, and surface dilatational moduli (Gibbs and Marangoni). §3 describes surfactant dynamics in fluid systems, including surfactant transport and interfacial stress boundary conditions, the competition between surface diffusion, advection, and adsorption/desorption, Marangoni stresses and flows, and surface excess rheology. §4 discusses paradigmatic problems from fluid mechanics that are impacted by surfactants, including translating drops and bubbles, surfactant adsorption to clean and oscillating interfaces; capillary wave damping, thin film dynamics, foam drainage, and the dynamics of particles and probes at surfactant-laden interfaces. Finally, §5 discusses the additional richness and complexity that frequently arise in 'real' surfactants, including phase transitions, phase coexistence, and polycrystalline phases within surfactant monolayers, and their impact on non-Newtonian surface rheology.Surfactants - molecules and particles that preferentially adsorb to fluid interfaces - play a ubiquitous role in the fluids of industry, of nature, and of life. Since most surfactants cannot be seen directly, their behavior must be inferred from their impact on observed flows, like the buoyant rise of a bubble, or the thickness of a coating film. In so doing, however, a difficulty arises: physically distinct surfactant processes can affect measurable flows in qualitatively identical ways, raising the specter of confusion or even misinterpretation. This Perspective describes, in one coherent piece, both the equilibrium properties and dynamic processes of surfactants, to better enable the fluid mechanics community to understand, interpret, and design surfactant/fluid systems. Specifically, §2 treats the equilibrium thermodynamics of surfactants at interfaces, including surface pressure, isotherms of soluble and insoluble surfactants, and surface dilatational moduli (Gibbs and Marangoni). §3 describes surfactant dynamics in fluid systems, including surfactant transport and interfacial stress boundary conditions, the competition between surface diffusion, advection, and adsorption/desorption, Marangoni stresses and flows, and surface excess rheology. §4 discusses paradigmatic problems from fluid mechanics that are impacted by surfactants, including translating drops and bubbles, surfactant adsorption to clean and oscillating interfaces; capillary wave damping, thin film dynamics, foam drainage, and the dynamics of particles and probes at surfactant-laden interfaces. Finally, §5 discusses the additional richness and complexity that frequently arise in 'real' surfactants, including phase transitions, phase coexistence, and polycrystalline phases within surfactant monolayers, and their impact on non-Newtonian surface rheology.
Surfactants – molecules and particles that preferentially adsorb to fluid interfaces – play a ubiquitous role in the fluids of industry, of nature and of life. Since most surfactants cannot be seen directly, their behaviour must be inferred from their impact on observed flows, like the buoyant rise of a bubble, or the thickness of a coating film. In so doing, however, a difficulty arises: physically distinct surfactant processes can affect measurable flows in qualitatively identical ways, raising the spectre of confusion or even misinterpretation. This Perspective describes, in one coherent piece, both the equilibrium properties and dynamic processes of surfactants, to better enable the fluid mechanics community to understand, interpret and design surfactant/fluid systems. Specifically, we treat the equilibrium thermodynamics of surfactants at interfaces, including surface pressure, isotherms of soluble and insoluble surfactants and surface dilatational moduli (Gibbs and Marangoni). We describe surfactant dynamics in fluid systems, including surfactant transport and interfacial stress boundary conditions, the competition between surface diffusion, advection and adsorption/desorption, Marangoni stresses and flows and surface-excess rheology. We discuss paradigmatic problems from fluid mechanics that are impacted by surfactants, including translating drops and bubbles, surfactant adsorption to clean and oscillating interfaces; capillary wave damping, thin-film dynamics, foam drainage and the dynamics of particles and probes at surfactant-laden interfaces. Finally, we discuss the additional richness and complexity that frequently arise in ‘real’ surfactants, including phase transitions, phase coexistence and polycrystalline phases within surfactant monolayers, and their impact on non-Newtonian surface rheology.
ArticleNumber P1
Author Squires, Todd M.
Manikantan, Harishankar
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Keywords complex fluids
non-Newtonian flows
interfacial flows (free surface)
Language English
License http://creativecommons.org/licenses/by/4.0/ This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
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current address: Department of Chemical Engineering, University of California, Davis, CA 95616, USA.
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PublicationTitle Journal of fluid mechanics
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Snippet Surfactants – molecules and particles that preferentially adsorb to fluid interfaces – play a ubiquitous role in the fluids of industry, of nature and of life....
Surfactants - molecules and particles that preferentially adsorb to fluid interfaces - play a ubiquitous role in the fluids of industry, of nature, and of...
Surfactants – molecules and particles that preferentially adsorb to fluid interfaces – play a ubiquitous role in the fluids of industry, of nature, and of...
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SubjectTerms Adsorption
Aquatic reptiles
Boundary conditions
Bubbles
Capillary waves
Coexistence
Damping
Experiments
Fluid dynamics
Fluid flow
Fluid mechanics
Fluids
Influence
Interfaces
Interfacial stresses
JFM Perspectives
Monomolecular films
Phase transitions
Pressure
Rheological properties
Rheology
Surface chemistry
Surface diffusion
Surfactants
Thermodynamic equilibrium
Thickness
Thin films
Velocity
Wave damping
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Title Surfactant dynamics: hidden variables controlling fluid flows
URI https://www.cambridge.org/core/product/identifier/S0022112020001706/type/journal_article
https://www.ncbi.nlm.nih.gov/pubmed/33776139
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https://pubmed.ncbi.nlm.nih.gov/PMC7995737
Volume 892
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