Palladium Catalysts on Alkaline-Earth Supports for Racemization and Dynamic Kinetic Resolution of Benzylic Amines

Palladium catalysts on alkaline‐earth supports were studied as new heterogeneous catalysts for racemization of chiral benzylic amines such as 1‐phenylethylamine. Particularly 5 % Pd/BaSO4 and 5 % Pd/CaCO3 were able to selectively racemize amines, with minimal formation of secondary amines or hydroge...

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Bibliographic Details

Published in:	Chemistry : a European journal Vol. 13; no. 7; pp. 2034 - 2043
Main Authors:	Parvulescu, Andrei N., Jacobs, Pierre A., De Vos, Dirk E.
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 01.01.2007 WILEY‐VCH Verlag
Subjects:	amides amines Amines - chemistry Catalysis Chemistry - methods heterogeneous catalysis kinetic resolution Kinetics Metals, Alkaline Earth - chemistry palladium Palladium - chemistry Stereoisomerism
ISSN:	0947-6539, 1521-3765
Online Access:	Get full text
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