Palladium Catalysts on Alkaline-Earth Supports for Racemization and Dynamic Kinetic Resolution of Benzylic Amines

Palladium catalysts on alkaline‐earth supports were studied as new heterogeneous catalysts for racemization of chiral benzylic amines such as 1‐phenylethylamine. Particularly 5 % Pd/BaSO4 and 5 % Pd/CaCO3 were able to selectively racemize amines, with minimal formation of secondary amines or hydroge...

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Vydané v:	Chemistry : a European journal Ročník 13; číslo 7; s. 2034 - 2043
Hlavní autori:	Parvulescu, Andrei N., Jacobs, Pierre A., De Vos, Dirk E.
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	Weinheim WILEY-VCH Verlag 01.01.2007 WILEY‐VCH Verlag
Predmet:	amides amines Amines - chemistry Catalysis Chemistry - methods heterogeneous catalysis kinetic resolution Kinetics Metals, Alkaline Earth - chemistry palladium Palladium - chemistry Stereoisomerism
ISSN:	0947-6539, 1521-3765
On-line prístup:	Získať plný text
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