Direct spectroscopic characterization of a transitory dirhodium donor-acceptor carbene complex

A multitude of organic transformations catalyzed by dirhodium(II) (Rh2) complexes are thought to proceed via the intermediacy of highly reactive, electrophilic carbenoid intermediates that have eluded direct observation. Herein, we report the generation of a metastable Rh2-carbenoid intermediate sup...

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Bibliographic Details

Published in:	Science (American Association for the Advancement of Science) Vol. 342; no. 6156; p. 351
Main Authors:	Kornecki, Katherine P, Briones, John F, Boyarskikh, Vyacheslav, Fullilove, Felicia, Autschbach, Jochen, Schrote, Kaitlin E, Lancaster, Kyle M, Davies, Huw M L, Berry, John F
Format:	Journal Article
Language:	English
Published:	United States 18.10.2013
ISSN:	1095-9203, 1095-9203
Online Access:	Get more information
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