Volcano plots in hydrogen electrocatalysis – uses and abuses

Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-cov...

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Veröffentlicht in:	Beilstein journal of nanotechnology Jg. 5; H. 1; S. 846 - 854
Hauptverfasser:	Quaino, Paola, Juarez, Fernanda, Santos, Elizabeth, Schmickler, Wolfgang
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	Germany Beilstein-Institut 13.06.2014
Schlagworte:	electrocatalysis Full Research Paper hydrogen evolution Nanoscience Nanotechnology Sabatier’s principle volcano curve hydrogen evolution volcano curve electrocatalysis Sabatier’s principle
ISSN:	2190-4286, 2190-4286
Online-Zugang:	Volltext
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