Volcano plots in hydrogen electrocatalysis – uses and abuses

Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-cov...

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Bibliographic Details
Published in:Beilstein journal of nanotechnology Vol. 5; no. 1; pp. 846 - 854
Main Authors: Quaino, Paola, Juarez, Fernanda, Santos, Elizabeth, Schmickler, Wolfgang
Format: Journal Article
Language:English
Published: Germany Beilstein-Institut 13.06.2014
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ISSN:2190-4286, 2190-4286
Online Access:Get full text
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