Volcano plots in hydrogen electrocatalysis – uses and abuses
Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-cov...
Uložené v:
| Vydané v: | Beilstein journal of nanotechnology Ročník 5; číslo 1; s. 846 - 854 |
|---|---|
| Hlavní autori: | , , , |
| Médium: | Journal Article |
| Jazyk: | English |
| Vydavateľské údaje: |
Germany
Beilstein-Institut
13.06.2014
|
| Predmet: | |
| ISSN: | 2190-4286, 2190-4286 |
| On-line prístup: | Získať plný text |
| Tagy: |
Pridať tag
Žiadne tagy, Buďte prvý, kto otaguje tento záznam!
|
| Abstract | Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-covered metals are left out. We examine the factors that govern the reaction rate in the light of our own theory and conclude, that Sabatier’s principle is only one of several factors that determine the rate. With the exception of nickel and cobalt, the reaction rate does not decrease for highly exothermic hydrogen adsorption as predicted, because the reaction passes through more suitable intermediate states. The case of nickel is given special attention; since it is a 3d metal, its orbitals are compact and the overlap with hydrogen is too low to make it a good catalyst. |
|---|---|
| AbstractList | Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-covered metals are left out. We examine the factors that govern the reaction rate in the light of our own theory and conclude, that Sabatier’s principle is only one of several factors that determine the rate. With the exception of nickel and cobalt, the reaction rate does not decrease for highly exothermic hydrogen adsorption as predicted, because the reaction passes through more suitable intermediate states. The case of nickel is given special attention; since it is a 3d metal, its orbitals are compact and the overlap with hydrogen is too low to make it a good catalyst. Sabatier's principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-covered metals are left out. We examine the factors that govern the reaction rate in the light of our own theory and conclude, that Sabatier's principle is only one of several factors that determine the rate. With the exception of nickel and cobalt, the reaction rate does not decrease for highly exothermic hydrogen adsorption as predicted, because the reaction passes through more suitable intermediate states. The case of nickel is given special attention; since it is a 3d metal, its orbitals are compact and the overlap with hydrogen is too low to make it a good catalyst.Sabatier's principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-covered metals are left out. We examine the factors that govern the reaction rate in the light of our own theory and conclude, that Sabatier's principle is only one of several factors that determine the rate. With the exception of nickel and cobalt, the reaction rate does not decrease for highly exothermic hydrogen adsorption as predicted, because the reaction passes through more suitable intermediate states. The case of nickel is given special attention; since it is a 3d metal, its orbitals are compact and the overlap with hydrogen is too low to make it a good catalyst. |
| Author | Santos, Elizabeth Juarez, Fernanda Quaino, Paola Schmickler, Wolfgang |
| AuthorAffiliation | 2 Institute of Theoretical Chemistry, Ulm University, D-89069 Ulm, Germany 1 PRELINE, Universidad Nacional del Litoral, Santa Fe, Argentina 3 Faculdad de Matemática, Astronomía y Física, IFEG-CONICET, Universidad Nacional de Córdoba, Córdoba, Argentina |
| AuthorAffiliation_xml | – name: 1 PRELINE, Universidad Nacional del Litoral, Santa Fe, Argentina – name: 3 Faculdad de Matemática, Astronomía y Física, IFEG-CONICET, Universidad Nacional de Córdoba, Córdoba, Argentina – name: 2 Institute of Theoretical Chemistry, Ulm University, D-89069 Ulm, Germany |
| Author_xml | – sequence: 1 givenname: Paola surname: Quaino fullname: Quaino, Paola – sequence: 2 givenname: Fernanda surname: Juarez fullname: Juarez, Fernanda – sequence: 3 givenname: Elizabeth surname: Santos fullname: Santos, Elizabeth – sequence: 4 givenname: Wolfgang surname: Schmickler fullname: Schmickler, Wolfgang |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/24991521$$D View this record in MEDLINE/PubMed |
| BookMark | eNptkctqWzEQhkVJadI0q-7LWRaKXd0vm0AJbRMIZJN0K3SkOY6MLLnSccC7vkPfsE_S4zoJSehsZpj555uB_y06yCUDQu8JnjMl6ed-mV0uczE38hU6osTgGadaHjypD9FJa0s8BcdUG_0GHVJuDBGUHKHTHyX5idCtUxlbF3N3uw21LCB3kMCPtXg3urRtsXV_fv3uNg1a53LoXL8r36HXg0sNTu7zMbr59vX67Hx2efX94uzL5cwLwsaZlgwgaOOCCIJI3jPQdDDeEy-9DpgRHASXpDcsTB3aAx1Y4FwLplQAw47RxZ4bilvadY0rV7e2uGj_NUpdWFfH6BPYQSsNMEhBBsenbaO0ICKoIJ3uGZUT63TPWm_6FQQPeawuPYM-n-R4axflznKsFMdiAny8B9TycwNttKvYPKTkMpRNs0RwRpWRVE3SD09vPR55MGASfNoLfC2tVRgeJQTbncN277AV1uxeJy_UPo5ujGX3aEz_3fkLFSqsJw |
| CitedBy_id | crossref_primary_10_1002_celc_202100307 crossref_primary_10_1016_j_jelechem_2016_09_051 crossref_primary_10_1016_j_apsusc_2021_152197 crossref_primary_10_1002_ppsc_201800186 crossref_primary_10_1007_s11003_019_00291_2 crossref_primary_10_1016_j_ijhydene_2017_09_038 crossref_primary_10_1021_acsenergylett_5c00439 crossref_primary_10_1002_anie_202307907 crossref_primary_10_1016_j_ijhydene_2015_03_083 crossref_primary_10_1016_j_electacta_2021_139413 crossref_primary_10_1007_s12678_017_0365_y crossref_primary_10_1016_j_jcat_2024_115872 crossref_primary_10_1016_j_ijhydene_2020_04_111 crossref_primary_10_1002_cphc_202000529 crossref_primary_10_1016_j_cattod_2024_115051 crossref_primary_10_1002_adma_202405029 crossref_primary_10_1002_celc_202001230 crossref_primary_10_1038_srep10589 crossref_primary_10_1016_j_electacta_2019_135555 crossref_primary_10_1021_acs_jpcc_5c02508 crossref_primary_10_1002_aesr_202400169 crossref_primary_10_1002_ange_202414346 crossref_primary_10_1021_jacs_5b07779 crossref_primary_10_1063_5_0101372 crossref_primary_10_1002_adsu_202500483 crossref_primary_10_3390_catal10111267 crossref_primary_10_1016_j_nanoen_2020_105270 crossref_primary_10_1002_anie_202111026 crossref_primary_10_1016_j_cattod_2022_05_031 crossref_primary_10_1016_j_ceramint_2021_06_093 crossref_primary_10_1016_j_electacta_2017_09_127 crossref_primary_10_1246_bcsj_20160165 crossref_primary_10_1016_j_ijhydene_2020_05_163 crossref_primary_10_1007_s40843_022_2379_8 crossref_primary_10_1016_j_jiec_2018_02_029 crossref_primary_10_1186_s40580_024_00467_w crossref_primary_10_1016_j_apsusc_2018_11_233 crossref_primary_10_1007_s12678_022_00742_6 crossref_primary_10_1016_j_envres_2022_113731 crossref_primary_10_1016_j_electacta_2017_11_069 crossref_primary_10_1002_cctc_201901183 crossref_primary_10_1016_j_ijhydene_2023_10_210 crossref_primary_10_1016_j_ijhydene_2024_01_135 crossref_primary_10_1016_j_jphotochem_2020_112462 crossref_primary_10_1002_cssc_202400873 crossref_primary_10_1016_j_fuel_2025_135227 crossref_primary_10_1016_j_jiec_2021_01_008 crossref_primary_10_1016_j_cej_2025_164204 crossref_primary_10_1002_pssr_202100657 crossref_primary_10_1016_j_electacta_2024_144953 crossref_primary_10_1016_j_jcis_2025_138452 crossref_primary_10_1002_advs_202207644 crossref_primary_10_1016_j_est_2024_113545 crossref_primary_10_1016_j_jallcom_2022_165352 crossref_primary_10_1016_j_jelechem_2018_10_047 crossref_primary_10_1016_j_ijhydene_2022_10_169 crossref_primary_10_1002_advs_202309635 crossref_primary_10_1111_jace_19274 crossref_primary_10_1016_j_electacta_2021_138583 crossref_primary_10_1016_j_ijhydene_2017_12_112 crossref_primary_10_1002_elsa_202100213 crossref_primary_10_1007_s12678_020_00588_w crossref_primary_10_1002_slct_201700103 crossref_primary_10_1016_j_seppur_2017_08_023 crossref_primary_10_1021_jacs_4c10246 crossref_primary_10_1002_adsu_202500142 crossref_primary_10_1007_s10562_025_05055_z crossref_primary_10_1002_adfm_202106715 crossref_primary_10_1103_PRXEnergy_3_043008 crossref_primary_10_1016_j_ijhydene_2022_05_145 crossref_primary_10_1038_s41570_021_00268_3 crossref_primary_10_1002_celc_201900834 crossref_primary_10_1007_s10008_020_04735_7 crossref_primary_10_1002_asia_202401055 crossref_primary_10_1016_j_jcis_2020_07_122 crossref_primary_10_1016_j_jpowsour_2018_07_040 crossref_primary_10_1016_j_jcat_2024_115725 crossref_primary_10_1016_j_electacta_2021_139783 crossref_primary_10_1016_j_ijhydene_2024_08_240 crossref_primary_10_1016_j_nanoen_2022_107231 crossref_primary_10_1016_j_jelechem_2022_116799 crossref_primary_10_1002_aenm_202100417 crossref_primary_10_1021_jacs_4c18638 crossref_primary_10_1016_j_ijhydene_2024_05_236 crossref_primary_10_1016_j_jpowsour_2025_238146 crossref_primary_10_1002_cssc_202200027 crossref_primary_10_1002_adfm_201803291 crossref_primary_10_1016_j_ijhydene_2022_03_065 crossref_primary_10_1016_j_cej_2025_164789 crossref_primary_10_1016_j_surfin_2024_104533 crossref_primary_10_1002_anie_202003688 crossref_primary_10_1002_anie_202005745 crossref_primary_10_1002_celc_202101278 crossref_primary_10_1016_j_cherd_2023_05_004 crossref_primary_10_1016_j_ijhydene_2020_05_196 crossref_primary_10_1016_j_ijhydene_2021_11_068 crossref_primary_10_1016_j_jechem_2023_12_048 crossref_primary_10_1016_j_cej_2022_137045 crossref_primary_10_1016_j_jpowsour_2021_229708 crossref_primary_10_1016_j_joule_2017_06_001 crossref_primary_10_3390_catal11111283 crossref_primary_10_1002_aenm_201601735 crossref_primary_10_1007_s11144_014_0808_x crossref_primary_10_1021_jacs_3c07312 crossref_primary_10_1038_s41929_022_00791_6 crossref_primary_10_1002_cssc_202400444 crossref_primary_10_1016_j_ccr_2021_214264 crossref_primary_10_1016_j_electacta_2024_143794 crossref_primary_10_3390_catal13010089 crossref_primary_10_1002_advs_201700464 crossref_primary_10_1007_s10971_023_06058_1 crossref_primary_10_1016_j_electacta_2024_145174 crossref_primary_10_1038_ncomms12272 crossref_primary_10_1016_j_elecom_2020_106871 crossref_primary_10_1021_jacs_7b02879 crossref_primary_10_1007_s11581_019_02933_6 crossref_primary_10_1016_j_jelechem_2021_115150 crossref_primary_10_1016_j_jelechem_2024_118151 crossref_primary_10_1039_D0SC00754D crossref_primary_10_1016_j_electacta_2023_143335 crossref_primary_10_1088_2515_7655_adad9f crossref_primary_10_1039_C6CC03969C crossref_primary_10_1002_smll_202301986 crossref_primary_10_1016_j_ijhydene_2020_10_030 crossref_primary_10_1016_j_fuel_2025_135153 crossref_primary_10_1002_cnma_201900536 crossref_primary_10_1039_D0RE00330A crossref_primary_10_1016_j_jechem_2022_09_022 crossref_primary_10_3390_nano13152176 crossref_primary_10_1002_anie_202414346 crossref_primary_10_1016_j_apsusc_2019_144571 crossref_primary_10_1002_elan_201600270 crossref_primary_10_1016_j_rser_2022_112323 crossref_primary_10_1002_er_7380 crossref_primary_10_1016_j_elecom_2016_10_014 crossref_primary_10_1038_s41467_022_33512_5 crossref_primary_10_1016_j_apsusc_2020_145516 crossref_primary_10_1016_j_elecom_2016_10_013 crossref_primary_10_3390_nano15090664 crossref_primary_10_1016_j_mtener_2023_101364 crossref_primary_10_1007_s12678_017_0381_y crossref_primary_10_1016_j_jechem_2018_02_005 crossref_primary_10_1016_j_ijhydene_2021_01_041 crossref_primary_10_1002_ange_202003688 crossref_primary_10_1002_ange_202005745 crossref_primary_10_1007_s12678_019_00546_1 crossref_primary_10_1016_j_corsci_2016_07_017 crossref_primary_10_1039_D0SE00634C crossref_primary_10_1038_s41560_025_01754_4 crossref_primary_10_1016_j_scriptamat_2025_116941 crossref_primary_10_1016_j_electacta_2018_07_063 crossref_primary_10_1039_D1EE02512K crossref_primary_10_1002_adma_201805606 crossref_primary_10_1002_adfm_202005060 crossref_primary_10_1016_j_jcis_2024_08_084 crossref_primary_10_1016_j_ccr_2023_215058 crossref_primary_10_1016_j_jmst_2023_04_073 crossref_primary_10_3762_bjnano_6_103 crossref_primary_10_1039_D1SE01347E crossref_primary_10_3390_catal10030290 crossref_primary_10_1002_ange_202111026 crossref_primary_10_1016_j_coelec_2018_04_006 crossref_primary_10_1002_advs_202104908 crossref_primary_10_1007_s10008_019_04374_7 crossref_primary_10_3390_catal13101373 crossref_primary_10_1016_j_ijhydene_2020_12_200 crossref_primary_10_1016_j_jallcom_2020_156651 crossref_primary_10_1039_C5CP04238K crossref_primary_10_1016_j_nanoen_2021_106046 crossref_primary_10_1016_j_apsusc_2023_156857 crossref_primary_10_1557_s43578_022_00497_2 crossref_primary_10_1038_nmat4738 crossref_primary_10_1016_j_apsusc_2023_157248 crossref_primary_10_1039_D0SC06139E crossref_primary_10_1002_cey2_27 crossref_primary_10_1021_acsaem_5c01775 crossref_primary_10_3390_catal11101165 crossref_primary_10_1016_j_jmst_2024_03_078 crossref_primary_10_1002_advs_202207109 crossref_primary_10_1002_aenm_201803185 crossref_primary_10_1002_cssc_202101272 crossref_primary_10_1016_j_ijhydene_2025_04_477 crossref_primary_10_1007_s11664_024_11025_9 crossref_primary_10_1016_j_coelec_2020_100673 crossref_primary_10_1021_jacs_0c12799 crossref_primary_10_1002_er_4765 crossref_primary_10_1039_D4CY00518J crossref_primary_10_1038_s41524_025_01704_4 crossref_primary_10_1002_chem_202402477 crossref_primary_10_1016_j_coelec_2022_101085 crossref_primary_10_1021_acs_chemmater_4c03479 crossref_primary_10_1021_jacs_9b07986 crossref_primary_10_3390_catal12121541 crossref_primary_10_1016_j_jpowsour_2015_11_008 crossref_primary_10_1016_j_renene_2025_124279 crossref_primary_10_1002_eom2_12265 crossref_primary_10_1016_j_apcatb_2022_121959 crossref_primary_10_1016_j_jcis_2020_06_117 crossref_primary_10_1016_j_apsusc_2023_157498 crossref_primary_10_1038_s41467_025_62160_8 crossref_primary_10_3390_en15051609 crossref_primary_10_1016_j_nanoen_2016_04_007 crossref_primary_10_3390_catal10101182 crossref_primary_10_1016_j_electacta_2023_142685 crossref_primary_10_1016_j_jpowsour_2021_230072 crossref_primary_10_1002_elsa_202100189 crossref_primary_10_1016_j_jcat_2021_04_008 crossref_primary_10_1002_wcms_1499 crossref_primary_10_1002_elsa_202400027 crossref_primary_10_1021_acsnano_5c00124 crossref_primary_10_1039_C8CP00927A crossref_primary_10_1007_s10008_021_05084_9 crossref_primary_10_1002_celc_202300394 crossref_primary_10_1016_j_jelechem_2024_118913 crossref_primary_10_1016_j_coelec_2022_101095 crossref_primary_10_1002_adma_201907818 crossref_primary_10_1016_j_nanoen_2016_01_027 crossref_primary_10_1016_S1872_2067_23_64581_4 crossref_primary_10_1039_D3CY00797A crossref_primary_10_1016_j_electacta_2017_03_012 crossref_primary_10_1016_j_est_2021_103025 crossref_primary_10_1038_s41929_023_00943_2 crossref_primary_10_1002_elsa_202200014 crossref_primary_10_1149_1945_7111_ade200 crossref_primary_10_1002_adfm_201601994 crossref_primary_10_1002_aenm_202404113 crossref_primary_10_1016_j_apsusc_2018_01_129 crossref_primary_10_1016_j_nanoen_2016_04_017 crossref_primary_10_1039_D1NR07254D crossref_primary_10_3390_nano12010118 crossref_primary_10_1016_S1872_2067_21_64088_3 crossref_primary_10_1103_PRXEnergy_3_023001 crossref_primary_10_1016_j_ccr_2021_213782 crossref_primary_10_1039_D3CY01485A crossref_primary_10_1007_s11244_025_02062_7 crossref_primary_10_1016_j_electacta_2022_140799 crossref_primary_10_5004_dwt_2021_26583 crossref_primary_10_1016_j_jallcom_2024_173862 crossref_primary_10_1039_D0SE01347A crossref_primary_10_1038_s41557_025_01932_7 crossref_primary_10_1016_j_cej_2018_12_060 crossref_primary_10_1016_j_jelechem_2017_09_032 crossref_primary_10_1002_cctc_201600983 crossref_primary_10_1016_j_jechem_2016_10_009 crossref_primary_10_1002_adfm_202404535 crossref_primary_10_1016_j_mtener_2021_100659 crossref_primary_10_1016_j_energy_2018_07_147 crossref_primary_10_1021_jacs_4c17263 crossref_primary_10_1038_s43246_025_00900_5 crossref_primary_10_1080_09506608_2019_1653520 crossref_primary_10_1002_adma_202417757 crossref_primary_10_1016_j_electacta_2018_05_035 crossref_primary_10_1016_j_electacta_2019_03_100 crossref_primary_10_1016_j_ijhydene_2022_02_117 crossref_primary_10_1021_jacs_7b00279 crossref_primary_10_1039_D4YA00609G crossref_primary_10_1039_D3NR06242B crossref_primary_10_1039_D4EE03150D crossref_primary_10_3390_catal12121576 crossref_primary_10_1016_j_coelec_2025_101691 crossref_primary_10_1016_j_coelec_2022_101194 crossref_primary_10_1016_j_jelechem_2022_116711 crossref_primary_10_1016_j_jelechem_2023_117548 crossref_primary_10_1021_jacs_7b10646 crossref_primary_10_1038_s41570_017_0087 crossref_primary_10_1038_s41598_024_71703_w crossref_primary_10_1063_5_0192779 crossref_primary_10_1002_cctc_202001639 crossref_primary_10_1016_j_ijhydene_2020_06_157 crossref_primary_10_1016_j_electacta_2018_08_130 crossref_primary_10_1021_jacs_3c10202 crossref_primary_10_1007_s10008_021_04950_w crossref_primary_10_1021_jacs_3c12980 crossref_primary_10_3390_polym16223155 crossref_primary_10_3390_ma12081336 crossref_primary_10_1016_j_ijhydene_2023_12_273 crossref_primary_10_1002_ente_202000927 crossref_primary_10_1002_adfm_201502217 crossref_primary_10_1007_s11244_015_0487_5 crossref_primary_10_1016_S1872_2067_22_64186_X crossref_primary_10_1016_j_apcatb_2023_122740 crossref_primary_10_1021_jacs_2c07988 crossref_primary_10_1002_aenm_201802614 crossref_primary_10_1016_j_jechem_2021_12_050 crossref_primary_10_1039_C9RA02605C crossref_primary_10_1016_j_elecom_2018_09_011 crossref_primary_10_1016_j_surfrep_2023_100597 crossref_primary_10_1002_aenm_201502319 crossref_primary_10_1002_cssc_201700017 crossref_primary_10_1007_s11814_025_00506_0 crossref_primary_10_1016_j_cej_2019_123428 crossref_primary_10_1016_j_cplett_2024_141588 crossref_primary_10_1016_j_catcom_2021_106378 crossref_primary_10_1016_j_ijhydene_2022_06_303 crossref_primary_10_1016_j_jcis_2024_10_141 crossref_primary_10_1016_j_renene_2020_03_031 crossref_primary_10_1016_j_xcrp_2025_102469 crossref_primary_10_1016_j_electacta_2018_02_106 crossref_primary_10_1557_mrc_2016_27 crossref_primary_10_1016_j_ijhydene_2015_12_026 crossref_primary_10_1002_er_6338 crossref_primary_10_1002_cssc_201600359 crossref_primary_10_1016_j_jelechem_2021_115429 crossref_primary_10_1080_1536383X_2022_2125959 crossref_primary_10_1021_acsnano_4c13602 crossref_primary_10_1007_s10008_020_04815_8 crossref_primary_10_1016_j_electacta_2024_144593 crossref_primary_10_1021_acs_analchem_5c04020 crossref_primary_10_1016_j_jcat_2023_115215 crossref_primary_10_1002_celc_202000319 crossref_primary_10_1038_s44160_023_00376_6 crossref_primary_10_1021_jacs_2c10212 crossref_primary_10_1016_j_checat_2024_101039 crossref_primary_10_3390_hydrogen4040049 crossref_primary_10_1002_ange_202307907 crossref_primary_10_1016_j_apsusc_2021_149568 crossref_primary_10_1002_smtd_201800415 crossref_primary_10_1016_j_cej_2025_161416 crossref_primary_10_1007_s12598_022_02259_9 crossref_primary_10_1002_adfm_202407342 crossref_primary_10_1016_j_jelechem_2023_117973 crossref_primary_10_1016_j_mtener_2020_100432 crossref_primary_10_1016_j_electacta_2021_137975 crossref_primary_10_1016_j_cej_2024_149486 crossref_primary_10_1016_S1872_2067_15_60875_0 crossref_primary_10_1039_D4EE01615G crossref_primary_10_3390_molecules25214996 crossref_primary_10_1016_j_ijhydene_2021_08_056 crossref_primary_10_1021_jacs_4c03915 crossref_primary_10_1016_j_cplett_2023_140650 crossref_primary_10_1016_j_susc_2019_04_007 crossref_primary_10_1016_j_electacta_2021_138136 crossref_primary_10_1016_j_ijhydene_2019_05_183 crossref_primary_10_1039_D5SE00408J crossref_primary_10_1016_S1872_2067_23_64486_9 crossref_primary_10_1016_j_apsusc_2020_147894 crossref_primary_10_1016_j_jpowsour_2021_230640 crossref_primary_10_1039_C9NR06078B crossref_primary_10_3390_catal11030315 crossref_primary_10_1016_j_cej_2023_144187 crossref_primary_10_1021_acsanm_5c00486 |
| Cites_doi | 10.1007/978-1-4613-3144-5 10.1021/jp1048887 10.1021/jp4071554 10.1016/S0079-6816(98)00015-X 10.1149/1.1856988 10.1016/j.electacta.2013.07.112 10.1021/jp302210y 10.1039/c2cp40717e 10.1021/cs300227s 10.1016/0013-4686(94)85159-X 10.1016/j.elecom.2013.06.023 10.1149/05002.2163ecst 10.1002/bscb.19580670714 10.1002/anie.200702338 10.1103/PhysRevB.79.235436 10.1016/S0022-0728(98)00093-X 10.1016/0022-0728(87)85258-0 10.1016/0360-3199(94)90173-2 10.1016/S0022-0728(99)00060-1 10.1021/jp048641u 10.1021/jp047349j 10.1039/C3EE00045A 10.1016/S0022-0728(72)80485-6 10.1149/1.2423674 10.1002/cphc.201100309 10.1063/1.1854623 10.1016/0039-6028(71)90175-0 10.1039/tf9585401053 10.1016/S0022-0728(75)80296-8 10.1002/cphc.200900808 10.1016/S0022-0728(72)80496-0 10.1063/1.1742723 10.1016/j.electacta.2006.12.007 10.1016/S0013-4686(97)00084-4 |
| ContentType | Journal Article |
| Copyright | Copyright © 2014, Quaino et al. 2014 Quaino et al. |
| Copyright_xml | – notice: Copyright © 2014, Quaino et al. 2014 Quaino et al. |
| DBID | AAYXX CITATION NPM 7X8 5PM DOA |
| DOI | 10.3762/bjnano.5.96 |
| DatabaseName | CrossRef PubMed MEDLINE - Academic PubMed Central (Full Participant titles) DOAJ (Directory of Open Access Journals) |
| DatabaseTitle | CrossRef PubMed MEDLINE - Academic |
| DatabaseTitleList | MEDLINE - Academic PubMed CrossRef |
| Database_xml | – sequence: 1 dbid: DOA name: DOAJ Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website – sequence: 2 dbid: NPM name: PubMed url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 3 dbid: 7X8 name: MEDLINE - Academic url: https://search.proquest.com/medline sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 2190-4286 |
| EndPage | 854 |
| ExternalDocumentID | oai_doaj_org_article_f878eef651fa477d978515d7d6a8b326 PMC4077405 24991521 10_3762_bjnano_5_96 |
| Genre | Journal Article |
| GroupedDBID | 53G 5VS AAFWJ AAKDD AAYXX ACGFO ACGOD ADBBV ADDVE ADRAZ AENEX AFPKN ALMA_UNASSIGNED_HOLDINGS AOIJS BAWUL BCNDV CITATION DIK FRP GROUPED_DOAJ GX1 HH5 HYE IPNFZ KQ8 M48 M~E OK1 PGMZT RIG RNS RPM ~9O 88I 8FE 8FG ABUWG AFKRA ARAPS AZQEC BENPR BFMQW BGLVJ BPHCQ CCPQU DWQXO GNUQQ HCIFZ M2P NPM P62 PHGZT PIMPY PQQKQ PROAC 7X8 5PM |
| ID | FETCH-LOGICAL-c513t-863eed89ad5d5164b3e82f9cc1c6c8d0310d5461b93dc6c2be2f3d4485377de93 |
| IEDL.DBID | DOA |
| ISICitedReferencesCount | 503 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000337811200001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| ISSN | 2190-4286 |
| IngestDate | Fri Oct 03 12:44:45 EDT 2025 Thu Aug 21 13:54:39 EDT 2025 Fri Jul 11 12:07:17 EDT 2025 Thu Apr 03 07:10:28 EDT 2025 Sat Nov 29 03:41:57 EST 2025 Tue Nov 18 22:35:33 EST 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 1 |
| Keywords | hydrogen evolution volcano curve electrocatalysis Sabatier’s principle |
| Language | English |
| License | http://creativecommons.org/licenses/by/2.0 The license is subject to the Beilstein Journal of Nanotechnology terms and conditions: (https://www.beilstein-journals.org/bjnano/terms) This is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c513t-863eed89ad5d5164b3e82f9cc1c6c8d0310d5461b93dc6c2be2f3d4485377de93 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| OpenAccessLink | https://doaj.org/article/f878eef651fa477d978515d7d6a8b326 |
| PMID | 24991521 |
| PQID | 1543279627 |
| PQPubID | 23479 |
| PageCount | 9 |
| ParticipantIDs | doaj_primary_oai_doaj_org_article_f878eef651fa477d978515d7d6a8b326 pubmedcentral_primary_oai_pubmedcentral_nih_gov_4077405 proquest_miscellaneous_1543279627 pubmed_primary_24991521 crossref_primary_10_3762_bjnano_5_96 crossref_citationtrail_10_3762_bjnano_5_96 |
| PublicationCentury | 2000 |
| PublicationDate | 2014-06-13 |
| PublicationDateYYYYMMDD | 2014-06-13 |
| PublicationDate_xml | – month: 06 year: 2014 text: 2014-06-13 day: 13 |
| PublicationDecade | 2010 |
| PublicationPlace | Germany |
| PublicationPlace_xml | – name: Germany – name: Trakehner Str. 7-9, 60487 Frankfurt am Main, Germany |
| PublicationTitle | Beilstein journal of nanotechnology |
| PublicationTitleAlternate | Beilstein J Nanotechnol |
| PublicationYear | 2014 |
| Publisher | Beilstein-Institut |
| Publisher_xml | – name: Beilstein-Institut |
| References | ref12 ref34 ref15 Morrison (ref30) 1980 ref37 ref14 ref36 ref31 ref11 ref33 ref10 ref32 ref2 ref17 ref39 ref16 ref38 Parsons (ref4) 2011 ref18 ref24 ref23 ref26 ref25 ref20 ref22 ref21 ref28 ref27 Gerischer (ref13) 1955; 59 ref29 ref8 ref7 ref9 ref3 ref6 ref5 Batrakov (ref19) 1972; 8 Kinoshita (ref35) 1992 Sabatier (ref1) 1920 |
| References_xml | – volume-title: Electrochemistry at Semiconductor, Oxidized Metal Electrodes year: 1980 ident: ref30 doi: 10.1007/978-1-4613-3144-5 – ident: ref33 doi: 10.1021/jp1048887 – ident: ref37 doi: 10.1021/jp4071554 – ident: ref23 doi: 10.1016/S0079-6816(98)00015-X – ident: ref7 doi: 10.1149/1.1856988 – ident: ref16 doi: 10.1016/j.electacta.2013.07.112 – volume: 59 start-page: 1049 year: 1955 ident: ref13 publication-title: Zeitschrift fuer Elektrochemie – ident: ref31 doi: 10.1021/jp302210y – ident: ref8 doi: 10.1039/c2cp40717e – volume: 8 start-page: 640 year: 1972 ident: ref19 publication-title: Elektrokhimiya – ident: ref38 doi: 10.1021/cs300227s – volume-title: Catalysis in Electrochemistry, from Fundamentals to Strategies for Fuel Cell Development year: 2011 ident: ref4 – ident: ref11 doi: 10.1016/0013-4686(94)85159-X – ident: ref17 doi: 10.1016/j.elecom.2013.06.023 – ident: ref22 doi: 10.1149/05002.2163ecst – volume-title: Electrochemical oxygen technology year: 1992 ident: ref35 – ident: ref2 doi: 10.1002/bscb.19580670714 – volume-title: La catalyse en chimie organique year: 1920 ident: ref1 – ident: ref9 doi: 10.1002/anie.200702338 – ident: ref10 doi: 10.1103/PhysRevB.79.235436 – ident: ref15 doi: 10.1016/S0022-0728(98)00093-X – ident: ref14 doi: 10.1016/0022-0728(87)85258-0 – ident: ref29 doi: 10.1016/0360-3199(94)90173-2 – ident: ref18 doi: 10.1016/S0022-0728(99)00060-1 – ident: ref21 doi: 10.1021/jp048641u – ident: ref36 doi: 10.1021/jp047349j – ident: ref34 doi: 10.1039/C3EE00045A – ident: ref5 doi: 10.1016/S0022-0728(72)80485-6 – ident: ref32 doi: 10.1149/1.2423674 – ident: ref25 doi: 10.1002/cphc.201100309 – ident: ref27 doi: 10.1063/1.1854623 – ident: ref39 doi: 10.1016/0039-6028(71)90175-0 – ident: ref3 doi: 10.1039/tf9585401053 – ident: ref28 doi: 10.1016/S0022-0728(75)80296-8 – ident: ref20 doi: 10.1002/cphc.200900808 – ident: ref12 doi: 10.1016/S0022-0728(72)80496-0 – ident: ref6 doi: 10.1063/1.1742723 – ident: ref24 doi: 10.1016/j.electacta.2006.12.007 – ident: ref26 doi: 10.1016/S0013-4686(97)00084-4 |
| SSID | ssj0000402898 |
| Score | 2.539442 |
| Snippet | Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and... Sabatier's principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and... |
| SourceID | doaj pubmedcentral proquest pubmed crossref |
| SourceType | Open Website Open Access Repository Aggregation Database Index Database Enrichment Source |
| StartPage | 846 |
| SubjectTerms | electrocatalysis Full Research Paper hydrogen evolution Nanoscience Nanotechnology Sabatier’s principle volcano curve |
| Title | Volcano plots in hydrogen electrocatalysis – uses and abuses |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/24991521 https://www.proquest.com/docview/1543279627 https://pubmed.ncbi.nlm.nih.gov/PMC4077405 https://doaj.org/article/f878eef651fa477d978515d7d6a8b326 |
| Volume | 5 |
| WOSCitedRecordID | wos000337811200001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVAON databaseName: DOAJ Directory of Open Access Journals customDbUrl: eissn: 2190-4286 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000402898 issn: 2190-4286 databaseCode: DOA dateStart: 20100101 isFulltext: true titleUrlDefault: https://www.doaj.org/ providerName: Directory of Open Access Journals – providerCode: PRVHPJ databaseName: ROAD: Directory of Open Access Scholarly Resources customDbUrl: eissn: 2190-4286 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000402898 issn: 2190-4286 databaseCode: M~E dateStart: 20100101 isFulltext: true titleUrlDefault: https://road.issn.org providerName: ISSN International Centre |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1Li9UwFD7o4EIX4tv6GCLMSujMTdO8NoLKDC50cKHD3YWmSZk7XNLh9l7Bjfgf_If-Es9pO5deGXDjppQ00HByknwnOfk-gAMvldUxeNq5D3kprc-98RxjHksEb6qMPaXQ2Ud9emrmc_t5IvVFOWEDPfBguKPGaBNjoyRvqlLrYElNXgYdVGU8Yg-afRH1TIKpfg4u6QStl6Oju9KIsdVwOQ_HU3HkL1KV2kN5SFT9k-WoZ-2_Dmr-nTE5WYJO7sHdETuyt0Ob78ONmB7AnQmj4EN4c9Yu0Vgtu1y2644tEjv_HlYtegkbBW_6_RqiIWG_f_5imy52rEqBVZ5eH8HXk-Mv7z_ko0RCXksu1rlRAhc5Y6sgg8TIx4toisbWNa9VbQLxfgZZKu6tCFhS-Fg0ImBIJgXaMlrxGPZSm-JTYFwa3yDe8lY2JZ-Zyhd-Jo3WM16LKOoMXl9ZytUjfzjJWCwdxhFkVjeY1UlnVQYH28qXA23G9dXekcm3VYjrui9AD3CjB7h_eUAGr646zOHYoAOPKsV20zmEh6LQJC-UwZOhA7e_wrDTEnbJQO907U5bdr-kxXnPv40xsEac--x_NP453EYIVlLyGRcvYG-92sSXcKv-tl50q324qedmv3dtfH76cfwHa4r_7w |
| linkProvider | Directory of Open Access Journals |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Volcano+plots+in+hydrogen+electrocatalysis+%E2%80%93+uses+and+abuses&rft.jtitle=Beilstein+journal+of+nanotechnology&rft.au=Quaino%2C+Paola&rft.au=Juarez%2C+Fernanda&rft.au=Santos%2C+Elizabeth&rft.au=Schmickler%2C+Wolfgang&rft.date=2014-06-13&rft.pub=Beilstein-Institut&rft.eissn=2190-4286&rft.volume=5&rft.spage=846&rft.epage=854&rft_id=info:doi/10.3762%2Fbjnano.5.96&rft_id=info%3Apmid%2F24991521&rft.externalDocID=PMC4077405 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2190-4286&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2190-4286&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2190-4286&client=summon |