Effect of water hardness on surface tension and dilational visco-elasticity of sodium dodecyl sulphate solutions

[Display omitted] ► The surface activity of SDS is increased due to presence of bivalent ions. ► In presence of bivalent ions double chain surfactants like Ca(DS)2 can be formed. ► The hydrolysis of SDS is enhanced in NaCl solutions, producing dodecanol. ► Bivalent ions further enhance the SDS hydro...

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Vydáno v:Journal of colloid and interface science Ročník 377; číslo 1; s. 1 - 6
Hlavní autoři: Fainerman, V.B., Lylyk, S.V., Aksenenko, E.V., Kovalchuk, N.M., Kovalchuk, V.I., Petkov, J.T., Miller, R.
Médium: Journal Article
Jazyk:angličtina
Vydáno: Amsterdam Elsevier Inc 01.07.2012
Elsevier
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ISSN:0021-9797, 1095-7103, 1095-7103
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Abstract [Display omitted] ► The surface activity of SDS is increased due to presence of bivalent ions. ► In presence of bivalent ions double chain surfactants like Ca(DS)2 can be formed. ► The hydrolysis of SDS is enhanced in NaCl solutions, producing dodecanol. ► Bivalent ions further enhance the SDS hydrolysis in solution. ► SDS in hard water represents a multicomponent surfactant solution. The complementary drop and bubble profile analysis and maximum bubble pressure tensiometry are used to measure the dynamic surface tension of aqueous SDS solutions in the presence of hardness salts (CaCl2 and MgCl2 in the ratio of 2:1 at concentrations of 6 and 40FH). The presence of hardness salts results in an essential increase of the SDS adsorption activity, which indicates the formation of Ca(DS)2 and Mg(DS)2 in the SDS solutions. The surface tension isotherms of SDS in presence of Ca(DS)2 and Mg(DS)2 are described using the generalised Frumkin model. The presence of hardness salts accelerates the ageing of SDS solutions as compared with the addition of 0.01M NaCl due to a faster hydrolysis and hence formation of dodecanol. These results are used to estimate the possible concentration of dodecanol in the studied SDS solutions. The buoyant bubble profile method with harmonic surface oscillations is used to measure the dilational rheology of SDS solutions in presence of hardness salts in the frequency range between 0.005Hz and 0.2Hz. The visco-elasticity modulus in the presence of hardness salts is higher as compared with its values in the presence of 0.01M NaCl additions. The ageing of SDS solutions leads to an essential increase of the visco-elastic modulus.
AbstractList The complementary drop and bubble profile analysis and maximum bubble pressure tensiometry are used to measure the dynamic surface tension of aqueous SDS solutions in the presence of hardness salts (CaCl₂ and MgCl₂ in the ratio of 2:1 at concentrations of 6 and 40FH). The presence of hardness salts results in an essential increase of the SDS adsorption activity, which indicates the formation of Ca(DS)₂ and Mg(DS)₂ in the SDS solutions. The surface tension isotherms of SDS in presence of Ca(DS)₂ and Mg(DS)₂ are described using the generalised Frumkin model. The presence of hardness salts accelerates the ageing of SDS solutions as compared with the addition of 0.01M NaCl due to a faster hydrolysis and hence formation of dodecanol. These results are used to estimate the possible concentration of dodecanol in the studied SDS solutions. The buoyant bubble profile method with harmonic surface oscillations is used to measure the dilational rheology of SDS solutions in presence of hardness salts in the frequency range between 0.005Hz and 0.2Hz. The visco-elasticity modulus in the presence of hardness salts is higher as compared with its values in the presence of 0.01M NaCl additions. The ageing of SDS solutions leads to an essential increase of the visco-elastic modulus.
The complementary drop and bubble profile analysis and maximum bubble pressure tensiometry are used to measure the dynamic surface tension of aqueous SDS solutions in the presence of hardness salts (CaCl(2) and MgCl(2) in the ratio of 2:1 at concentrations of 6 and 40FH). The presence of hardness salts results in an essential increase of the SDS adsorption activity, which indicates the formation of Ca(DS)(2) and Mg(DS)(2) in the SDS solutions. The surface tension isotherms of SDS in presence of Ca(DS)(2) and Mg(DS)(2) are described using the generalised Frumkin model. The presence of hardness salts accelerates the ageing of SDS solutions as compared with the addition of 0.01 M NaCl due to a faster hydrolysis and hence formation of dodecanol. These results are used to estimate the possible concentration of dodecanol in the studied SDS solutions. The buoyant bubble profile method with harmonic surface oscillations is used to measure the dilational rheology of SDS solutions in presence of hardness salts in the frequency range between 0.005 Hz and 0.2 Hz. The visco-elasticity modulus in the presence of hardness salts is higher as compared with its values in the presence of 0.01 M NaCl additions. The ageing of SDS solutions leads to an essential increase of the visco-elastic modulus.
The complementary drop and bubble profile analysis and maximum bubble pressure tensiometry are used to measure the dynamic surface tension of aqueous SDS solutions in the presence of hardness salts (CaCl2 and MgCl2 in the ratio of 2: 1 at concentrations of 6 and 40 FH). The presence of hardness salts results in an essential increase of the SDS adsorption activity, which indicates the formation of Ca(DS)2 and Mg(DS)2 in the SDS solutions. The surface tension isotherms of SDS in presence of Ca(DS)2 and Mg(DS)2 are described using the generalised Frumkin model. The presence of hardness salts accelerates the ageing of SDS solutions as compared with the addition of 0.01 M NaCl due to a faster hydrolysis and hence formation of dodecanol. These results are used to estimate the possible concentration of dodecanol in the studied SDS solutions. The buoyant bubble profile method with harmonic surface oscillations is used to measure the dilational rheology of SDS solutions in presence of hardness salts in the frequency range between 0.005 Hz and 0.2 Hz. The visco-elasticity modulus in the presence of hardness salts is higher as compared with its values in the presence of 0.01 M NaCl additions. The ageing of SDS solutions leads to an essential increase of the visco-elastic modulus.
The complementary drop and bubble profile analysis and maximum bubble pressure tensiometry are used to measure the dynamic surface tension of aqueous SDS solutions in the presence of hardness salts (CaCl(2) and MgCl(2) in the ratio of 2:1 at concentrations of 6 and 40FH). The presence of hardness salts results in an essential increase of the SDS adsorption activity, which indicates the formation of Ca(DS)(2) and Mg(DS)(2) in the SDS solutions. The surface tension isotherms of SDS in presence of Ca(DS)(2) and Mg(DS)(2) are described using the generalised Frumkin model. The presence of hardness salts accelerates the ageing of SDS solutions as compared with the addition of 0.01 M NaCl due to a faster hydrolysis and hence formation of dodecanol. These results are used to estimate the possible concentration of dodecanol in the studied SDS solutions. The buoyant bubble profile method with harmonic surface oscillations is used to measure the dilational rheology of SDS solutions in presence of hardness salts in the frequency range between 0.005 Hz and 0.2 Hz. The visco-elasticity modulus in the presence of hardness salts is higher as compared with its values in the presence of 0.01 M NaCl additions. The ageing of SDS solutions leads to an essential increase of the visco-elastic modulus.The complementary drop and bubble profile analysis and maximum bubble pressure tensiometry are used to measure the dynamic surface tension of aqueous SDS solutions in the presence of hardness salts (CaCl(2) and MgCl(2) in the ratio of 2:1 at concentrations of 6 and 40FH). The presence of hardness salts results in an essential increase of the SDS adsorption activity, which indicates the formation of Ca(DS)(2) and Mg(DS)(2) in the SDS solutions. The surface tension isotherms of SDS in presence of Ca(DS)(2) and Mg(DS)(2) are described using the generalised Frumkin model. The presence of hardness salts accelerates the ageing of SDS solutions as compared with the addition of 0.01 M NaCl due to a faster hydrolysis and hence formation of dodecanol. These results are used to estimate the possible concentration of dodecanol in the studied SDS solutions. The buoyant bubble profile method with harmonic surface oscillations is used to measure the dilational rheology of SDS solutions in presence of hardness salts in the frequency range between 0.005 Hz and 0.2 Hz. The visco-elasticity modulus in the presence of hardness salts is higher as compared with its values in the presence of 0.01 M NaCl additions. The ageing of SDS solutions leads to an essential increase of the visco-elastic modulus.
[Display omitted] ► The surface activity of SDS is increased due to presence of bivalent ions. ► In presence of bivalent ions double chain surfactants like Ca(DS)2 can be formed. ► The hydrolysis of SDS is enhanced in NaCl solutions, producing dodecanol. ► Bivalent ions further enhance the SDS hydrolysis in solution. ► SDS in hard water represents a multicomponent surfactant solution. The complementary drop and bubble profile analysis and maximum bubble pressure tensiometry are used to measure the dynamic surface tension of aqueous SDS solutions in the presence of hardness salts (CaCl2 and MgCl2 in the ratio of 2:1 at concentrations of 6 and 40FH). The presence of hardness salts results in an essential increase of the SDS adsorption activity, which indicates the formation of Ca(DS)2 and Mg(DS)2 in the SDS solutions. The surface tension isotherms of SDS in presence of Ca(DS)2 and Mg(DS)2 are described using the generalised Frumkin model. The presence of hardness salts accelerates the ageing of SDS solutions as compared with the addition of 0.01M NaCl due to a faster hydrolysis and hence formation of dodecanol. These results are used to estimate the possible concentration of dodecanol in the studied SDS solutions. The buoyant bubble profile method with harmonic surface oscillations is used to measure the dilational rheology of SDS solutions in presence of hardness salts in the frequency range between 0.005Hz and 0.2Hz. The visco-elasticity modulus in the presence of hardness salts is higher as compared with its values in the presence of 0.01M NaCl additions. The ageing of SDS solutions leads to an essential increase of the visco-elastic modulus.
Author Kovalchuk, V.I.
Miller, R.
Fainerman, V.B.
Lylyk, S.V.
Petkov, J.T.
Kovalchuk, N.M.
Aksenenko, E.V.
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  fullname: Miller, R.
  email: miller@mpikg.mpg.de
  organization: Max-Planck-Institut für Kolloid- und Grenzflächenforschung, 14424 Potsdam, Germany
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Issue 1
Keywords Thermodynamic adsorption model
Dilational surface rheology
SDS
Maximum bubble pressure tensiometry
Bivalent ions
Dynamics of adsorption
Drop and bubble profile tensiometry
Water hardness
Water
Elasticity
Ionic surfactant
Maximum bubble pressure
Bubble
Thermodynamic model
Dynamics
Oscillation
Elastic modulus
Rheology
Ageing
Ions
Hardness
Lauryl sulfate
Drop
Hydrolysis
Dynamic surface tension
Anionic surfactant
Adsorption
Sodium
Isotherm
Frequency
Surface tension
Aqueous solution
Physicochemical properties
Language English
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CC BY 4.0
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Snippet [Display omitted] ► The surface activity of SDS is increased due to presence of bivalent ions. ► In presence of bivalent ions double chain surfactants like...
The complementary drop and bubble profile analysis and maximum bubble pressure tensiometry are used to measure the dynamic surface tension of aqueous SDS...
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SubjectTerms adsorption
Aging
Bivalent ions
Bubbles
Buoyancy
calcium chloride
Calcium Chloride - chemistry
Chemistry
Dilational surface rheology
Dodecanol
Drop and bubble profile tensiometry
Dynamics of adsorption
Exact sciences and technology
General and physical chemistry
Hardness
hydrolysis
magnesium chloride
Magnesium Chloride - chemistry
Mathematical models
Maximum bubble pressure tensiometry
rheology
SDS
sodium chloride
sodium dodecyl sulfate
Sodium Dodecyl Sulfate - chemistry
Solutions
Surface physical chemistry
Surface Tension
Thermodynamic adsorption model
Viscoelastic Substances - chemistry
Viscoelasticity
Water - chemistry
Water hardness
Title Effect of water hardness on surface tension and dilational visco-elasticity of sodium dodecyl sulphate solutions
URI https://dx.doi.org/10.1016/j.jcis.2012.03.030
https://www.ncbi.nlm.nih.gov/pubmed/22484167
https://www.proquest.com/docview/1013765864
https://www.proquest.com/docview/1038246528
https://www.proquest.com/docview/1803124554
Volume 377
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