Redox-Induced Spin-State Switching and Mixed Valency in Quinonoid-Bridged Dicobalt Complexes

The complexes [{(tmpa)CoII}2(μ‐L1)2−]2+ (12+) and [{(tmpa)CoII}2(μ‐L2)2−]2+ (22+), with tmpa=tris(2‐pyridylmethyl)amine, H2L1=2,5‐di‐[2‐(methoxy)‐anilino]‐1,4‐benzoquinone, and H2L2=2,5‐di‐[2‐(trifluoromethyl)‐anilino]‐1,4‐benzoquinone, were synthesized and characterized. Structural analysis of 22+...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 20; no. 12; pp. 3475 - 3486
Main Authors:	Schweinfurth, David, Rechkemmer, Yvonne, Hohloch, Stephan, Deibel, Naina, Peremykin, Irina, Fiedler, Jan, Marx, Raphael, Neugebauer, Petr, van Slageren, Joris, Sarkar, Biprajit
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 17.03.2014 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Subjects:	Bridging bridging ligands Chemistry Cobalt Ferromagnetism Ion exchangers Ligands mixed-valent compounds non-innocent ligands Oxidation quinones spectroelectrochemistry Spin exchange SQUIDs Structural analysis Superconducting quantum interference devices spectroelectrochemistry bridging ligands quinones non-innocent ligands mixed-valent compounds
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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